Sharif Digital Repository

Interfacial tension is one of the very important parameters in pharmacology science, chemical engineering and petroleum engineering. The interfacial tension between pure hydrocarbons and water is widely used in chemical and petroleum engineering and so that it is highly desirable to find its accurate values. In this study a new unique correlation has been developed based on a comprehensive database of pure hydrocarbons-water interfacial tension values which contained both aliphatic and aromatic compounds (32 different hydrocarbons) with pressure ranges of 0.1-300 MPa and temperature ranges of 252.44-550 K. The proposed correlation uses the density difference between pure hydrocarbon and... 

The solution for the Duffing equation in a nonlinear vibration problem is studied in this paper. Clearly, in the case of the perturb parameter being a larger value, the traditional perturbation method is no longer valid but the Homotopy Perturbation Method (HPM) is applicable usually. HPM is used to solve the weak and strong nonlinear differential equations for finding the perturbed frequency of the response. The obtained frequencies via HPM and the approximate method have good accordance for weak and strong nonlinear differential equations. Additionally, the calculated responses by use of the approximate method are compared with the responses obtained from the Numerical method in the time... 

Nanoemulsion is a novel type of emulsified solutions holding great promises for utilizing in industrial applications. Although microemulsions have been the subject of numerous studies in past decades, however, nanoemulsions are quite virgin and merit detailed investigation to scrutinize their characteristics specific to reservoir engineering, in particular, Enhanced Oil Recovery (EOR). To this end, the present study is an attempt to evaluate the effectiveness of a specific nanoemulsion for oil displacement through porous media. In this regard, flooding experiments were designed and Hexa decyl trimethylammonium bromide (CTAB), which is a cationic surfactant, was used as the emulsifying agent.... 

While studying the operation of a rectangular bubble column in laboratory scale, it was observed that under certain circumstances tiny bubbles attach to larger bubbles without causing them to coalesce. In other words, bubbles with large diameters (d > 5 mm) swept tiny bubbles (d < 1 mm) in their way to the top of the column resulting in grapelike clusters of bubbles. This phenomenon was named "bubble bunch" by us and its effect on total gas holdup and interfacial area was discussed. Although it was found to have almost no affect on gas holdup, bubble bunch can increase the interfacial area up to 10% more than what is anticipated in the literature. The process of film thinning was modeled for... 

Molecular dynamics (MD) simulation was utilized to study the role of asphaltene extracted from Gachsaran (an Iranian oilfield) at the synthetic oil-water interface. In agreement with experimental data, IFTs predicted by MD simulation for heptol/brine system showed a minima at around 50 vol.% n-heptane, reflecting the highest contribution of asphaltene into the interface. At greater n-heptane fractions, IFT was increased steadily. Simulation results suggest the asphaltene propensity for remaining in the bulk heptol phase rather related to the fraction of toluene in the mixture. Heptol ingredients, i.e., toluene and heptane, act differently with respect to asphaltene, where former tends to... 

We investigated the effect of loading rate on tensile properties of sheep bone-anulus-bone specimens in axial direction. Disc anulus Samples with adjacent bone attachments were prepared from lateral, posterior and anterior regions of sheep lumbar spinal segments. The specimens were then tested at different strain rates under non-destructive cyclic tensile loading followed by destructive tensile loading. Each specimen was prepared by embedding the bony parts in the polymethylmetacrylate (PMMA) exposing the anulus portion to support tension. The results of non-destructive cyclic tests indicated a decrease in the hysteresis energy loss as strain rate increased. In the destructive tests, no... 

Summary Conventional design methods do not ensure that the desired collapse mechanism is developed at target displacement. In this paper, a case study is presented to analyze concentrically braced frames with steel shear panel (CBFSP). Also, extensive investigation in the failure modes are made, to have the global yielding mode at the final state. For this purpose, each of one-story, three-story, six-story and nine-story CBFSP models were decomposed into three parts where the members' closed-form equations of internal forces were identified and superimposed. On the basis of the kinematic theorem of plastic collapse, the possible mechanisms and the related energy equations were defined to... 

