Sharif Digital Repository

In this study, a hydrophilic metal-organic framework (MOF) was applied to improve the performance of a cellulosic membrane for forward osmosis (FO) desalination application. The characterization results confirmed that the MOF particles existed within the matrix of the modified membrane. The MOF loading led to adjustment of the membranes in terms of overall porosity, pore inter-connectivity and hydrophilicity. These features caused an improvement in the pure water permeability (72%) and reduce the structural parameter of the modified membrane to 136 μm. The FO water flux of the modified membrane enhanced by about 180% compared to an unmodified membrane, without decreasing its selectivity. FO... 

In this paper, a periodic structure of different dielectric layers is proposed and investigated for relativistic electron acceleration. The periodic dielectric structure provides an accelerating electric field inside the structure. Results show that the electron beam can experience a strong electric force in one direction during propagation in the structure, leading to the acceleration gradient increasing by more than double in comparison with dual-grating structures. Acceleration gradient enhancement occurs without increasing the electric field much inside the structure; therefore, the maximum achievable acceleration gradient and acceleration factor are increased by more than 100%, reaching... 

Let G be a graph and I be an interval. In this paper, we present bounds for the number mGI of Laplacian eigenvalues in I in terms of structural parameters of G. In particular, we show that mG(n−α(G),n]≤n−α(G) and mG(n−d(G)+3,n]≤n−d(G)−1, where α(G) and d(G) denote the independence number and the diameter of G, respectively. Also, we characterize bipartite graphs that satisfy mG[0,1)=α(G). Further, in the case of triangle-free or quadrangle-free, we prove that mG(n−1,n]≤1. © 2021 Elsevier Inc  

Properties of melt processed polyamide 66 (PA66)/multiwalled carbon nanotube composite were first characterized experimentally. The experimental results exhibited the formation of crystalline layer around the nanotubes and a considerable enhancement in mechanical properties by incorporation of multiwalled carbon nanotube up to 1 wt%. Mechanical properties were analyzed in terms of structural parameters using micromechanical models proposed in this study. It was suggested that the mechanical properties were greatly dominated by crystalline layer and nanotube length. It was also deduced that the melt mixing process caused a significant nanotube breakage restricting further enhancement of... 

The thermal conductivity (λ) of nanoconfined polyamide-6,6 (PA) oligomers in polymer-graphene nanocomposites has been investigated by reverse nonequilibrium molecular dynamics (RNEMD) simulations. The preferential alignment of the PA chains parallel to the graphene plane as well as their elongation implies that λ of the polymer in nanocomposites is larger than that in the neat polymer system. The ordering of the polymer phase is enhanced in an arrangement of charged graphene surfaces made of one layer with a charge deficit and one with a charge excess. The consequence of the enhanced polymer ordering as well as the denser packing is an increase in λ in the polymer network. Differences in the... 

During design, microsatellites are subject to different changes like the changes in weight, location and dimension of parts and elements of subsystems and the payload. These changes should be accumulated by the structure subsystem in a way that some key structural parameters like the center of gravity (CG) and inertia moments remain unchanged. This subject is also important regarding the design of a modular structure of a satellite. In the present study it is tried to accommodate any changes in weight and location of any part(s) and element(s) of a microsatellite by optimum (minimum) rearrangement of other parts on their plane of rest in order to keep the CG and inertia moments unchanged.... 

Cat free fall righting maneuverer has inspired many aerial, space and legged robotic research. Conservation of angular momentum principle is used to derive the inverse differential kinematic and TMT vector form dynamics of the motion for three robotic models: a two-link model, a three-link model with tail, and a comprehensive eight-link model with the addition of legs. The path planning problem in the presence of geometric and kinematic constraints is addressed using a novel singularity free single shooting optimization method. While a 2 DOF torso is sufficient to perform a full maneuver, the addition of the tail reduces the time and increases the maneuverability despite the leg motions that... 

We have applied Rosenbrock's optimization algorithm to obtain the optimized efficiency of a solar cell and its structural parameters. To obtain these parameters, we have developed a computer program for simultaneous optimization and simulation of the solar cell. We have used experimental data on the electrical and optical properties of a-Si1-xCx layers, put them into the written code and obtained the optimized parameters of this solar cell. The maximum efficiency is 6.32% which is close to one experimental result. © 2004 Elsevier B.V. All rights reserved  

The objective of the present study is to predict Young's modulus of polymer-layered silicate nanocomposites (PLSNs) containing fully intercalated structures. The particular contribution of this article is to consider the changes in structural parameters of different intercalated morphologies in vicinity of each other. These parameters include aspect ratio of intercalated stacks, number of silicate layers per stack, d-spacing between the layers, modulus of the gallery phase, and volume fraction of each intercalated morphology. To do this, the effective particle concept has been employed and combined with the Mori-Tanaka micromechanical model. It has been shown that the simultaneous effects of... 

The effect of electrostatic field on the aggregation rate and aggregate size of asphaltene particles precipitated from three different crude oil samples suspended in a mixture of toluene and n-heptane (a model oil) was investigated. An electrode-embedded glass micro-model utilizing a high-voltage direct current power supply was utilized in this study. The asphaltene particle size and the rate of aggregation under the electric field were monitored using a high-resolution optical microscope and the average aggregate size for asphaltene particles was estimated using image processing software. To investigate the effects of structural parameters on asphaltene aggregation rate, aggregate size and... 

Polymer-layered silicate nanocomposites have been observed to demonstrate enhanced mechanical properties particularly at low weight fractions of silicate. Experimental and theoretical investigations reveal that numerous structural parameters strongly influence the modulus of such nanocomposites. A multiscale micromechanical model is developed which considers a wide range of different affecting parameters including the particle aspect ratio, the number of silicate layers per stack, the d-spacing ratio between the layers, the penetration of polymer chains along silicate sheets, the intercalation feature, and the particle volume fraction. The developed model illustrates the accuracy and... 

Ni II-(N,N′-bis(2,4-dihydroxyacetophenone)-2, 2-dimethylpropandiimine (Ni II{salnptn(4-OH) 2}) complex has been encapsulated within the supercage of zeolite-NaY by reacting Ni 2+-exchanged NaY with the flexible Schiff-base ligand that diffuses into the cavities. The encapsulated complex is characterized by EDX, scanning electron microscopy, powder X-ray diffraction, FT-IR, and cyclic voltammetry studies. Density functional calculation is being carried out on both the free nickel Schiff-base complex and that encapsulated in NaY zeolite to investigate changes in structural parameters, energies of the HOMO and LUMO, and absolute hardness and softness. Electrochemical properties of the NaY... 

Thermal conductivity, thermal dispersion, and structural effects in resin transfer molding (RTM) process are studied numerically. The injection part of the RTM process is modeled as a transport of resin flow through a fibrous porous medium in a long rectangular channel. The fluid flow is modeled using the Darcy-Brinkman-Forchheimer model and the heat transfer process using the energy equation based on local thermal equilibrium assumption. Both isotropic and anisotropic heat transfer in porous media are investigated. The governing equations are solved numerically for the isotropic heat transfer case and analytically for the anisotropic case. The numerical results are fitted to the available... 

Co-Ce doped Ni nanocrystalline ferrites having composition Ni0.8Ce0.2CoxFe2-xO4 with x = 0.00, 0.25, 0.50, 0.75, 1.00 were fabricated by sol gel auto combustion method. Synthesized samples were investigated by thermal gravimetric and differential thermal analysis (TGA-DTA), Fourier transform infrared spectroscopy (FTIR), x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis (EDX) and vibrating sample magnetometer (VSM) to study the phase, vibrational modes, structure, surface analysis and magnetic properties respectively. Structural parameters (lattice parameters, cell volume, crystallite size and micro strains) were also calculated from XRD recorded data.... 

A new robust AQM strategy for dynamically varying TCP/AQM networks is proposed and its performance is investigated through computer simulations in MATLAB and ns-2 environments. The developed AQM is designed based on coefficient diagram method (CDM), which is a new indirect pole placement method that considers the speed, stability and robustness of the closed loop system in terms of time domain specifications. Simulation results indicate that the new method (CDM-AQM) performs very well for network variations both in topology and traffic. Besides, a new adaptive controller based on CDM as an AQM method is introduced. In the developed adaptive AQM (ACDM), the output feedback pole placement is...