Sharif Digital Repository

Tetraphenylthiophene diamine (TPTDA) was prepared through a modified three-step route to achieve an improved overall yield. TPTDA reacted with succinic, adipic, suberic, sebasic, and fumaric acids via the Yamazaki phosphorylation method to yield novel partially aromatic polyamides (TPT series). A counterpart polyamide series based on p-phenylene diamine (Ph series) was also synthesized under the same conditions. All of the polymers were characterized by means of spectrochemical (Fourier transform infrared spectroscopy, 1H-nuclear magnetic resonance (NMR), and 13C-NMR) and thermal (differential scanning calorimetry and thermogravimetric) methods of analysis. Solubility of TPT polyamides was... 

This work focuses on transient thermal behavior of radial fins of rectangular, triangular and hyperbolic profiles with temperature-dependent properties. A hybrid numerical algorithm which combines differential transformation (DTM) and finite difference (FDM) methods is utilized to theoretically study the present problem. DTM and FDM are applied to the time and space domains of the problem, respectively. The accuracy of this method solution is checked against the numerical solution. Then, the effects of some applicable parameters were studied comparatively. Since a broad range of governing parameters are investigated, the results could be useful in a number of industrial and engineering... 

Using two techniques of thermogravimetry and differential scanning calorimetry under O2 and N2 gas atmosphere from 25 to 600 °C, the thermal behavior of chromium(VI) oxide CrO3 was investigated. The identity of products at different decomposition steps was confirmed by XRD technique. Both techniques produced similar results supporting the same steps for the compound. The received products were investigated by SEM electron microscope. The form and the size of crystals were investigated. Three distinct energy changes were observed, namely, two endothermic and one exothermic in DSC. The amount of ΔH for each peak is also reported  

The compounds α-lead oxide (α-PbO) and β-lead oxide (β-PbO) were purchased from Merck co. and used for thermal investigations in laboratory. The compound was heated in a thermogravimeter at different temperature, from 25 to 400 °C. The used gas atmosphere was O2. The received products were investigated by X-ray diffraction (XRD) technique. The received product Pb3O4 was confirmed by XRD. The textures of two different morphologies of α-PbO, β-PbO and the product Pb3O4 is investigated by scanning electron microscope (SEM) and transmission electron microscope (TEM) techniques. © 2018, Faculty of Metallurgy. All rights reserved  

Balance theory proposed by Heider for the first time modeled triplet interaction in a signed network, stating that relationships between two people, friendship or enmity, is dependent on a third person. The Hamiltonian of this model has an implicit assumption that all triads are independent, meaning that the type of each triad, being balanced or imbalanced, determined apart from the state of other triads. This independence forces the network to have completely balanced final states. However, there exists evidence indicating that real networks are partially balanced, raising the question of what is the mechanism preventing the system to be perfectly balanced. Our suggestion is to consider a... 

Controlling the localized heat generation density and temperature profile of nanostructures exploiting perfect absorption of individual resonance modes is reported. The methodology is applied to spherically symmetric nanostructures using the T-matrix method. It is demonstrated that perfect modal splitting of the absorption power at desired wavelengths and individual excitation of the modes provide the ability to localize the generated heat at desired locations, and control the resulting temperature profile in multilayer core–shell structures. By knowing the thermal behavior of individual modes, it is shown that excitation of the perfect absorption modes at desired temperatures can result in... 

The compound, alkaline lead acetate, Pb(CH3COO)2·PbO·H2O (ALA), was purchased from the Fluka Company. The X-ray diffraction film and SEM electron microgaph of this compound were obtained and reported in this paper for the first time. The thermal behavior of alkaline lead acetate (ALA) was studied using thermogravimetery (TGA) and Differential Scanning Calorimetery (DSC) techniques under an O2 gas atmosphere from 25 to 600°C. Four distinct energy changes associated with weight changes were observed, all of them being exothermic in the DSC results. The amount of ΔH for each peak is reported. © Sharif University of Technology  

Lanthanum hydroxide (La(OH)3) nanostructures, including elliptical nanoparticles, octahedral rods and irregular nanoparticles were prepared chemically in NaOH and KOH solutions with 10 M concentration. The obtained powders were characterized with XRD, SEM, TEM and DTA. Crystallinities, morphologies and thermal behavior of the obtained nanostructure powders were investigated under the influence of above mentioned solvents. The effect of chemical's temperature was also determined in one of the solvents (i.e. NaOH). The formation of growth in nanostructure mechanism under the influence of alkali solutions (i.e., KOH and NaOH) have been discussed considerably in this paper  

A mathematical time-dependent and isothermal model based on the grain model has been developed to simulate the kinetic and thermal behaviors of a porous iron oxide pellet undergoing chemical reactions with a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. Its novelty consists in fact that it can deal with a multi-species reducing gas and oxide pellet. In spite of previous models in which the pure reductant was applied as reducing gas, this model can indicate an actual view of pellet reduction including the effects of reducing gas utility and reducing gas ratio. A finite volume fully implicit technique was applied for solving the governing equations. The model has been... 

