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tin-oxides
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Synthesis of tin oxide nanoparticles in order to study its properties
, Article Digest Journal of Nanomaterials and Biostructures ; Volume 16, Issue 1 , 2021 , Pages 41-49 ; 18423582 (ISSN) ; Ali, N ; Shahid, A ; Khan, S ; Alrobei, H ; Sharif University of Technology
S.C. Virtual Company of Phisics S.R.L
2021
Abstract
Pure tin oxide nanoparticles ware synthesized via Co-precipitation method. The as-synthesized nanoparticles were characterized by Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), X-ray diffraction (XRD) and diffuse reflectance spectroscopy (DRS). X-ray diffraction shows that tetrahedral shaped nanoparticles of crystallite size 47.35nm were prepared successfully. The crystallinity was established due the reduction in distortion ratio and dislocation density. The value of strain showed that the nanoparticles fabricated were of high stability. The direct and indirect optical band gap of as-synthesized SnO2 nanoparticles were determined from the reflectance...
Deposition of Nanostructure Antimony Doped Tin Oxide (ATO) on Glass By Sol-Gel
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor)
Abstract
Antimony Doped tin oxide as a conductive film has found a wide range of applications and sol-gel method has so advantageous with respect to another methods for preparing ATO thin films. In this study, ATO thin film has been synthesized using a solution containing metal salts of tin chloride and antimony chloride. The microstructure of the obtained films was studied by applying scanning electron microscopy (SEM) and X-ray diffraction patterns (XRD). In diffraction patterns of the acquired ATO layers which was deposited from a sol containing SnCl4.5H2O and SnCl2.2H2O with Sb concentration of 15%mol and layers which was deposited from a sol containing SnCl4.5H2O with Sb concentration of 15%mol...
The ITO-capped WO3 nanowires biosensor based on field-effect transistor in label-free protein sensing
, Article Applied Physics A: Materials Science and Processing ; Volume 123, Issue 5 , 2017 ; 09478396 (ISSN) ; Sharif University of Technology
Springer Verlag
2017
Abstract
The fabrication of ITO-capped WO3 nanowires associated with their bio-sensing properties in field-effect transistor diagnostics basis as a biosensor has been reported. The bio-sensing property for manipulated nanowires elucidated that the grown nanostructures were very sensitive to protein. The ITO-capped WO3 nanowires biosensor showed an intensive bio-sensing activity against reliable protein. Polylysine strongly charged bio-molecule was applied as model system to demonstrate the implementation of materialized biosensor. The employed sensing mechanism was ‘label-free’ and depended on bio-molecule’s intrinsic charge. For nanowires synthesis, the vapor–liquid–solid mechanism was used....
Effect of content silver and heat treatment temperature on morphological, optical, and electrical properties of ITO films by sol-gel technique
, Article Journal of Nanoparticle Research ; Volume 16, Issue 9 , September , 2014 ; ISSN: 13880764 ; Dolati, A ; Sharif University of Technology
Abstract
Silver-doped indium tin oxide thin films were synthesized using sol-gel dip-coating technique. The influence of different silver-dopant contents and annealing temperature on the electrical, optical, structural, and morphological properties of the films were characterized by means of four-point probe, UV-Vis spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and X-ray photoelectron spectroscope (XPS). XRD analysis confirmed the formation of cubic bixbyte structure of In2O3with silver nanoparticles annealed at 350 °C. XPS analysis showed that divalent tin transformed to tetravalent tin through oxidization, and silver nanoparticles embedded into ITO...
Novel nanocomposite polyethersulfone- antimony tin oxide membrane with enhanced thermal, electrical and antifouling properties
, Article Polymer ; Volume 163 , 2019 , Pages 48-56 ; 00323861 (ISSN) ; Hosseini, S. A ; Ma, G ; McGregor, M ; Sadrzadeh, M ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
Application of organic−inorganic nanocomposite membranes for water treatment is exceptionally growing owing to their tunable functionalities in addition to their enhanced permeation and antifouling propensity. In the present work, novel nanocomposite polyethersulfone (PES) membrane was synthesized using antimony-doped tin oxide (ATO) nanoparticles (NPs) via phase separation technique. It was found that the modified PES-ATO nanocomposite membranes exhibited significantly higher fouling resistance and larger permeate flux recovery ratio when tested with oil sands produced water than unmodified PES membranes. Furthermore, the PES-ATO membranes provided 40% more organic matter removal compared...
