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    Synthesis and cation-exchange behavior of expanded MoS2 nanosheets for anticorrosion applications

    , Article 2017 INN International Conference/Workshop on Nanotechnology and Nanomedicine, NTNM 2017, 2 May 2017 through 3 May 2017 ; Volume 5, Issue 7 , 2018 , Pages 15573-15579 ; 22147853 (ISSN) Haddadi, S. A ; Amini, M ; Ghaderi, S ; Ramazani, A ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Molybdenum disulfide (MoS2), a 2D layered structure, because of its unique properties has widely attracted many researchers. In this study, by employing physical and chemical methods, not only layers of MoS2 have been intercalated, but also their surface properties enhanced. Low-dimensional and potential properties of intercalated MoS2 nanosheets are the aim of many researches. Here, we report a novel four step method to intercalate the layers of MoS2 nanosheets successfully using acid treatment, sonication, oxidization and thermal shocking. The other goal in this study is to evaluate the cation exchange ability and anticorrosion performance of the Ce3+ doped MoS2 nanosheets. The... 

    A Comparison of the Effects of Additives Alumina Nanoparticles and Microparticles on Microstructure and Properties of Magnesia-Doloma Refractory

    , M.Sc. Thesis Sharif University of Technology Shahraki, Aziz (Author) ; Nemati, Ali (Supervisor)
    Abstract
    Magnesia-Doloma refractories has advantages such as stability in alkaline environments, clean steel production, resistance to acid slag, good cement kiln coating flexibility, low production cost. It also has some weaknesses such as low resistance to thermal shock and quick hydration. In the present study using Birjand Mines Magnesite powders and Dolomites from Zefreh, Esfahan, Magnesia-Doloma clinkers were pressed under the pressure 90 MP and prepared at 1650⁰C in furnace under air atmosphere. The effect of adding 0, 2, 4, 6, and 8% of the Microparticles and Nanoparticles of α-Alumina on microstructure, physical properties, hydration resistance and Thermal shock resistance was studied. Phase... 

    Effect of microstructural constituents on the thermal fatigue life of A319 aluminum alloy

    , Article Materials Science and Engineering A ; Volume 454-455 , 2007 , Pages 528-535 ; 09215093 (ISSN) Firouzdor, V ; Rajabi, M ; Nejati, E ; Khomamizadeh, F ; Sharif University of Technology
    2007
    Abstract
    In this investigation, the effect of microstructural constituents on thermal fatigue resistance of A319 aluminum casting alloy was studied. For this purpose, both thermo-mechanical fatigue and thermal-shock fatigue experiments were performed in thermal cycling range between 40 and 250 °C. Following the results, samples with finer SDAS, lower porosity volume fraction and lower brittle intermetallic contents, as well as higher Si modification showed better thermal fatigue resistance. Moreover, T6 and T7 heat treatments appeared to be highly beneficial for thermal fatigue performance. According to the fractography analysis, porosities and coarse intermetallic phases were determined as the most... 

    Boundary identification between LBLOCA and SBLOCA based on stratification and temperature gradient in two-phase PTS

    , Article Annals of Nuclear Energy ; Volume 115 , May , 2018 , Pages 430-441 ; 03064549 (ISSN) Ghafari, M ; Ghofrani, M. B ; D'Auria, F ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Temperature gradient on the thick Reactor Pressure Vessel (RPV), caused by sudden overcooling events, especially in the downcomer, would intensify the propagation of structural defects. This situation known as Pressurized Thermal Shock (PTS) could be created in case of Emergency Core Cooling System (ECCS) actuation which leads to injection of cold water into the cold leg of the primary loop in some accidents, e.g. Loss Of Coolant Accident (LOCA). Prediction of Plant response to LOCA and water temperature gradient in the downcomer are performed in thermal-hydraulic section of PTS analysis. Employment of system codes is one of the proposed procedures in literature to obtain plant response and... 

