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Thermogravimetric analysis and kinetic study of heavy oil pyrolysis
, Article Petroleum Science and Technology ; Volume 34, Issue 10 , 2016 , Pages 911-914 ; 10916466 (ISSN) ; Hami, M. R ; Sharif University of Technology
Taylor and Francis Inc
2016
Abstract
ABSTRACT: Pyrolysis, so-called devolatilization, is one of the first steps of all thermochemical processes occurring in an inert atmosphere. The authors discuss the main kinetic features of heavy oil pyrolysis, on the basis of the data derived m from a TGA analysis and by using a kinetic model. The samples were heated over a range of temperature from 400 K to 430°C at various heating rates between 10 and 80°C/min. Experimental results showed that the effect of time is considerable in the case of tar conversion, compared to char and gases