Optimization of sputtering parameters for the deposition of low resistivity indium tin oxide thin films
, Article Acta Metallurgica Sinica (English Letters) ; Vol. 27, issue. 2 , Apr , 2014 , p. 324-330 ; Bagheri, B ; Yazdanfar, P ; Rashidian, B ; Sasanpour, P ; Sharif University of Technology
Abstract
Indium tin oxide (ITO) thin films have been deposited using RF sputtering technique at different pressures, RF powers, and substrate temperatures. Variations in surface morphology, optical properties, and film resistances were measured and analyzed. It is shown that a very low value of sheet resistance (1.96 ω/sq.) can be achieved with suitable arrangement of the deposition experiments. First, at constant RF power, deposition at different pressure values is done, and the condition for achieving minimum sheet resistance (26.43 ω/sq.) is found. In the next step, different values of RF powers are tried, while keeping the pressure fixed on the previously found minimum point (1-2 Pa). Finally,...
Facile deposition of porous fluorine doped tin oxide by Dr. blade method for capacitive applications
, Article Ceramics International ; Volume 47, Issue 4 , 2021 , Pages 5487-5494 ; 02728842 (ISSN) ; Tajabadi, F ; Dastan, D ; Sangpour, P ; Shi, Z ; Taghavinia, N ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
Three-dimensional macroporous fluorine-doped tin oxide (p-FTO) films were successfully deposited using commercial ink of FTO powder and SnCl2 salt via Dr. Blade method. Various features of p-FTO thin films were studied as a function of the ink composition and sintering temperature. The morphological studies corroborated formation of porous, uniform, and crack-free FTO films after annealing at 300 °C for 10 min in air. X-ray diffraction pattern demonstrated development of highly crystalline FTO films. The lowest sheet resistance of 47 Ω/□ was obtained for the p-FTO film with a thickness of 21 μm. The capacitance of thin p-FTO films was investigated using a three-electrode system and the...
Facile deposition of porous fluorine doped tin oxide by Dr. Blade method for capacitive applications
, Article Ceramics International ; 2020 ; Tajabadi, F ; Dastan, D ; Sangpour, P ; Shi, Z ; Taghavinia, N ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
Three-dimensional macroporous fluorine-doped tin oxide (p-FTO) films were successfully deposited using commercial ink of FTO powder and SnCl2 salt via Dr. Blade method. Various features of p-FTO thin films were studied as a function of the ink composition and sintering temperature. The morphological studies corroborated formation of porous, uniform, and crack-free FTO films after annealing at 300 °C for 10 min in air. X-ray diffraction pattern demonstrated development of highly crystalline FTO films. The lowest sheet resistance of 47 Ω/□ was obtained for the p-FTO film with a thickness of 21 μm. The capacitance of thin p-FTO films was investigated using a three-electrode system and the...
Pulsed electrodeposition of gold nanoparticles on fluorine-doped tin oxide glass and absorption-based surface plasmon resonance evaluation
, Article Journal of Nano Research ; Volume 33 , 2015 , Pages 11-26 ; 16625250 (ISSN) ; Sadrnezhaad, S. K ; Sharif University of Technology
Trans Tech Publications Ltd
2015
Abstract
Synthesis and immobilization of Au nanoparticles (AuNPs) was performed on transparent fluorine-doped tin oxide (FTO) substrate by pulse electrodeposition method. The method was cost effective, simple and capable of producing nanoparticles strongly attached to the substrate. Effects of several influencing factors such as duty cycle, pulse frequency, current density, solution concentration, deposition period and annealing procedure on the optical properties of AuNPs-FTO electrode were investigated. AuNPs-FTO electrodes were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM) and UV-Vis absorption analysis. Controllability...
Microstructure, Properties and Kinetic Characterization in SnO2-Based Varistor with Addition of CuO Nano Particle
, M.Sc. Thesis Sharif University of Technology ; Nemati, Ali (Supervisor) ; Seyyed Reyhani, Morteza (Supervisor)
Abstract
The aim of this study is to investigate the effect of Copper oxide on the microstructure, properties, and grain growth kinetic in Tin oxide- Based varistors. Copper oxide was mixed in Tin oxide with different concentration, including 0, 0.1, 0.25, 0.5, and 1 mol% and the samples were sintered at 1250, 1300, and 1350 oC. Then, phase and microstructural characterization was investigated and consequently, electrical properties were evaluated. According to results, Copper Oxide with forming the liquid phase through the sintering process, accelerated grain growth. It was found that, by increasing concentration of CuO, mean grain size was increased from 2.6 µm in 1250 oC and 5 hours to 17.1 µm...