    Determination of Optimum Temperature Profile in Fermentation of B.Subtilis to Maximize Alpha-Amylase Activity

    , M.Sc. Thesis Sharif University of Technology Abdollahi Mofrad, Younes (Author) ; Vosoughi, Manouchehr (Supervisor) ; Roostaazad, Reza (Supervisor)
    Abstract
    Alpha amylase enzyme is one of the most important enzymes used in a wide range of industries. The enzyme is used in industries such as detergents, food, pharmaceuticals, paper making and textile. Various national and international articles have been published on this enzyme that focused on specific targets. Despite the extensive studies carried out in this area inside the country, there is still no industrial production of alpha amylase and other enzymes in our country. In the view of the fundamental problem of the lack of industrialization of these studies, in addition to the lack of a riskier investor, it seems that there is a lack of industrial vision in these studies.In this study, the... 

    Fault Modeling of Transient Faults in Embedded Processors

    , M.Sc. Thesis Sharif University of Technology Tajik, Hossein (Author) ; Ejlali, Alireza (Supervisor)
    Abstract
    Many embedded processors are used in harsh environments and their behavior should be investigated against the incidence of common faults. Fault Injection is a prevalent method to do this investigation. Simulation-based fault injection is one of the most prominent forms of fault injection. A fault model is required to do simulation-based fault injection. Simulated faults should have the most similarity to the real faults. Temperature variation and in the extreme case thermal shock is one of the probable faults in harsh environment. In this thesis, we want to propose fault models for thermal shock in various abstraction levels, evaluate and compare these fault models and present methods to use... 

    Investigation and Simulation of Overcooling Transients of The Bushehr's VVER-1000 Nuclear Power Plant with RELAP5/MOD3.3

    , M.Sc. Thesis Sharif University of Technology Yousefi, Amir Hossein (Author) ; Ghofrani, Mohammad Bagher (Supervisor)
    Abstract
    During the operation of a nuclear power plant, the reactor pressure vessel (RPV) is exposed to a variety of pressure and thermal stresses and neutron radiations. This will cause the loss of the initial strength of the reactor vessel component. During the occurrence of some of accidents, an excessive cooling of the coolant inside the RPV takes place which in the term is called overcooling transients. In addition, in some of these events, a break in a section of the circuit will reduce the water level at the core of the reactor. By reducing the water level, the existing emergency makeup water systems are activated and inject water into the reactor. The temperature of the added water is much... 

    Fracture Mechanics Analysis of Boshehr Nuclear Power Plant (BNPP) RPV during LBLOCA Using ABAQUS Software

    , M.Sc. Thesis Sharif University of Technology Mirseifi, Miryousef (Author) ; Ghafari, Mohsen (Supervisor)
    Abstract
    In nuclear power plants (NPPs), the integrity of the Reactor Pressure Vessel (RPV) is one of the most essential issues in assessing the life of the NPPs. The RPV in a nuclear power plant cannot be replaced during plant life. Hence, maintaining the integrity of the RPV nuclear power plant is of great importance. In this study, the RPV integrity of Boshehr Nuclear Power Plant (BNPP) gainst crack formation and growth in the case of LBLOCA is evaluated and studied by the finite element method (FEM) in ABAQUS using the J-Integral method and also the weight function, which is a function of crack shape. According to the results, stress values increased significantly during the LBLOCA incident. The... 

    Optimization of air plasma sprayed thermal barrier coating parameters in diesel engine applications

    , Article Journal of Materials Engineering and Performance ; Volume 22, Issue 11 , 2013 , Pages 3530-3538 ; 10599495 (ISSN) Azadi, M ; Farrahi, G. H ; Moridi, A ; Sharif University of Technology
    2013
    Abstract
    In the present paper, an optimization of thermal barrier coating parameters is performed for diesel engine applications. The substrate is A356.0-T7, a cast aluminum alloy which has a vast application in diesel engines, and the alloy is coated by plasma sprayed ZrO2-8 wt.% Y2O3. Parameters including the feed rate of coating powders, the nozzle distance to specimen surfaces, and the coating thickness are optimized by thermal shock fatigue tests and bending tests. Optimum values of the feed rate and the nozzle distance are 30 g/min and 80 mm, respectively, when the objective is considered as maximizing the bending strength. Thermal shock tests demonstrate that lower thickness of coating layers... 

