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    Rapid and simultaneous determination of tetracycline and cefixime antibiotics by mean of gold nanoparticles-screen printed gold electrode and chemometrics tools

    , Article Measurement: Journal of the International Measurement Confederation ; Vol. 47, Issue. 1 , 2014 , pp. 145-149 ; ISSN: 02632241 Asadollahi-Baboli, M ; Mani-Varnosfaderani, A ; Sharif University of Technology
    Abstract
    The screen-printed gold electrode (SPGE) modified with the formation of self-assembly monolayer (SAM) of cysteine (Cys) on gold-nanoparticles (Au nano) was utilized for rapid and simultaneous determination of tetracycline and cefixime antibiotics by square wave voltammetry (SWV). Electrochemical investigation and characterization of the modified electrode was achieved using cyclic voltammetry (CV) and scanning electron microscopy (SEM). A principal component artificial neural network (PCANN) with three layer back-propagation network was utilized for the analysis of the voltammogram data. It is possible to simultaneously determine the tetracycline and cefixime concentrations in the ranges of... 

    Mechanochemical green synthesis of exfoliated edge-functionalized boron nitride quantum dots: application to vitamin c sensing through hybridization with gold electrodes

    , Article ACS Applied Materials and Interfaces ; Volume 10, Issue 34 , 2018 , Pages 28819-28827 ; 19448244 (ISSN) Angizi, S ; Hatamie, A ; Ghanbari, H ; Simchi, A ; Sharif University of Technology
    American Chemical Society  2018
    Abstract
    Two-dimensional boron nitride quantum dots (2D BNQDs) with excellent chemical stability, high photoluminescence efficiency, and low toxicity are a new class of advanced materials for biosensing and bioimaging applications. To overcome the current challenge about the lack of facile, scalable, and reproducible synthesis approach of BNQDs, we introduce a green and facile approach based on mechanochemical exfoliation of bulk h-BN particles in ethanol. Few-layered hydroxylated-functionalized QDs with a thickness of 1-2 nm and a lateral dimension of 2-6 nm have been prepared. The synthesized nanocrystals exhibit a strong fluorescence emission at 407 and 425 nm with a quantum efficiency of ∼6.2%....