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Wide color-varying visualization of sulfide with a dual emissive ratiometric fluorescence assay using carbon dots and gold nanoclusters
, Article Microchemical Journal ; Volume 157 , September , 2020 ; Bigdeli, A ; Hormozi Nezhad, M. R ; Sharif University of Technology
Elsevier Inc
2020
Abstract
Development of visual detection methods regarding water pollutants can effectively facilitate water resource monitoring programs. A wide color-varying ratiometric approach has been developed for sensitive determination of sulfide by mixing orange emissive glutathione stabilized gold nanoclusters (AuNCs) and blue emissive urea stabilized carbon dots (CDs) in an appropriate ratio. Under a single excitation wavelength of 365 nm, the ratiometric fluorescence (RF) probe exhibited two distinct emission bands at 452 and 607 nm corresponding to CDs and AuNCs, respectively. Owing to the high affinity of sulfide ions to AuNCs in alkaline medium, the fluorescence (FL) of AuNCs was turned-off while the...
Evaluation of spatial and temporal variation in water quality by pattern recognition techniques: A case study on Jajrood River (Tehran, Iran)
, Article Journal of Environmental Management ; Volume 91, Issue 4 , 2010 , Pages 852-860 ; 03014797 (ISSN) ; Abrishamchi, A ; Torkian, A ; Sharif University of Technology
2010
Abstract
In this paper, principal component analysis (PCA) and hierarchical cluster analysis (CA) methods have been used to investigate the water quality of Jajrood River (Iran) and to assess and discriminate the relative magnitude of anthropogenic and "natural" influences on the quality of river water. T, EC, pH, TDS, NH4, NO3, NO2, Turb., T.Hard., Ca, Mg, Na, K, Cl, SO4, SiO2 as physicochemical and TC, FC as biochemical variables have been analyzed in the water samples collected every month over a three-year period from 18 sampling stations along a 50 km section of Jajrood River that is under the influence of anthropogenic and natural changes. Exploratory analysis of experimental data has been...
A conflict resolution method for waste load reallocation in river systems
, Article International Journal of Environmental Science and Technology ; Volume 16, Issue 1 , 2019 , Pages 79-88 ; 17351472 (ISSN) ; Moridi, A ; Mirbagheri, A ; Abbaspour, M ; Sharif University of Technology
Center for Environmental and Energy Research and Studies
2019
Abstract
Various urban, industrial, and agricultural pollutions discharge more than river self-purification potential damages river ecosystem and increases water treatment costs. As different decision-makers and stakeholders are involved in the water quality management in river systems, a new bankruptcy form of the game theory is used to resolve the existing conflict of interests related to waste load allocation in downstream river. The river restoration potential can allocate to the conflicting parties with respect to their claims, by using bankruptcy solution methods. In this research, dischargeable pollution loads to Karun River are determined by pollution sources in various scenarios using...
A conflict resolution method for waste load reallocation in river systems
, Article International Journal of Environmental Science and Technology ; 2018 ; 17351472 (ISSN) ; Moridi, A ; Mirbagheri, A ; Abbaspour, M ; Sharif University of Technology
Center for Environmental and Energy Research and Studies
2018
Abstract
Various urban, industrial, and agricultural pollutions discharge more than river self-purification potential damages river ecosystem and increases water treatment costs. As different decision-makers and stakeholders are involved in the water quality management in river systems, a new bankruptcy form of the game theory is used to resolve the existing conflict of interests related to waste load allocation in downstream river. The river restoration potential can allocate to the conflicting parties with respect to their claims, by using bankruptcy solution methods. In this research, dischargeable pollution loads to Karun River are determined by pollution sources in various scenarios using...
A novel analysis of critical water pollution in the transboundary Aras River using the Sentinel-2 satellite images and ANNs
, Article International Journal of Environmental Science and Technology ; Volume 19, Issue 9 , 2022 , Pages 9011-9026 ; 17351472 (ISSN) ; Zarghami, M ; Mosaferi, M ; Karimzadeh, S ; Sharif University of Technology
Springer Science and Business Media Deutschland GmbH
2022
Abstract
Recently, remote sensing considered as important tool in studies of water quality issues. The Aras River flows across a transboundary basin in northern Iran. In this study, the aim is to model the water quality parameters (WQPs) using remote sensing and an artificial neural network (ANN), which is a new method proposed to find WQPs based on multivariate regression approaches. The relationship between WQPs and digital data from the Sentinel-2 satellite was determined to estimate and map the WQPs in this river. Using the field data and digital image data, the obtained results show that multivariate regression approaches and high-resolution remote sensing could monitor and predict the...
A polypyrrole-based sorptive microextraction coating for preconcentration of malathion from aquatic media
, Article Chromatographia ; Volume 74, Issue 9-10 , 2011 , Pages 731-735 ; 00095893 (ISSN) ; Aghakhani, A ; Ayazi, Z ; Khakinezhad, M ; Sharif University of Technology
Abstract
A new micro-solid phase extraction method was developed by combining solid-phase extraction and stir bar sorptive extraction to benefit from the advantages of both techniques. A polypyrrole coating was electrochemically synthesized on the surface of an already used graphite furnace, employed in electro-thermal atomic absorption spectroscopy. The cylindrical geometry of the graphite tube provided a rather huge surface area, suitable for sorptive extraction. The novel sorbent coating was examined as an extracting medium to isolate malathion. Effects of different parameters such as extraction time, salt concentration, sample volume, desorption solvent and time were investigated and optimized....
Oppositely charged MXene fibers as a highly efficient osmotic power generator from sea and river water
, Article Journal of Materials Chemistry A ; Volume 10, Issue 46 , 2022 , Pages 24915-24926 ; 20507488 (ISSN) ; Esfandiar, A ; Sharif University of Technology
Royal Society of Chemistry
2022
Abstract
Ion-exchange membrane-based reverse electrodialysis (RED) shows great potential for harvesting osmotic energy from seawater and converting it to electricity. However, their low energy conversion efficiency and huge ionic resistance hinder their application on large scales. The implementation of nanofluidic channels in RED devices can significantly improve the performance of osmotic power generators due to their selective and fast ion transport. However, technical challenges in scalable processing at the nanoscale and ion-selective membranes restrict their development in economically viable generators. Here, we report fibrous-based channels as positively and negatively charged MXene fibers...
High-throughput micro-solid phase extraction on 96-well plate using dodecyl methacrylate-ethylen glycol dimethacrylate monolithic copolymer
, Article Analytica Chimica Acta ; Volume 792 , August , 2013 , Pages 59-65 ; 00032670 (ISSN) ; Es'haghi, A ; Es-haghi, A ; Mohammadkhani, E ; Sharif University of Technology
2013
Abstract
A novel high-throughput device based on 96-micro-solid phase extraction (96-μ-SPE) system was constructed for multiresidue determination of nine pesticides in aquatic samples. The extraction procedure was performed on a commercially available 96-well plate system. The extraction module consisted of 96 pieces of 1cm×3cm of cylindrically shaped stainless steel meshes. The prepared meshes were fixed in a home-made polytetrafluoroethylene-based constructed ninety-six holes block for possible simultaneous immersion of meshes into the center of individual wells. Dodecyl methacrylate and ethylene glycol dimethacrylate was copolymerized as a monolithic polymer and placed in the cylindrically shaped...
Uncertainty analysis in QUAL2E model of Zayandeh-Rood River
, Article Water Environment Research ; Volume 77, Issue 3 , 2005 , Pages 279-286 ; 10614303 (ISSN) ; Tajrishy, M ; Shafieian, P ; Sharif University of Technology
Water Environment Federation
2005
Abstract
Water-quality modeling and prediction is a complicated task because of inherent randomness and uncertainties associated with various processes and variables throughout the stream environment and the lack of appropriate data. Hence, the results of mathematical models are always approximate, lying within an uncertainty. This paper describes and demonstrates the application of the U.S. Environmental Protection Agency's water-quality model, QUAL2E-UNCAS, to the Zayandeh-Rood River in Iran. First-order reliability analysis is used to examine the variability of predicted water-quality parameters of total dissolved solids, dissolved oxygen, and biochemical oxygen demand. This analysis also...
Polyaniline-nylon-6 electrospun nanofibers for headspace adsorptive microextraction
, Article Analytica Chimica Acta ; Volume 713 , 2012 , Pages 63-69 ; 00032670 (ISSN) ; Aghakhani, A ; Sharif University of Technology
2012
Abstract
A headspace adsorptive microextraction technique was developed using a novel polyaniline-nylon-6 (PANI-N6) nanofiber sheet, fabricated by electrospinning. The homogeneity and the porosity of the prepared PANI-N6 sheet were studied using the scanning electron microscopy (SEM) and nanofibers diameters were found to be around 200nm. The novel nanofiber sheet was examined as an extracting medium to isolate some selected chlorobenzenes (CBs), as model compounds, from aquatic media. The extracted analytes were desorbed using μL-amounts of solvent and eventually an aliquot of extractant was injected into gas chromatography-mass spectrometry (GC-MS). Various parameters affecting the extraction and...
