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    Preparation and Properties of Zinc Sulfide Nanoparticles Doped with Manganese

    , M.Sc. Thesis Sharif University of Technology Raeesi, Padideh (Author) ; Mohammadi Boghaei, Davar (Supervisor)
    Abstract
    The optical properties of semiconductor nanoparticles are dependent on their size. Then, the important problem in synthesized semiconductor nanoparticles is controllable of their size. In this research ZnS nanoparticles were synthesized by hydrothermal method and taguchi design of experiments and study on effect of solvent, reaction temperature and molar precursor ratio on band gap and particle size of ZnS . The UV-Vis spectrum was carried out for measurement of band gap and the size of nanoparticles by using the effective mass approximation. The X-ray diffraction patterns exhibited a cubic zinc blende structure for the nanoparticles. The ZnS:Mn +2 nanoparticles werw synthesized. With... 

    Grit blasting of Ti-6Al-4V alloy: Optimization and its effect on adhesion strength of plasma-sprayed hydroxyapatite coatings

    , Article Journal of Materials Processing Technology ; Volume 194, Issue 1-3 , 2007 , Pages 15-23 ; 09240136 (ISSN) Mohammadi, Z ; Ziaei Moayyed, A. A ; Mesgar, A. S. M ; Sharif University of Technology
    Elsevier BV  2007
    Abstract
    The effect of grit blasting parameters on the surface roughness of Ti-6Al-4V alloy as the substrate for plasma-sprayed hydroxyapatite (HA) coatings was examined using the factorial and Taguchi designs of experiments. In this study, two grit materials (Al2O3 and SiO2) each at two sizes, and two types of blasting systems (pressure and suction) were used. An equivalent surface roughness of 3.51 μm was obtained in three optimum conditions. The results of the Taguchi designed experiments were analyzed using signal to noise ratio. The tensile bonding strength of HA coatings deposited on the roughened substrates at the three different optimum conditions was measured by the standard adhesion test... 

    Electrophoretic deposition of chitosan/45S5 Bioglass® composite coatings for orthopaedic applications

    , Article Surface and Coatings Technology ; Volume 205, Issue 23-24 , 2011 , Pages 5260-5268 ; 02578972 (ISSN) Pishbin, F ; Simchi, A ; Ryan, M. P ; Boccaccini, A. R ; Sharif University of Technology
    2011
    Abstract
    This article presents experimental results on the electrophoretic deposition (EPD) of bioresorbable chitosan/45S5 Bioglass® composite coatings for orthopaedic implants based on the Taguchi design of experiments (DOE) approach. The influence of EPD parameters including Bioglass® concentration, electric voltage and deposition time on deposition yield was studied by an orthogonal Taguchi array of L18 type. Multivariate analysis of variance (MANOVA) and regression analysis based on the partial least-square method were used to identify the significant factors affecting the deposition yield and its stability during constant-voltage EPD. The coatings were characterised by high resolution scanning... 

    Experimental investigation of operating conditions for preparation of PVA-PEG blend membranes using supercritical CO2

    , Article Journal of Supercritical Fluids ; Vol. 95 , November , 2014 , pp. 603-609 ; ISSN: 08968446 Taji, S ; Nejad-Sadeghi, M ; Goodarznia, I ; Sharif University of Technology
    Abstract
    Poly(vinyl alcohol)-polyethylene glycol, PVA-PEG, blended membrane were prepared using supercritical fluid assisted phase-inversion method, in which scCO2 was used as the anti-solvent. Poly(vinyl alcohol) was utilized as the main polymer, polyethylene glycol as the additive, and dimethyl sulfoxide (DMSO) as the solvent of these polymers. Taguchi method was used to investigate the effect of some operating parameters on the morphology of the membranes. The L16 orthogonal array was selected under the following conditions: pressure (100, 135, 165 and 200 bar), temperature (40, 45, 50 and 55°C) and PEG weight percent (0, 0.33, 0.66, and 1%). Total polymer concentration of solutions in all... 

    A study of the electrophoretic deposition of Bioglass® suspensions using the Taguchi experimental design approach

    , Article Journal of the European Ceramic Society ; Volume 30, Issue 14 , October , 2010 , Pages 2963-2970 ; 09552219 (ISSN) Pishbin, F ; Simchi, A ; Ryan, M. P ; Boccaccini, A. R ; Sharif University of Technology
    2010
    Abstract
    This paper presents a study of the Taguchi design method to optimise the rate of electrophoretic deposition (EPD) of Bioglass® particles from aqueous suspensions. The effect of Bioglass® concentration, pH and electric field was investigated. An orthogonal array of L16 type with mixed levels of the control factors was utilized. Multivariate analysis of variance (MANOVA) and regression analysis based on the partial least-square method were used to identify the significant factors affecting the deposition rate and its stability during constant-voltage EPD. It was found that the pH of the suspension significantly influences the deposition rate whereas the applied electric field has the smallest... 

    Optimization of supercritical carbon dioxide extraction of essential oil from Dracocephalum kotschyi Boiss: An endangered medicinal plant in Iran

    , Article Journal of Chromatography A ; Volume 1422 , 2015 , Pages 73-81 ; 00219673 (ISSN) Nejad Sadeghi, M ; Taji, S ; Goodarznia, I ; Sharif University of Technology
    Elsevier  2015
    Abstract
    Extraction of the essential oil from a medicinal plant called Dracocephalum kotschyi Boiss was performed by green technology of supercritical carbon dioxide (SC-CO2) extraction. A Taguchi orthogonal array design with an OA16 (45) matrix was used to evaluate the effects of five extraction variables: pressure of 150-310bar, temperature of 40-60°C, average particle size of 250-1000μm, CO2 flow rate of 2-10ml/s and dynamic extraction time of 30-100min. The optimal conditions to obtain the maximum extraction yield were at 240bar, 60°C, 500μm, 10ml/s and 100min. The extraction yield under the above conditions was 2.72% (w/w) which is more than two times the maximum extraction yield that has been...