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    Property investigation of polypropylene/multiwall carbon nanotube nanocomposites prepared via in situ polymerization

    , Article Polymer International ; Vol. 63, issue. 4 , April , 2014 , pp. 689-694 ; ISSN: 09598103 Jafariesfad, N ; Ramazani, S. A ; Azinfar, B ; Sharif University of Technology
    Abstract
    In this study, polypropylene/carbon nanotube nanocomposites were prepared via in situ polymerization using a bi-supported Ziegler-Natta catalytic system. In this system, magnesium ethoxide and multiwall carbon nanotubes (MWCNTs) are jointly used as catalyst supports. SEM images reveal the distribution and quite good dispersion of MWCNTs throughout the polypropylene (PP) matrix. The thermal properties of the samples were examined using DSC and TGA tests. The results show that the crystallization temperature of the nanocomposites significantly increases while the melting point is not markedly affected. In addition, the thermal stability is improved. The melt rheological properties of PP/MWCNT...