    Performance improvement of MgO-CaO refractories by the addition of nano-sized Al2O3

    , Article Materials Chemistry and Physics ; Volume 198 , 2017 , Pages 354-359 ; 02540584 (ISSN) Shahraki, A ; Ghasemi kahrizsangi, S ; Nemati, A ; Sharif University of Technology
    Abstract
    Magnesia-dolomite refractories have advantages such as stability in the basic environments, clean steel production, high corrosion resistance, proper covering in the cement furnace, and low production costs. However, their application is restricted due to low hydration resistance. In this research, the effects of nano and micro alumina particles on the microstructure, sintering behavior, and properties of magnesia-dolomite refractories were studied. For this purpose, MgO-CaO refractories were formulated using dolomite and magnetite and 0, 2, 4, 6 and 8 wt percentage nano and micro alumina were added to the formulation. Phase and microstructure analysis of the samples were performed using... 

    Effect of rare earth elements addition on thermal fatigue behaviors of AZ91 magnesium alloy

    , Article Journal of Rare Earths ; Volume 27, Issue 2 , 2009 , Pages 255-258 ; 10020721 (ISSN) Bayani, H ; Saebnoori, E ; Sharif University of Technology
    Chinese Society of Rare Earths  2009
    Abstract
    Influences of rare earth (RE) elements addition on thermal fatigue behaviors of AZ91 alloy were studied. Repeated heating and cooling cycles were applied on the samples at 170 and 210 °C to develop thermal fatigue cracks. Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy (SEM) as well as energy dispersive X-ray spectroscopy (EDS). Thermal fatigue behaviors were observed to improve successively by addition of the RE up to 2wt.%. This improvement was attributed to the consummation of aluminum in melt by precipitation of the needle shaped Al11RE3 phases. This process was attributed to the reduction of Mg17Al12 phase volume... 

    Visualization of Flow Pattern and Experimental Investigation of Thermal Performance of Pulsating Heat Pipe with Proposed Fluid

    , M.Sc. Thesis Sharif University of Technology Gandomkar, Amir Reza (Author) ; Saeedi, Mohammad Hassan (Supervisor) ; Shafii, Mohammad Behshad ($item.subfieldsMap.e)
    Abstract
    Pulsating heat pipe (PHP) is a two-phase device for the means of transferring high heat fluxes and is used extensively for the electronic cooling. In this study the different flow regimes in PHP with different fluids have been investigated. In this research, 3 different fluids including: Pure fluids, Ferro-fluid and surfactant solution with %50 filling ratio have been used. For ferro-fluid, 5 different concentrations and 3 type of magnetic fields have been operated in 2 different heat pipes. Results show that ferrofluid is more stable in Pyrex made-heat pipe for long period of time and no magnet mode has the best thermal performance due to high conductivity of fluid. In copper made-heat pipe... 

    3D dynamic coupled thermoelastic solution for constant thickness disks using refined 1D finite element models

    , Article Applied Mathematical Modelling ; Volume 60 , 2018 , Pages 273-285 ; 0307904X (ISSN) Entezari, A ; Filippi, M ; Carrera, E ; Kouchakzadeh, M. A ; Sharif University of Technology
    Elsevier Inc  2018
    Abstract
    This paper deals with the generalized coupled thermoelastic solution for disks with constant thickness. It is a sequel to the authors's previous work in which refined 1D Galerkin finite element models with 3D-like accuracies are developed for theories of coupled thermoelasticity. Use of the reduced models with low computational costs may be of interest in a laborious time history analysis of the dynamic problems. In this paper, the developed models are applied and evaluated for a 3D solution of the dynamic generalized coupled thermoelasticity problem in the disk subjected to thermal shock loads. Comparison of the obtained result with the results available in the literature verified the... 

    Preparation of nanostructured and nanosheets of MoS2 oxide using oxidation method

    , Article Ultrasonics Sonochemistry ; Volume 39 , 2017 , Pages 188-196 ; 13504177 (ISSN) Amini, M ; Ramazani S. A. A ; Faghihi, M ; Fattahpour, S ; Sharif University of Technology
    Abstract
    Molybdenum disulfide (MoS2), a two-dimensional transition metal has a 2D layered structure and has recently attracted attention due to its novel catalytic properties. In this study, MoS2 has been successfully intercalated using chemical and physical intercalation techniques, while enhancing its surface properties. The final intercalated MoS2 is of many interests because of its low-dimensional and potential properties in in-situ catalysis. In this research, we report different methods to intercalate the layers of MoS2 successfully using acid-treatment, ultrasonication, oxidation and thermal shocking. The other goal of this study is to form S[dbnd]O bonds mainly because of expected enhanced... 