Thermal behavior and require power in hot continuous strip rolling are predicted by means of a coupled finite element-upper bound approach. A thermal-finite element analysis is utilized to simultaneously determine temperature distributions within the work-piece and the work-rolls while an upper bound solution is employed at the same time to estimate the rate of heat of deformation and the required power in each rolling stand. The proposed model can be applied for determining thermal behaviors of the strip and the work-rolls in single and multi- pass rolling schedules while the effects of different parameters including initial temperature and rolling speed can be considered in the analysis.... 

In this study, we simulate the thermal behavior of a kerosene-fired oxy-fuel burner. To do this, the velocity of pure oxygen is suitably changed to achieve variable-mixing of fuel and oxidizer. Before the simulation procedure, a number of primitive steps are taken to evaluate the selected numerical approaches and methods. In other words, we simulate the turbulent non-premixed kerosene–air flame confined in a combustor and compare the achieved numerical solutions with the available measurements to appraise the validity of achieved solutions. The comparisons are mainly provided for the predicted flame structure. The comparison indicates that the achieved numerical solutions are accurate enough... 

Hydrolysis of titanium isopropoxide alcoholic solution has been used to prepare the crystallized TiO2 nanoparticles at low temperature. Concentration ratio was used to control the pathway of sol-gel process and change the physical characteristics of TiO2 nanopowders. The crystallinity, morphology and size of aged TiO2 nanopowders were studied by X-ray diffraction and Scanning Electron Microscopy (SEM). FTIR and, Thermo-Gravimetric (TG) analysis were used to identify the functional groups and thermal behavior of prepared samples. Experimental results have shown that high crystalline TiO2 nanomaterial with anatase polymorph can be obtained at room temperature. It has been found that the... 

Thermal transport characteristics of electroosmotic flow of power-law fluids in the presence of pressure gradient through a slit microchannel are studied in this paper. Considering a fully developed flow with a constant wall heat flux as the boundary condition, the governing equations are numerically solved by means of the finite difference method. A complete parametric study is done in order to investigate the effects of different flow parameters on the thermal behaviors of the flow. The results show that the non-Newtonian characteristic of the fluid can influence the thermal behaviors of the flow by affecting the rate of heat convection and viscous dissipation; however, its influence... 

In automobile painting industries, new automobile body products frequently should be tested in order to determine the actual thermal behavior of a paint curing process before starting mass production. During the hardening processes of dipped paint coating, applied in the electrophoretic enameling process, or top paint coating, applied in the final coating process, the automobile body must be warmed up according to the specific paint manufacturer curve. Consequently, prediction of car body temperature during the curing process may be vital in the design and performance analysis of the paint ovens. Numerical simulation of these processes may reduce expensive and time-consuming experimental... 

The objective of the present work is to compare the performance of the regenerator of pulse tube refrigerators at low and high frequencies. The hydrodynamic and thermal behavior of the regenerator is investigated in this respect. To consider the system performance, a system of conservation equations including two energy equations for the regenerator as a porous media is employed. The present model considers one-dimensional, periodic, unsteady, compressible flow in the regenerator. The conservation equations are transformed by implementing the volumetric average scheme. The method of harmonic approximation is employed to derive an analytical solution. To explore the system performance, net... 

The objective of the present work is to analyze the performance of the regenerator of pulse tube refrigerators. Hydrodynamic and thermal behavior of the regenerator is investigated in this respect. To consider the system performance, a system of conservation equations including two energy equations for the regenerator as a porous media is employed. The present model considers one dimensional periodic unsteady compressible flow in the regenerator. The conservation equations are transformed by implementing the volumetric average scheme. Method of harmonic approximation is employed to derive an analytical solution. To explore the system performance, net energy flow and entropy generation... 

Graft copolymerization of methyl methacrylate (MMA) was carried out on bagasse fibers in an aqueous medium using eerie ammonium nitrate (CAN) as initiator under a neutral atmosphere. In order to obtain the optimum condition for graft copolymerization, the effects of initiator concentration, temperature, time of reaction, and monomer concentration were studied. The maximum grafting percent was found to be 122%. The bagasse grafted poly(methyl methacrylate) was characterized by FTIR and its thermal behavior was characterized by TGA. Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA