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solid-electrolyte-interphase--sei
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Study of the Surface Effect on the Behavior of a FG Multiphase Nano-sphere with Spherical Anisotropy due to Some Nonuniform Eigenstrain Field
, M.Sc. Thesis Sharif University of Technology ; Mohammadi Shodja, Hossein (Supervisor)
Abstract
The elastic field is one of the challenges in optimizing the lifetime and capacity of the lithiumion batteries. Graphite nanoparticles have been widely used in Li-ion batteries, due to their mechanical, thermal and electrical properties. During the lithiation, chemical reactions occurred in the electrolyte, which forms a solid electrolyte interphase(SEI) in the surrounding of nanoparticles as well as stress fields inside the nanoparticles. Therefore, the purpose of this research is to examine the effects of the surface/interface on diffusion induced stresses(DIS) within core-shell nanosphere due to non-uniform distribution of eigenstrain fields. Due to the mechanical behavior of the phases,...
Study of the Surface Effect on the Behavior of a FG Multiphase Nano-Sphere with Spherical Anisotropy Due to some Nonuniform Eigenstrain Field
, M.Sc. Thesis Sharif University of Technology ; Mohammadi Shodja, Hossein (Supervisor)
Abstract
The elastic field is one of the challenges in optimizing the lifetime and capacity of the lithium-ion batteries. Graphite nanoparticles have been widely used in Li-ion batteries, due to their mechanical, thermal and electrical properties. During the lithiation, chemical reactions occurred in the electrolyte, which forms a solid electrolyte interphase(SEI) in the surrounding of nanoparticles as well as stress fields inside the nanoparticles. Therefore, the purpose of this research is to examine the effects of the surface/interface on diffusion induced stresses(DIS) within core-shell nanosphere due to non-uniform distribution of eigenstrain fields. Due to the mechanical behavior of the phases,...
A novel lifetime prediction method for lithium-ion batteries in the case of stand-alone renewable energy systems
, Article International Journal of Electrical Power and Energy Systems ; Volume 103 , 2018 , Pages 115-126 ; 01420615 (ISSN) ; Dufo López, R ; Roshandel, R ; Bernal Agustin, J. L ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
This paper presents a mathematical formulation of lithium-ion batteries, including aging and temperature effects. The model is developed by integrating the simplified single particle model (SSPM) and reduced-order model (ROM) to predict solid electrolyte interphase growth (SEI). Results show agreement with the experimental data at 25 °C operating temperature and moderate cycling currents. A maximum error of 3.6% in finding the battery discharged Ah is observed in harsh operating conditions, including 60 °C and approaching the end of life of the battery. Due to the typical operating conditions of stand-alone renewable energy systems, more accurate estimations are expected. Finally, this...
Cycling performance of LiFePO4/graphite batteries and their degradation mechanism analysis via electrochemical and microscopic techniques
, Article Ionics ; Volume 28, Issue 1 , 2022 , Pages 213-228 ; 09477047 (ISSN) ; Mosallanejad, B ; Mohammadzad, M ; Hosseini Hosseinabad, S. M ; Ramakrishna, S ; Sharif University of Technology
Springer Science and Business Media Deutschland GmbH
2022
Abstract
In this work, cycling-induced aging occurring in 18650-type LiFePO4/graphite full cells at different C-rates is studied extensively. The mechanism of performance degradation is investigated using a combination of electrochemical and microstructural analyses. Half-cell studies are carried out after dismantling the full cells, using fresh and cycled LiFePO4 cathode and graphite anode to independently study them. The results show that the capacity of LiFePO4 electrodes is significantly recovered. The rate of capacity fading in the discharge state considered as irreversible capacity in the graphite is higher than LiFePO4 half cells, indicating a greater degradation in the performance of this...