Sharif Digital Repository

The purpose of this research is producing one phase silica superhydrophobic coating by sol-gel method and drying temperature less than 200 degrees. For preparing micrometer and nanometer scaled hierarchical structure based on silica, TEOS precursor and Fumed Silica nanoparticles were used by density of 43/30 cc/lit and 6/52 gr/lit in order to provide desired roughness in the range of 40 nm. Moreover, HMDS surface modifying agent was used for reducing the surface energy of coating, which is not a danger to the environment in comparison to the same substances. The best Contact Angle is 155 degree and the best Sliding Angle is less than 5 degree. For instance, it was created with the... 

Through history, increased energy consumption has been encouraged researchers to improve the performance of energy-using devices. Some researchers believe that hydrophobic surfaces can play an important role in this regard.The encounter and the presence of water on different surfaces can have different effects on them. The surface sedimentation of these surfaces, the eating of metal surfaces, the drag force (water friction) due to water collision with the moving object in water and the attachment of algae And other marine organisms to the surfaces, including the limitations and problems faced by professionals and staff associated with this sector.In the present study, the drag reduction of... 

Today, with rapid developments and advances in science and technology, different ways have been studied to reduce energy consumption in various industries. Reducing the drag force and thus reducing the friction force is one of these methods which has many applications (e. g, in submarine construction industries). Creating some microgrooves in the microchannels is one of the most effective methods in order to reduce the friction force in microchannels that has recently been studied. In this method the air is trapped within the microgrooves and when the fluid (e. g, water) enters the channel passes over the trapped air within these microgrooves instead of touching the channel walls (solid... 

Although using solar energies have some limitations, such as low efficiency, require a large space and high starting cost, they are one of the most attractive source of energies. The reasons that cause efficiency of the solar panels decrease are contamination of dust particles on them and formation of water droplet on solar panel surface due to humidity of the air. Also, a solar panel can absorb only 25% of incident light and the others are reflected by the cover glass. Therefore, fabrication of a self-cleaning surface that can inhibit the aggregation of dust particles and also transparent that doesn’t reflect the incident light is crucial.In this work, we aim to obtain a transparent,... 

Ice formation upon various surfaces could lead to many industry problems and result in unpleasant accidents. For instance, the formation of ice on wind turbine blades or airplanes/helicopter wings could cause catastrophic disasters. The methods used to address this problem usually require exogenous energy consumption or anti-ice ingredients. The energy or anti-ice ingredients usage has adverse environmental effects and should be replaced with better approaches. One of these approaches is utilizing modified anti-ice surfaces. In this method, by modifying surface features, such as physical asperities and surface energy, the icing time of the surface could be prolonged. These surfaces are... 

Superhydrophobic surfaces have attracted so mucha attenetions in recent years. High contact angle, Low adhesion and low friction drag are the most important features of these surfaces. Two main parameters of these surfaces are hydrophobicity and micro-( or nano) scale roughness. In this Project a 2-D simulation of flow on superhydrophobic surfaces have been considered. Shan-Chen multiphase Lattice Boltzmann Model has been used for the simulation and carnahan-starling equation of state have been used or a higher density ratio. In the first step flow in a channel with smooth walls with different hydrophobicity have been simulated and effects of hydrophobicity on pressure drop have been... 

The increasing demand of energy and energy consumption, urged researchers of different fields of science to investigate different aspects of energy efficiency methods. One way of optimization of energy consumption is to reduce drag force in moving objects in fluids. Changing the geometry of objects, bubble injection, air suction and blowing on surface, using nano fluid and superhydrophobic surface are just a number of drag reduction methods. Among the mentioned methods, using superhydrophobic surface due to its simplicity, low cost and no need to change in geometry of vehicles attracted attentions of researchers of all over the world. These surfaces with micro/nano roughness combined with... 

Nowdays, one of the most important concerns for scientists is increasing CO2 emmisions and global warming. To overcome this problem, a large number of studies have been carried out to improve energy system performance and reducing the overall energy consumption. One solution to this problem is using the superhydrophobic surfaces with contact angle larger than 150°.In this study, we try to reduce the pressure drop through the galvanized pipes. So, by reducing the pressure drop, power required for pumps can be reduced. To this end, two different coatings by silica nano-particles which were modified with first hydrophobic agent are used. In first coating which is named as PS coating, stearic... 

This thesis is a research corresponding to Super-Hydrophobic condensation substrates with Nanometer texture. In this study, the foresaid surfaces are fabricated by two methods that are Nano-composite paint and Electrophoretic coating. As a summary for the first method (the Super-Hydrophobic Nano-composite paint), the hybrid coating contains two mineral and organic phases; The organic phase is a two-part clear-coat polyurethane and plays the role as a polymer matrix in Nano-composite structure. Silica Nano-particles are the mineral phase and the two phases of Nano-composite have made connection with silane compounds. Also, surface-modification in Nano-particles for giving hydrophobicity... 

Rehabilitation usually involves physical therapy, occupational therapy and counseling for the patient's morale to help to restore his power and performance. Considering the economic outlook and the costs of rehabilitation methods and due to the increasing prevalence of stroke and the need to recover the patients in a short period, only the use of robotic systems opens the door to the medical community. Since a large rehabilitation robots designed and built and each been used according to their advantages and shortcomings. In this project, the major shortcomings examined and exoskeleton designed on two major features including portability and covering shoulder workspace. Shoulder movement was... 

