Sharif Digital Repository

Nanoemulsion is a novel type of emulsified solutions holding great promises for utilizing in industrial applications. Although microemulsions have been the subject of numerous studies in past decades, however, nanoemulsions are quite virgin and merit detailed investigation to scrutinize their characteristics specific to reservoir engineering, in particular, Enhanced Oil Recovery (EOR). To this end, the present study is an attempt to evaluate the effectiveness of a specific nanoemulsion for oil displacement through porous media. In this regard, flooding experiments were designed and Hexa decyl trimethylammonium bromide (CTAB), which is a cationic surfactant, was used as the emulsifying agent.... 

Densities and viscosities of aqueous solutions containing sulfolane and ternary aqueous solutions of sulfolane and triethanolamine and ternary aqueous solutions containing sulfolane and disopropanolamine and also equilibrium surface tensions of the above ternary aqueous solutions were measured at temperatures ranging from (303.15 to 343.15) K and atmospheric pressure. The overall concentration of sulfolane, triethanolamine, and diisopropanolamine in solutions varied in the range of 0 to 16.5, 0 to 43, and 0 to 40 mass percent, respectively. Using the density, viscosity, and surface tension of pure water as the solvent, the corresponding experimental values obtained for the investigated... 

In this paper the density and temperature dependencies of surface tension are investigated. Using the Lennard-Jones (12,6), as an effective pair interaction potential, a linear expression is derived for isotherms of γ /ρ 2 versus ρ 2 for some normal and ChloroFluoroCarbons (CFCs) fluids, where is surface tension and ρ = 1/v is molar density. The linearity behavior of the derived equation is well fitted onto the experimental data of surface tension for monatomic, diatomic, nonpolar, polar, hydrogen-bonded and chlorofluorocarbons. In addition, the temperature dependence of surface tension for 20 different fluids is examined, in which the contributions of both terms of the average effective... 

This paper deals with numerical modeling of two-phase liquid jet breakup using the smoothed particle hydrodynamics (SPH) method. Simulation of multiphase flows involving fluids with a high-density ratio causes large pressure gradients at the interface and subsequently divergence of numerical solutions. A modified procedure extended by Monaghan and Rafiee is employed to stabilize the sharp interface between the fluids. Various test cases such as Rayleigh-Taylor instability, two-phase still water and air bubble rising in water have been conducted, by which the capability of accurately capturing the physics of multiphase flows is verified. The results of these simulations are in a good... 

The current study was undertaken to compare four analytical methods including drop collapse, oil spreading, surface tension (SFT) measurements, and blood agar lysis tests for detection of biosurfactant-producing bacteria. Among 32 biosurfactant-producing bacteria isolated from Ahvaz oil fields, in south of Iran, 16 isolates (50%) exhibited highest biosurfactant production. Eleven isolates (MASH.1 to MASH.11) demonstrated a reduction in surface tension from 65 mN/m to less than 41 mN/m. The results showed that about 91% of these highly biosurfactant producers had the same response levels of "++++" and "+++" in the case of both SFT and oil spreading methods. Among these, seven isolates had the... 

Surface tension driven passive micro-pumping relies mainly on the surface tension properties. To have control over surface tension driven passive micro-pumps (STD-PMPs), it is essential to understand the physical background of the fluid flow in these pumps. Hence, the purpose of this work is to give an exploration of the flow physics of a STD-PMP. In this regard, computer simulation is used to give detailed information about the flow pattern and physical phenomena at different conditions. To this end, a droplet of water, with a specified diameter, is placed onto an entry port connected to another droplet at the exit port via a microchannel. The results indicate that the pumping process, in... 

Multiphase problems with high density ratios and complex interfaces deal with numerical instabilities and require accurate considerations for capturing the multiphase interfaces. An Incompressible Smoothed Particle Hydrodynamics (ISPH) scheme is presented to simulate such problems. In order to keep the present scheme simple and stable, well-established formulations are used for discretizing the spatial derivatives and a repulsive force is applied at the multiphase interface between particles of different fluids to maintain the interface sharpness. Special considerations are included to overcome the difficulties to model severe physical discontinuities at the interface and surface tension... 

The formation of liquid bridges can maintain capillary continuity between matrix blocks during gas/oil gravity drainage in fractured reservoirs. A travelling oil drop draining into a fracture either forms a liquid bridge or breaks into detached drops. However, the different characteristics of a travelling drop during its elongation and required conditions for transformation into a liquid bridge are not well described in the published literature. In this work, a one-dimensional model based on slender-drop theory is employed that holds gravity, viscosity, and surface tension forces but ignores inertia. This model, together with Young-Laplace equation, gives the fracture capillary pressure.... 

Water impact phenomenon in the case of a circular cylinder is an important issue in offshore industry where cross members may be in the splash zone of the incident wave. An analytical method as well as a numerical solution are employed to study the water entry problem of a circular section. The procedure for derivation of the analytical formulas is demonstrated step by step. The volume of fluid (VOF) simulation of the water entry problem is also performed to offer comparison of the results of the linearized analytical solution with a fully nonlinear and viscous fluid flow solution. To achieve this, the FLOW- 3D code is utilized. Some consideration has also been given to the points of... 

A model based on the perturbation theory of fluids was proposed to correlate the experimental data for surface tension of pure hydrocarbons in a wide range of temperature. The results obtained for the pure hydrocarbons were directly used to predict the surface tension for binary hydrocarbon mixtures at various temperatures. In the proposed model, a modified form of the square well potential energy between the molecules of the reference fluid was taken into account while the Lennard-Jones dispersion energy was considered to be dominant amongst the molecules as the perturbed term to the reference part of the model. In general, the proposed model has three adjustable parameters which are chain... 

Profile analysis tensiometry (PAT) is presently the most frequently used technique for measuring surface tensions of liquids. The basis of this methodology is however an equilibrium force balance as given by the Gauss-Laplace equation. Therefore, its application under dynamic conditions, i.e. for growing drops or bubbles, is questionable. We discuss the limits of the applicability of PAT under dynamic conditions by using a growing drop configuration equipped with a high speed video camera. The systems studied are the water/air and water/hexane interface. The obtained "dynamic" drop profiles are analyzed by fitting the classical Gauss-Laplace equation. The results are additionally compared... 

The adsorption of proteins at liquid interfaces happens at rather low bulk concentrations due to their rather high surface activity. In contrast typical surfactants start to decrease the surface tension at bulk concentration in the range of mmol/l and reach a minimum value at about two or three orders of magnitude higher concentration. The two proteins studied here, β-lactoglobulin and β-casein, adsorb already remarkably at much lower concentrations, i.e. less than 1. μmol/l. When smallest amounts of a non-ionic surfactant are added to low concentrated protein solutions, changes in the surface tension are observed which cannot be explained by the existing theoretical models. An agreement...