Sharif Digital Repository

Silica composite membranes and BaCe0.9Y0.1O3-δ (BCY) perovskite membranes were successfully synthesized to separate hydrogen in an equimolar mixture of H2, CH4, CO, and CO2 at temperature range of 500–900 °C and pressure difference of 1 bar. The phase structure of both membranes was characterized by X-ray diffraction (XRD). Thermogravimetric analysis (TGA) was used to evaluate phase stability of perovskite membrane. FESEM images confirmed graded structure of silica membrane and uniform, dense structure of perovskite membrane. H2 permeation in semi-dense silica layer deposited on alumina substrate indicated that permeation in top selective layer follows a diffusion mechanism which is based on... 

ABSTRACT: Experimental study of the performance of a gas centrifuge can be appreciably simplified if instead of isotopic mixtures, a binary mixture of gases with large molecular weight difference is used. The current study undertook this approach by injecting a 53%–47% (w/w) mixture of “Freon12-Freon22” into a gas centrifuge. The two parameters, whose investigation was the objective of the current study were: the feed flow rate (F), and the clearance between tail scoop and the rotor wall (d). The results demonstrated that changing the scoop-wall clearance has the most significant effect on the cut (θ), so that by fixing “d”, “θ” becomes nearly invariant. The head separation factor (α)... 

In this study, solvent extraction method has been utilized for separation of molybdenum and vanadium from nitrate solution by utilizing coupling of acid and solvating extractants (D2EHPA and TBP extractants). The outcomes demonstrated that synergistic solvent extraction improves stability of formatted complexes for transfer to the organic phase. The main parameters such as pH value, concentration of extractants, NH4OH concentration as the stripping agent and contact time were optimized at 0.4, 15% (v/v) D2EHPA, 10% (v/v) TBP, 2 M and 30 min, respectively. The maximum separation factor of 24.84 was obtained with a new synergistic mixture of D2EHPA and TBP diluted with kerosene. According to... 

Scanning process usually degrades digital documents due to the contents of the backside of the scanned manuscript. This is often because of the show-through effect, i.e. the backside image that interferes with the main front side picture mainly due to the intrinsic transparency of the paper used for printing or writing. In this paper, we first use one of Non-negative Matrix Factorization (NMF) methods for canceling show-through phenomenon. Then, non-linearity of show-through effect is included by changing the cost function used in this method. Simulation results show that this proposed algorithm can remove show-through effectively  

UF6 gas flow in the total regions of a rotor with the radius of 0.1 m and the length of 1 m in axisymmetric and steady states was simulated using a new hybrid CFD-DSMC method in the OpenFOAM framework. Implicit coupled density-based scheme was performed for CFD method, and Variable Hard Sphere (VHS) and diffuse model were employed in DSMC method. Also, as an initial estimation, the local Knudsen number was applied to determine the interface location between the continuum-rarefied regions (r = 0.0855 m). Then it was modified (r = 0.084 m) to reduce the computational cost. The comparison results of pure CFD and CFD-DSMC methods illustrated that there were large differences between the flow... 

In this research, the separation of tellurium from selenium was studied from chloride solution by TBP extractant. In the batch experiments, the experimental findings indicated that the feed acidity, TBP concentration, and contact time were optimized to achieve the high separation factor. In continuous mode of pulsed disc and doughnut column, the impacts of operating parameters have been discussed on the distribution coefficients of selenium and tellurium, and mass transfer enhancement. A new model for predicting Koca was proposed in terms of holdup values, Sherwood, Reynolds, and Schmidt numbers, which has an acceptable agreement with the mass transfer data. © 2020 Taylor & Francis Group,... 

UF6 gas flow in the total regions of a rotor with the radius of 0.1 m and the length of 1 m in axisymmetric and steady states was simulated using a new hybrid CFD-DSMC method in the OpenFOAM framework. Implicit coupled density-based scheme was performed for CFD method, and Variable Hard Sphere (VHS) and diffuse model were employed in DSMC method. Also, as an initial estimation, the local Knudsen number was applied to determine the interface location between the continuum-rarefied regions (r = 0.0855 m). Then it was modified (r = 0.084 m) to reduce the computational cost. The comparison results of pure CFD and CFD-DSMC methods illustrated that there were large differences between the flow...