Evaluation Effects of Mo, Bi &Sn Biocides On the Anti-Fouling Paints
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this research Feasibility of application of oxide compounds of bismuth, molybdenum and tin as biocide was studied. So some epoxy paints with different ratio of these compounds were formulated. Afterward some tests were performed to assessment paints properties such as leaching rate, antifouling activity, adhesion, corrosion resistance and impact resistance. Results of leaching rate test showed that increase in the ratio of bismuth oxide from 10% to 60%, led to increase leaching rate from 0.029mg.day-1.cm-2 to 0.126mg.day-1.cm-2. beside that Microscopic results showed proved that the ratio of bismuth oxide in the cured coating is 25% of the paint formulate. In similar ratio of biocides,...
Deposition of Indium-tin-oxide on Glass By Sol-gel and Effect of Noble Dopants on the Optical and Electerical Properties of Indium-tin-oxide Thin Films
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor)
Abstract
Thin film of Indium oxide doped with tin is used as a transparent electrode for different applications like screening panels, solar cells, touch panels and elechtrochromic tools. Trading thin films of ITO are precipitated using sputtering. However sol gel method can be simple and economic to make transparent electrodes. In this thesis first ITO sols is prepared using Indium nitrate and tin chloride with two or four capacities due to the production of transparent oxides on soda lime glass. Then the effect of tin chloride with two and four capacities is investigated on resistance and optic properties. Results show that tin chloride with four capacities in comparison with tin of two capacities...
Microwave Assisted Synthesis of Sno2 Nanoparticles from Sn Coated Cu Wire Scraps
, M.Sc. Thesis Sharif University of Technology ; Sadrnezhaad, Kh (Supervisor) ; Mohammadi, MohammadReza (Supervisor)
Abstract
Tin Oxide Nanoparticle (SnO2) with the band gap of around 3.6 eV is one of the promising materials in various fields such as photocatalysis water splitting, pollutant removal and also biotechnology. Inorder to use this material in a visible-light rang, some promotions should be conducted.By combining SnO2 nanoparticles with the non-metalic graphitic carbon nitride (g-C3N4), a proper nanocomposite with wide range of application can be obtained. But, in order to industrialize this material, the cost of the final product is an imperative issue to consider.Here we have introduced a novel and low-cost method for synthesis of g-C3N4/SnO2 nanocomposite by using urea as a precursor for g-C3N4 and...
Synthesis, Characterization and Catalytic Application of rGO based Tin Oxide Nanocatalyst in Oxidative Desulfurization Process
, M.Sc. Thesis Sharif University of Technology ; Kazemeini, Mohammad (Supervisor) ; Hasannia, Saeed (Supervisor)
Abstract
In recent years, graphene-based materials have received much attention due to their prominent physicochemical properties such as high specific surface area, high mechanical strength and rich surface functional groups. In addition to these properties, low cost and environmental safety make graphene-based materials a green catalyst for many catalytic processes, including oxidative desulfurization. Tin oxide is a substance with strong acidic sites. Recent studies have shown that the oxidative desulfurization process using tin oxide nanoparticles is a new method for producing cleaner diesel fuels. In this study, rGO based tin oxide nanocatalyst was synthesized. To synthesize this catalyst,...
Smart chip for visual detection of bacteria using the electrochromic properties of polyaniline
, Article Analytical Chemistry ; Volume 91, Issue 23 , 2019 , Pages 14960-14966 ; 00032700 (ISSN) ; Farahmand Nejad, M. A ; Parolo, C ; Shahrokhian, S ; Merkoci, A ; Sharif University of Technology
American Chemical Society
2019
Abstract
Finding fast and reliable ways to detect pathogenic bacteria is crucial for addressing serious public health issues in clinical, environmental, and food settings. Here, we present a novel assay based on the conversion of an electrochemical signal into a more convenient optical readout for the visual detection of Escherichia coli. Electropolymerizing polyaniline (PANI) on an indium tin oxide screen-printed electrode (ITO SPE), we achieved not only the desired electrochromic behavior but also a convenient way to modify the electrode surface with antibodies (taking advantage of the many amine groups of PANI). Applying a constant potential to the PANI-modified ITO SPE induces a change in their...
