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    Effect of TiO2 morphology on in vitro bioactivity of polycaprolactone/TiO2 nanocomposites

    , Article Materials Letters ; Volume 65, Issue 15-16 , 2011 , Pages 2530-2533 ; 0167577X (ISSN) Tamjid, E ; Bagheri, R ; Vossoughi, M ; Simchi, A ; Sharif University of Technology
    Abstract
    TiO2 nanostructures with different morphologies (spherical, tube, leaf-like and flower-like particles) were synthesized via a facile hydrothermal process. Polycaprolactone (PCL)/10 vol.% TiO2 nanocomposites were prepared by solvent casting methods. In vitro bioactivity of the nanocomposite films was examined by immersion in the simulated body fluid (SBF) for up to 28 days. It was found that the morphology of titania nanostructures significantly influence the in vitro bioactivity of PCL/TiO 2 nanocomposites. This observation was attributed to the amount of anatase phase and the specific surface area of the TiO2 nanostructures, which provide high surface exposure to SBF  

    Physicochemical and antibacterial properties of chitosan-polyvinylpyrrolidone films containing self-organized graphene oxide nanolayers

    , Article Journal of Applied Polymer Science ; Volume 133, Issue 11 , 2016 ; 00218995 (ISSN) Mahmoudi, N ; Ostadhossein, F ; Simchi, A ; Sharif University of Technology
    John Wiley and Sons Inc  2016
    Abstract
    Chitosan films have a great potential to be used for wound dressing and food-packaging applications if their physicochemical properties including water vapor permeability, optical transparency, and hydrophilicity are tailored to practical demands. To address these points, in this study, chitosan (CS) was combined with polyvinylpyrrolidone (PVP) and graphene oxide (GO) nanosheets (with a thickness of ∼1 nm and lateral dimensions of few micrometers). Flexible and transparent films with a high antibacterial capacity were prepared by solvent casting methods. By controlling the evaporation rate of the utilized solvent (1 vol % acidic acid in deionized water), self-organization of GO in the... 

    Developing a novel technique for the fabrication of PLA-graphite composite filaments using FDM 3D printing process

    , Article Ceramics International ; Volume 48, Issue 21 , 2022 , Pages 31850-31858 ; 02728842 (ISSN) Mohammadi Zerankeshi, M ; Sayedain, S. S ; Tavangarifard, M ; Alizadeh, R ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Developing a uniform polymer-based composite filament is a critical factor for a successful 3D printing process. In this regard, a novel technique for the fabrication of PLA-graphite filament with the potential to be applied to other PLA-based composite filaments was proposed and compared to the solvent casting method. This modified mixing technique involves partial dissolution of the PLA pellets surface by dichloromethane (DCM), which creates a sticky surface for the strong adhesion of reinforcement powders. The manufactured composite filament by this method exhibited excellent structural features, while the solvent casting method yielded a heterogeneous filament with a non-uniform diameter... 

    Biological evaluation of a novel tissue engineering scaffold of Layered Double Hydroxides (LDHs)

    , Article Key Engineering Materials, 6 November 2011 through 9 November 2011 ; Volume 493-494 , November , 2012 , Pages 902-908 ; 10139826 (ISSN) ; 9783037852552 (ISBN) Fayyazbakhsh, F ; Solati Hashjin, M ; Shokrgozar, M. A ; Bonakdar, S ; Ganji, Y ; Mirjordavi, N ; Ghavimi, S. A ; Khashayar, P ; Sharif University of Technology
    2012
    Abstract
    Bone Tissue Engineering (BTE) composed of three main parts: scaffold, cells and signaling factors. Several materials and composites are suggested as a scaffold for BTE. Biocompatibility is one of the most important property of a BTE scaffold. In this work synthesis of a novel nanocomposite including layered double hydroxides (LDH) and gelatin is carried out and its biological properties were studied. The co-precipitation (pH=11) method was used to prepare the LDH powder, using calcium nitrate, Magesium nitrate and aluminum nitrate salts as starting materials. The resulted precipitates were dried. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron...