Search for: supramolecular-assemblies
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    Supramolecular assembly through intermolecular n → π∗ interactions through a coordinated perrhenate formed: Via superoxidation of Re(i) to Re(vii) in the formation of substituted Re(CO)3complexes bearing Diimine ligands

    , Article CrystEngComm ; Volume 22, Issue 39 , September , 2020 , Pages 6448-6452 Kia, R ; Taghavi, T ; Raithby, P. R ; Sharif University of Technology
    Royal Society of Chemistry  2020
    We report the structural, spectroscopic, and computational studies of two new Re(i) tricarbonyl complexes bearing 2,3,6,7-tetraphenyl-1,4,5,8-tetraazaphenanthrene (Ph4TAP) and 4,5-diazafluoren-9-one (dafone) having a coordinated perrhenate group obtained via in situ superoxidation of Re(i) to Re(vii); intramolecular and intermolecular n → π∗ interactions are dominant and stabilize the molecular geometry and crystal packing. This journal is © The Royal Society of Chemistry  

    Visual recognition of tryptophan enantiomers using chiral self assemblies of quantum dots

    , Article ACS Applied Nano Materials ; 2021 ; 25740970 (ISSN) Fahimi Kashani, N ; Jafar Nezhad Ivrigh, Z ; Bigdeli, A ; Hormozi Nezhad, M.R ; Sharif University of Technology
    American Chemical Society  2021
    Discrimination of chiral targets is generally achieved with chiral nanomaterials. However, the limited number of intrinsic chiral nanostructures as well as their complex synthesis procedure has led to the production of chirality-induced nanomaterials as alternatives. Chirality can be induced in nanomaterials by either chirality transfer or the formation of chiral assemblies. Using the latter approach, in this work, we have provided chiral supramolecular assemblies of CdTe quantum dots (QDs) from achiral starting materials. CTAB-QD assemblies showed chiroptical activities, and their orange emission in combination with the blue emission of carbon dots was utilized as a ratiometric chiral...