SnO2/ZnO double layer thin films: A novel economical preparation and investigation of sensitivity and stability of double layer gas sensors
, Article International Journal of Nanomanufacturing ; Volume 2, Issue 1-2 , 2008 , Pages 59-69 ; 17469392 (ISSN) ; Shokuhfar, A ; Sadrnezhaad, S. K ; Shokuhfar, T ; Sharif University of Technology
Inderscience Publishers
2008
Abstract
A double-layer SnO2/ZnO gas sensor was produced by utilisation of SnOSUB align=right2 and ZnO thin films. Top layer consisted of SnOSUB align=right2 produced by a sol gel-controlled annealing technique. Bottom coating consisted of ZnO thin film precipitated by Two-Stage Chemical Deposition (TSCD) from an aqueous zinc-containing solution. Both top and bottom coatings were analysed by SEM, XRD, EDAX and AAS. Gas sensitivity of the SnO2/ZnO double layer was determined by electrical resistance measurements. Although sensitivity was slightly reduced by double-layer formation, selectivity and stability were considerably improved by combination of the two thin layers. The existence of an...
Ultraviolet photodetectors based on ZnO sheets: The effect of sheet size on photoresponse properties
, Article Applied Surface Science ; Volume 258, Issue 14 , 2012 , Pages 5405-5411 ; 01694332 (ISSN) ; Pazoki, M ; Mahdavi, S. M ; Bahrampour, A. R ; Taghavinia, N ; Sharif University of Technology
Abstract
In this work, ultraviolet photodetectors based on electrodeposited ZnO sheet thin films were fabricated on a glass substrate. Before electrodeposition, a thin buffer layer of ZnO was deposited on the glass by pulsed laser deposition method. This layer not only acted as a nucleation site for ZnO sheet growth, but also made it possible to use cheap glass substrate instead of conventional fluorine-doped tin oxide (FTO) substrate. Our results showed that photoresponse properties of the photodetectors strongly depend on the sheet sizes. The smaller sheets exhibited enhanced photosensitivity, shortened fall times and decreased gain compared to larger ones. We showed that photodetectors based on...
Influence of Substrate, Additives, and Pulse Parameters on Electrodeposition of Gold Nanoparticles from Potassium Dicyanoaurate
, Article Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science ; Volume 46, Issue 6 , December , 2015 , Pages 2584-2592 ; 10735615 (ISSN) ; Sadrnezhaad, S. K ; Sharif University of Technology
Springer Boston
2015
Abstract
Gold nanoparticles (AuNPs) of less than 50 nm diameter were electrodeposited from cyanide solution by pulsating electric current on modified copper and indium tin oxide (ITO) films coated on glass. Morphology, size, and composition of the deposited AuNPs were studied by X-ray photoelectron spectroscopy, atomic force microscopy, and field emission scanning electron microscopy. Effects of peak current density, pulse frequency, potassium iodide and cysteine on grain size, and morphology of the AuNPs were determined. Experiments showed that cathode current efficiency increases with the pulse frequency and the iodide ion. Size of the AuNPs increased with the current density. The number of...
Effects of tin valence on microstructure, optical, and electrical properties of ITO thin films prepared by sol–gel method
, Article Journal of Sol-Gel Science and Technology ; Volume 75, Issue 3 , September , 2015 , Pages 582-592 ; 09280707 (ISSN) ; Dolati, A ; Sharif University of Technology
Kluwer Academic Publishers
2015
Abstract
Abstract: This study aimed to understand the microstructural, optical, and electrical properties of tin-doped indium oxide (ITO) prepared with tetravalent and divalent tin salts. The influence of tin valence on the electrical, optical, structural, and morphological properties of the films were characterized by the mean of four-point probe, thermogravimetric analysis, differential thermal analysis (DTA), UV–Vis spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and X-ray photoelectron spectroscope. XRD results revealed formation of cubic bixbyite structure of In2 O3 with a small shift in major peak position toward lower angles with...
Sequential deposition as a route for efficient counter electrodes in quantum dot sensitized solar cells
, Article RSC Advances ; Volume 5, Issue 57 , May , 2015 , Pages 45592-45598 ; 20462069 (ISSN) ; Samadpour, M ; Taghavinia, N ; Sharif University of Technology
Royal Society of Chemistry
2015
Abstract
In this paper, we introduce the sequential deposition method for enhancing the performance of nanocomposite counter electrodes (CEs) in quantum dot sensitized solar cells (QDSCs). Here, various CEs are made by the deposition of CuS, PbS, and CuS/PbS nanocomposite layers on an FTO (fluorine doped tin oxide) coated glass substrate by a simple successive ionic layer adsorption and reaction (SILAR) method. The result indicates that the efficiency of the cells with CuS/PbS CEs is enhanced by 2.65% compared with the bare CuS (0.99%) or PbS (1.47%) CEs. Also, no considerable improvement is observed for PbS/CuS CEs (1.09%), which indicates that the order of PbS and CuS deposition is critical for...