In this research we developed a superhydrophobic and anti-wear coating on a glass substrate using SiO2 nanoparticles to form a transparent superhydrophobic thin film and SiC nanoparticles to improve the wear resistance of coating.
Silica nanoparticles were produced via a simple sol gel method from Tetraethylorthosilicate (TEOS) as precursor. Hexamethyldisilazane (HMDS) and Tetramethylclourosilane (TMCS) were used as hydrophobic inducing agents and at last SiC nanoparticles were dispersed in the solution in order to provide wear resistance. The final results indicate the contact angle (CA) of water droplet on the surface was about 158° and sliding angle (SA) lower than 9°. Studying the... 

Phase change processes have been used in heat transfer industries for decades. However, the heat transfer rate enhancement of the surfaces is still a challenging issue for the researchers. In this path, emerging nanostructured surfaces have shown great potentials. We demonstrate that using nanostructured surfaces in the condensation processes enhances the heat transfer behaviour of the fluid through interfacial contact area increase. In the present study molecular dynamics simulation have been employed to monitor the atomic behaviour of the system components at nanoscale. The argon liquid is considered as the working fluid and the copper surfaces as the phase change site. The effect of... 

Due to their unique characteristics, such as drag reduction, anti-fouling, and enhancing condensation, hydrophobic and superhydrophobic surfaces have attracted a lot of attention in the past decades. Since approximately 4% of the fossil fuel usage and 14-19% of the air pollution (including greenhouse gases, sulfur, and so forth) are attributed to naval activities, and the dominant form of drag on vessels is friction, drag reduction will not only reduce the cost and usage of fossil fuels, but it will also have numerous environmental benefits  

The main objective of this project was to create some coatings with different wettability properties of water and oil on the 304 stainless steel mesh In order to achieve phase separation. With the aim of creating a hydrophilic property, Various resin such as SILRES BS29, PDDA PDMS-OH, PDMS-NH2 was used individually or mixed. Furthermore, silica and TiO2 nanoparticles were used to make surface roughness. Perfluorooctanoic acid with 15 fluorine atoms in its molecular structure were added to solution to create the effect of superoleophobic. The contact angle and the slip angle measurements tests were performed. morphology and structure of nanocomposite coating study by FESEM microscopy and... 

Increasing energy consumption and limited energy resources are instances of the concerns of human societies and environmentalists today. The condensation process, as one of the most important processes in the industry, plays an important role in saving and regeneration the existing energy. Nowdays, surface optimization is one of the modern ways to improve condensation.In this research, two methods have been used to construct surfaces useful for enhancement of droplet condensation, including hybrid surfaces and solid infused surfaces. In the construction of hybrid surfaces, superhydrophobic coating with silica nanoparticles based on hydroxyl acrylic resin was used. The superhydrophilic parts... 

When the fluid passes through the microchannel, some energy is lost due to drag force and pressure drop. One of the methods used in the last few decades to optimize energy consumption is creating superhydrophobic surfaces in microchannels. These surfaces, with their features such as increasing the contact angle and reducing the contact angle hysteresis, can reduce energy loss, which is due to the presence of unevenness on the surface, and by trapping air and creating a two-phase flow, they reduce the drag force. On the other hand, the air trapped inside these irregularities will also affect the heat transfer of the passing fluid in the microchannel, which by creating resistance in the... 

In this project, melamine formaldehyde was chosen as initial substrate for its high porosity. Then for having superhydrophobic surface, surface functional groups were silanized and deactivated as a result. It was assumed that high porosity of prepared sorbent and its nonpolar nature, can increase extraction efficiency. To study extraction efficiency of the prepared sorbent, it was filled inside a needle and used for needle-trap head-space extraction of BTEX (abbreviation for Benzene, Toluene, Ethylbenzene and Xylenes). Needle packed with sorbent was held on headspace of sample containing BTEX and head- space was pumped with a peristaltic pump. Pumping introduces fresh sample to sorbent... 

This dissertation argues that bi-conductive textured surfaces increase both Critical Heat Flux (CHF) and Heat Transfer Coefficient (HTC) simultaneously. Surface modification is applied to stainless steel specimens by the anodizing method in an electrolyte containing Ammonium Fluoride and DI-Water and Ethylene Glycol as the based solvent. The process of oxidation was under constant DC voltage and constant temperature. The contact angle on self-aligned Nano-porous oxide layer fabricated on the substrate substantially decreases to about 5.7 degree which has a dramatic effect on CHF. Furthermore, the oxide layer augments the boiling efficiency by increasing the number of active sites and... 

Condensation is one of the main processes in environment and engineering systems, including thermal power plants, desalination systems and air conditioners. Thus, improvement of its performance can lead to decrease of energy consumption and the resulting air pollutions. Recently, using nanotechnology and new coating methods, there have been great researches on stable superhydrophobic surfaces and using theme as condensing surfaces which because of jumping droplet phenomena can increase condensation performance. Because of the great influence of wetting and structure properties of surfaces on condensation, in this study nucleation and growth of condensing droplets on smooth and structured... 

Many researches have been made on super hydrophobic and photocatalyst nano coatings in the last decades as a solution to some environmental issues. Among all semiconductors chosen for this property, titanium dioxide is often used because of it's low cost, ease of accessibility and stability in different chemical circumstances to break up organic pollutions. Mixing this property of TiO2 with hydrophobic manner of SiO2 causes a superhydrophobe & photocatalyst nano coating. Doping TiO2 with another semiconductor may also improve photocatalytic behavior of coating by increasing surface area of reaction or decreasing the band-gap.In this research TiO2-SiO2 hybrid nano coating is made via...