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    Developing potentiometric sensors for scandium

    , Article Sensors and Actuators B: Chemical ; Volume 348 , 2021 ; 09254005 (ISSN) Dehabadi, M ; Legin, E ; Legin, A ; Yaghmaei, S ; Nechaev, A ; Babain, V ; Kirsanov, D ; Sharif University of Technology
    Elsevier B.V  2021
    Scandium is a rare earth element that is not very abundant on Earth, however in recent years due to the employment of scandium in various high-tech fields the interest in the analytical chemistry of this metal is growing. Currently, the methods for scandium quantification are mainly based on inductively coupled plasma atomic emission and mass-spectrometry and to the best of our knowledge no potentiometric sensors for scandium detection were reported so far. This study is devoted to the development of simple and cost-effective ion-selective sensors for quantification of Sc3+ in aqueous media. Employing the variety of lipophilic ligands suggested in liquid extraction for separation of... 

    Electrochemical determination of l-dopa in the presence of ascorbic acid on the surface of the glassy carbon electrode modified by a bilayer of multi-walled carbon nanotube and poly-pyrrole doped with tiron

    , Article Journal of Electroanalytical Chemistry ; Volume 636, Issue 1-2 , 2009 , Pages 40-46 ; 15726657 (ISSN) Shahrokhian, S ; Asadian, E ; Sharif University of Technology
    Elsevier  2009
    There are high attractions in the development of conducting polymer (CP) coatings to improve the electrochemical properties and biocompatibility of electrodes in the area of biosensors. A new type of the modified electrodes is prepared in a layer-by-layer process by using multi-walled carbon nanotube (MWCNT) and poly-pyrrole. In this procedure, the glassy carbon electrode is casted by a drop suspension of MWCNT, which leads to form a thin film of nanotube on its surface. In the second step, electrochemical polymerization of pyrrole in the presence of tiron (used as doping anion) is performed on the surface of the MWCNT pre-coated electrode. The modification procedure led to fabrication of a...