Studies on corrugated steel shear walls (CSSWs) generally indicate noticeable increase of energy absorption, as well as increasing shear buckling capacity of corrugated plates being more likely rather than the flat plates. In this paper, the effect of variation in the angle of trapezoidal plate on the behavior of CSSWs has extensively been investigated. Three specimens of CSSW with 1 story and single bay in half scale are tested under cyclic load. The observations of experiment do indicate that stress concentration has been increased in the corner of subpanels, by increasing of the corrugation angle. Development of the tensile field and wall yield and damage depends on the geometry of the... 

Crude oil reservoirs have different temperatures, compositions, and pressures, therefore oil recovery performance by CO2 injection varies from one case to another. Furthermore, it is predicted that lower interfacial tension between injected CO2 and reservoir fluid results in more oil recovery. In this study, we investigate the effect of temperature on the equilibrium interfacial tension between CO2 and three different oil fluids at different pressures. Also minimum miscible pressure (MMP) is measured by the vanishing interfacial tension (VIT) technique to determine the temperature effect on the CO2 miscible gas injection. The results on different pure and mixtures of hydrocarbon fluids show... 

Densities and viscosities of aqueous solutions containing sulfolane and ternary aqueous solutions of sulfolane and triethanolamine and ternary aqueous solutions containing sulfolane and disopropanolamine and also equilibrium surface tensions of the above ternary aqueous solutions were measured at temperatures ranging from (303.15 to 343.15) K and atmospheric pressure. The overall concentration of sulfolane, triethanolamine, and diisopropanolamine in solutions varied in the range of 0 to 16.5, 0 to 43, and 0 to 40 mass percent, respectively. Using the density, viscosity, and surface tension of pure water as the solvent, the corresponding experimental values obtained for the investigated... 

This paper attempts to describe the fatigue response of a foam the core sandwich composite with unsymmetrical carbon/glass face sheets under tension-tension cyclic loading. The laminate is a critical element of the structure of a light full composite airplane which was determined through the stress analyses for numerous load cases. The face sheets, over a PVC foam the core, consist of two similar woven E-glass fibers following unidirectional carbon fibers with epoxy resin. Extensive fatigue data were generated for the S-N diagram of this laminate. Based on the static FEM analyses, two designs for the configuration of foam to solid laminate bonding zone have been investigated. Hence, the... 

A new shear strengthening method involving post-tensioning of the critical shear region of reinforced concrete beams is investigated. Thirty-one experiments were carried out using 24 specimens. Theoretical load-deflection relations are obtained from moment-curvature analysis using fiber cross sections and taking into consideration the effects of different concrete confinements along the beam length. A theoretical shear strength model that includes three shear resisting components in the critical shear region of the strengthened beams is provided. Experimental results from beams with and without shear strengthening are compared with calculated load-deflection relations and predicted shear... 

In this research purely oscillation fluid flow in two microtubes 150 and 250 μM(3.5 mm length) is studied using computational fluid dynamic (CFD) approach and utilizing a new experimental setup developed for dynamic interfacial tension measurement (capillary pressure technique) in the frequency range between 0.2 and 80 Hz. The experiments are done with pure water at a mean temperature of about 25 °C. The results of oscillatory conditions for microtubes of 0.5 mm in diameter have been compared with experimental results for several frequencies. The computational approach was validated by comparison with experimental data of the continuous constant flow through microtubes and also with... 

In this paper the density and temperature dependencies of surface tension are investigated. Using the Lennard-Jones (12,6), as an effective pair interaction potential, a linear expression is derived for isotherms of γ /ρ 2 versus ρ 2 for some normal and ChloroFluoroCarbons (CFCs) fluids, where is surface tension and ρ = 1/v is molar density. The linearity behavior of the derived equation is well fitted onto the experimental data of surface tension for monatomic, diatomic, nonpolar, polar, hydrogen-bonded and chlorofluorocarbons. In addition, the temperature dependence of surface tension for 20 different fluids is examined, in which the contributions of both terms of the average effective...