    New turbulence modeling for simulation of Direct Contact Condensation in two-phase pressurized thermal shock

    , Article Progress in Nuclear Energy ; Volume 108 , 2018 , Pages 358-371 ; 01491970 (ISSN) Ghafari, M ; Ghofrani, M. B ; D'Auria, F ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Injection of Emergency Core Cooling System (ECCS) water into the primary loops of the Pressurized Water Reactors (PWRs) leads to rapid cooling of Reactor Pressure Vessel (RPV) inside wall after Loss Of Coolant Accident (LOCA). This condition, known as Pressurized Thermal Shock (PTS) intensifies the propagation of the RPV structural defects and would be considered as an ageing mechanism. For structural and fracture analysis of RPV wall, thermal-hydraulic analysis of PTS should be accomplished to obtain the steam/water flow characteristics in the downcomer. For this purpose, simulation of steam/water stratified flow (due to density difference) after the injection point should be done by... 

    Thermal-Hydraulic Simulation and Analysis of Two-Phase Thermal Shock in Pressurized Light Water Power Plants

    , Ph.D. Dissertation Sharif University of Technology Ghafari, Mohsen (Author) ; Ghofrani, Mohammad Bagher (Supervisor)
    Abstract
    As a result of fission reaction in a nuclear reactor, the produced high neutron flux would affect the material of Reactor Pressure Vessel (RPV). This neutron radiation has a detrimental impact on the mechanical properties of the RPV material such as hardening (or embrittlement) while neutrons are absorbed by the material. A major concern in embrittled RPVs is propagation of critical flaw causing through-wall cracks. Some transients leading to overcooling of RPV intensify the propagation of theses cracks and result in thermal load on RPV, known as Pressurized Thermal Shock (PTS). Such situation could be created in case of Emergency Core Cooling System (ECCS) actuation which leads to injection... 

    Modified Green–Lindsay analysis of an electro-magneto elastic functionally graded medium with temperature dependency of materials

    , Article Mechanics of Time-Dependent Materials ; Volume 26, Issue 4 , 2022 , Pages 871-890 ; 13852000 (ISSN) Mirparizi, M ; Razavinasab, S. M ; Sharif University of Technology
    Institute for Ionics  2022
    Abstract
    This article presents a modified Green–Lindsay (MG-L) thermoelasticity model considering temperature and strain rate. Previously, this model has been developed based on the Green–Lindsay theory of thermoelasticity using strain and temperature rate dependent thermoelastic equations. This study analyzes stress and thermal wave propagation of a functionally graded medium exposed to an electromagnetic field and a thermal shock. All magnetic, elastic, and thermal features of the medium are considered to vary in the longitudinal direction. Additionally, the properties of the material are dependent on the temperature in the form of a cubic function. Using the large displacement formulation and the... 

    Effect of exfoliated molybdenum disulfide oxide on friction and wear properties of ultra high molecular weight polyethylene

    , Article Polymers for Advanced Technologies ; Volume 29, Issue 12 , 2018 , Pages 3085-3096 ; 10427147 (ISSN) Amini, M ; Ramazani S. A., A ; Afkhami Varjouy, A ; Faghihi, M ; Sharif University of Technology
    John Wiley and Sons Ltd  2018
    Abstract
    The aim of this work is to investigate the effect of molybdenum disulfide on tribological properties of Ultra-high-molecular-weight polyethylene (UHMWPE). UHMWPE/MoS2 nano-composites were prepared using in-situ polymerization and Ziegler-Natta catalytic system. Studies showed that, in order to obtain the optimum tribological properties, interlayer distance between nanosheets should be as high as possible. Therefore, the nanosheets were subjected to oxidation using the required oxidants followed by thermal shock and ultrasound. Fourier-transform infrared spectroscopy (FTIR) analysis was used to determine the formation of functional groups which indicate the formation of S═O bond in the...