Multiple interactive pollutants in water quality trading
, Article Environmental Management ; Volume 42, Issue 4 , 2008 , Pages 620-646 ; 0364152X (ISSN) ; Lence, B. J ; Shamsai, A ; Sharif University of Technology
2008
Abstract
Efficient environmental management calls for the consideration of multiple pollutants, for which two main types of transferable discharge permit (TDP) program have been described: separate permits that manage each pollutant individually in separate markets, with each permit based on the quantity of the pollutant or its environmental effects, and weighted-sum permits that aggregate several pollutants as a single commodity to be traded in a single market. In this paper, we perform a mathematical analysis of TDP programs for multiple pollutants that jointly affect the environment (i.e., interactive pollutants) and demonstrate the practicality of this approach for cost-efficient maintenance of...
On-line micro solid-phase extraction of clodinafop propargyl from water, soil and wheat samples using electrospun polyamide nanofibers
, Article Chromatographia ; Vol. 77, issue. 9-10 , May , 2014 , p. 723-728 ; Asgari, S ; Piri-Moghadam, H ; Sharif University of Technology
Abstract
An on-line extraction/determination set up was designed for micro solid-phase extraction of clodinafop propargyl from water, soil and wheat samples using electrospun polyamide nanofiber mats. The prepared mats were packed in a stainless steel tube which conveniently acted as a high-performance liquid chromatography injection loop. Influential parameters affecting the extraction efficiency were optimized using a distilled water sample fortified with 25 μg L-1 of clodinafop propargyl. An enrichment factor of 440 was achieved for clodinafop propargyl indicating the ability of the whole procedure. Under the optimum conditions, the linearity for the analyte was in the range of 6-700 μg L-1, while...
Larval habitats and biodiversity of anopheline mosquitoes (Diptera: Culicidae) in a malarious area of southern Iran
, Article Journal of Vector Borne Diseases ; Volume 49, Issue 2 , Jun , 2012 , Pages 91-100 ; 09729062 (ISSN) ; Vatandoost, H ; Oshaghi, M. A ; Charrahy, Z ; Haghdoost, A. A ; Sedaghat, M. M ; Abedi, F ; Soltani, M ; Raeisi, A ; Sharif University of Technology
JVBD
2012
Abstract
Background & objectives: Malaria is the most important mosquito-borne disease in Iran. It is endemic in south to southeastern part of the country. Knowledge about bio-ecology of vectors will support authorities for appropriate management of the disease. Bashagard district is one of the main endemic areas for malaria in south of Iran. This study was conducted to determine anopheline fauna, diversity and affinity in the area, characterization of larval habitats, and mapping their potential distribution across the district. Methods: The potential aquatic habitats for Anopheles larvae were extracted from Indian Remote Sensing Satellite (IRS) image and digital elevation model of the area using...
Magnetic nanoparticle-based micro-solid phase extraction and GC-MS determination of oxadiargyl in aqueous samples
, Article Chromatographia ; Volume 74, Issue 5-6 , 2011 , Pages 483-488 ; 00095893 (ISSN) ; Zandi, O ; Aghakhani, A ; Sharif University of Technology
Abstract
A new facile, rapid, inexpensive, and sensitive method based on magnetic micro-solid phase extraction (M-μ-SPE) coupled to gas chromatography-mass spectrometry (GC-MS) was developed for determination of the herbicide oxadiargyl in environmental water samples. The feasibility of employing non-modified magnetic nanoparticles (MNPs) as sorbent was examined and applied to perform the extraction process. Influential parameters affecting the extraction efficiency along with desorption conditions were investigated and optimized. The limit of detection (LOD, S/N = 3) and limit of quantification (LOQ, S/N = 10) of the method under optimized conditions were 0.005 and 0.030 ng mL-1, respectively. The...
Forecasting models for flow and total dissolved solids in Karoun river-Iran
, Article Journal of Hydrology ; Volume 535 , 2016 , Pages 148-159 ; 00221694 (ISSN) ; Salmani Jajaei, E ; Sharif University of Technology
Abstract
Water quality is one of the most important factors contributing to a healthy life. From the water quality management point of view, TDS (total dissolved solids) is the most important factor and many water developing plans have been implemented in recognition of this factor. However, these plans have not been perfect and very successful in overcoming the poor water quality problem, so there are a good volume of related studies in the literature. We study TDS and the water flow of the Karoun river in southwest Iran. We collected the necessary time series data from the Harmaleh station located in the river. We present two Univariate Seasonal Autoregressive Integrated Movement Average (ARIMA)...
