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    Studies on the catalyst preparation methods and kinetic behavior of supported cobalt catalysts for the complete oxidation of cyclohexane

    , Article Reaction Kinetics, Mechanisms and Catalysis ; Volume 114, Issue 2 , Jan , 2015 , Pages 611-628 ; 18785190 (ISSN) Zabihi, M ; Khorasheh, F ; Shayegan, J ; Sharif University of Technology
    Springer Netherlands  2015
    Abstract
    Low cost dispersed supported cobalt oxide nanocatalysts on activated carbon (AC) were prepared by two different methods: (1) combined impregnation and deposition–precipitation (IMP-DP) and (2) heterogeneous deposition–precipitation (HDP). XRD, TEM, FESEM, BET and Boehm techniques were used for the characterization of the support and the catalysts. Characterization analyses indicated the negative effect of the wet impregnation method on the IMP-DP technique for the preparation of catalysts for the total oxidation of cyclohexane in air. The catalysts prepared by HDP and IMP-DP methods were found to have significant differences in oxidation activity, morphology, particle size, and shape of...