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    A novel approach for preparation of CL-20 nanoparticles by microemulsion method

    , Article Journal of Molecular Liquids ; Vol. 193, issue , May , 2014 , pp. 83-86 Bayat, Y ; Zarandi, M ; Zarei, M. A ; Soleyman, R ; Zeynali, V ; Sharif University of Technology
    Abstract
    2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) as one of the high energy cage nitramines has been used in various propellants and explosive formulations. The performance of energetic materials depends on its particle size and shape. Therefore, in this research, microemulsion method has been applied for the preparation of CL-20 nanoparticles via oil in water (O/W) microemulsions. The optimized formulation contains water 45%, n-butyl acetate 20.5%, sodium dodecyl sulfate (SDS, as anionic surfactant) 6.5% and 2-propanol (as co-surfactant) 26.5%. CL-20 nanoparticles that were obtained by microemulsion method are spherical with an average diameter of 25 nm, based on TEM image.... 

    Effect of NaOH on the structure and corrosion performance of alumina and silica PEO coatings on aluminum

    , Article Journal of Materials Engineering and Performance ; Volume 21, Issue 10 , October , 2012 , Pages 2195-2202 ; 10599495 (ISSN) Salehi Doolabi, D ; Ehteshamzadeh, M ; Mirhosseini, S. M. M ; Sharif University of Technology
    Springer  2012
    Abstract
    The effect of NaOH content of electrolyte on the properties of ceramic coatings, produced in silicate solution, was studied. Morphology, chemical analysis, phase composition, and cross-section of the ceramic coatings were investigated by SEM, EDS, XRD, and OM, respectively. The corrosion resistance and corrosion mechanism were also studied using potentiodynamic polarization and electrochemical impedance spectroscopy in a 3.5% NaCl solution. To study the surface roughness, a brightness SEM image analysis method was used. Results suggested that increasing the NaOH concentration of sediment production size causes thickness and coating roughness to decrease. The lowest corrosion rate belonged to...