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    Localized surface plasmon resonance sensor for simultaneous kinetic determination of peroxyacetic acid and hydrogen peroxide

    , Article Analytica Chimica Acta ; Volume 762 , 2013 , Pages 87-93 ; 00032670 (ISSN) Tashkhourian, J ; Hormozi Nezhad, M. R ; Khodaveisi, J ; Dashti, R ; Sharif University of Technology
    2013
    Abstract
    A new sensor for simultaneous determination of peroxyacetic acid and hydrogen peroxide using silver nanoparticles (Ag-NPs) as a chromogenic reagent is introduced. The silver nanoparticles have the catalytic ability for the decomposition of peroxyacetic acid and hydrogen peroxide; then the decomposition of them induces the degradation of silver nanoparticles. Hence, a remarkable change in the localized surface plasmon resonance absorbance strength could be observed. Spectra-kinetic approach and artificial neural network was applied for the simultaneous determination of peroxyacetic acid and hydrogen peroxide. Linear calibration graphs were obtained in the concentration range of (8.20×10-5 to...