Influence of lakebed sediment deposit on the interaction of hypersaline lake and groundwater: A simplified case of lake Urmia, Iran
, Article Journal of Hydrology ; Volume 588 , 2020 ; Ataie Ashtiani, B ; Safaie, A ; Simmons, C. T ; Sharif University of Technology
Elsevier B.V
2020
Abstract
Lake Urmia, which was once the second-largest saline lake in the world, has been shrinking dramatically. Moreover, Lake Urmia has become supersaturated with total salinity averaging more than 350 g/l. Salt precipitation and dissolved materials brought by inflowing rivers have formed a layer of sediment with low hydraulic conductivity on the lakebed. Considering the flat bathymetry of Lake Urmia, we conducted a series of numerical simulation scenarios to study the groundwater flow pattern in the vicinity of the hypersaline Lake Urmia using COMSOL Multiphysics®. In the first step, we performed the simulations in steady-state conditions. Secondly, we simulated the lake level fall in 10 years at...
On-fiber standardization technique for solid-coated solid-phase microextraction
, Article Analytical Chemistry ; Volume 79, Issue 3 , 2007 , Pages 1221-1230 ; 00032700 (ISSN) ; Zhang, X ; Ouyang, G ; Es-haghi, A ; Pawliszyn, J ; Sharif University of Technology
2007
Abstract
The on-fiber standardization technique for solid-coated solid-phase microextraction (SPME) was studied, and a theoretical model is proposed for the isotropic behavior of adsorption and desorption, based on Fick's law of diffusion and the Langmuir model. The isotropy of the adsorption and desorption of analytes onto and from the surface of porous solid SPME fiber was validated with the use of a commercially available fiber, a 50-μm Carbowax/ templated resin for carbamate pesticide analysis in various sample matrixes, and a self-made polypyrrole fiber for diazepam analysis in blood samples. Time constants were comparable for the adsorption and desorption processes. Equilibrium constants and...
Immersed solvent microextraction and gas chromatography-mass spectrometric detection of s-triazine herbicides in aquatic media
, Article Analytica Chimica Acta ; Volume 537, Issue 1-2 , 2005 , Pages 81-87 ; 00032670 (ISSN) ; Khalilian, F ; Sharif University of Technology
Elsevier
2005
Abstract
An immersed solvent microextraction (SME) method was successfully developed for the trace enrichment of s-triazine herbicides from aquatic media. A microdrop of butyl acetate was applied as the extraction solvent. After extraction, the microdrop was introduced directly into a gas chromatography-mass spectrometry (GC-MS) injection port. Some important extraction parameters such as type of solvent, extraction time, stirring rate, and temperature were investigated and optimized. The highest possible microdrop volume of 3 μl, a sampling temperature of 60°C, and use of butyl acetate are major parameters to obtain high enrichment factors. The enrichment factor and linearity was studied by...
How to quantify sustainable development: A risk-based approach to water quality management
, Article Environmental Management ; Volume 41, Issue 2 , 2008 , Pages 200-220 ; 0364152X (ISSN) ; Vahedi, A ; Shamsai, A ; Sharif University of Technology
2008
Abstract
Since the term was coined in the Brundtland report in 1987, the issue of sustainable development has been challenged in terms of quantification. Different policy options may lend themselves more or less to the underlying principles of sustainability, but no analytical tools are available for a more in-depth assessment of the degree of sustainability. Overall, there are two major schools of thought employing the sustainability concept in managerial decisions: those of measuring and those of monitoring. Measurement of relative sustainability is the key issue in bridging the gap between theory and practice of sustainability of water resources systems. The objective of this study is to develop a...
Multiresidue determination of pesticides from aquatic media using polyaniline nanowires network as highly efficient sorbent for microextraction in packed syringe
, Article Analytica Chimica Acta ; Volume 740 , 2012 , Pages 43-49 ; 00032670 (ISSN) ; Alipour, N ; Ayazi, Z ; Sharif University of Technology
Abstract
A simple, rapid and sensitive method based on microextraction in packed syringe (MEPS), in combination with gas chromatography-mass spectrometry (GC-MS) was developed. Polyaniline (PANI) nanowires network was synthesized and used as sorbent of MEPS for the multiresidue determination of selected analytes from triazine, organochlrorine and organophosphorous pesticides in aqueous samples. The PANI nanowires network was prepared using soft template technique and its characterization was studied by scanning electron microscopy (SEM). The presence of micelles in this methodology showed to be an important parameter in shaping the growing polymer. Hexadecyltrimethylammonium bromide (HTAB) was used...