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    Study of plastics elimination in bioleaching of electronic waste using Acidithiobacillus ferrooxidans

    , Article International Journal of Environmental Science and Technology ; Volume 16, Issue 11 , 2019 , Pages 7113-7126 ; 17351472 (ISSN) Arshadi, M ; Yaghmaei, S ; Mousavi, S. M ; Sharif University of Technology
    Center for Environmental and Energy Research and Studies  2019
    Abstract
    Polystyrene, acrylonitrile butadiene styrene, and polypropylene are the main polymers in E-waste, existing about 31%, 16%, and 13%, respectively. In this research, the effects of the elimination of low-density materials (such as polymers and plastics) were studied using the shaking table method. Bioleaching of Cu and Ni against the original sample (Sample #1) and pre-treated sample without low-density materials (Sample #2) was compared. The amount of bioleached metals and growth characteristics (including pH, Eh, bacterial count) was investigated within 25 days. The analysis of Sample #1 showed that at pulp density of 15 g/l, 94% and 79% of Cu and Ni were recovered maximally, respectively,... 

    Photocatalytic degradation of 3-methyl-4-nitrophenol over Ag/AgCl-decorated/[MOYI]-coated/ZnO nanostructures: Material characterization, photocatalytic performance, and in-vivo toxicity assessment of the photoproducts

    , Article Environmental Technology and Innovation ; 2020 Padervand, M ; Heidarpour, H ; Goshadehzehn, M ; Hajiahmadi, S ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    In this work, a facile ionic liquid-mediated method was utilized to fabricate an efficient photocatalyst for environmental remediation. The eco-friendly aspect of the treatment was explored through an in-vivo toxicity bioassay. ZnO particles, prepared by a combined solid state-pyrolysis method, were coated by 1-methyl-3-(oxiran-2ylmethyl)-1H-imidazolium-3-chloride ([MOYI]Cl) ionic liquid. Then, Ag/AgCl species were grown on the surface to make a heterojunction system leading to efficient charge separation and light absorption extension to the visible domain. The products were characterized by XRD, FTIR, SEM, EDX, DRS, BET, and PL analysis. Photocatalytic performance of the nanostructures was... 

    A mechanistic approach for toxicity and risk assessment of heavy metals, hydroquinone and microorganisms in cosmetic creams

    , Article Journal of Hazardous Materials ; Volume 433 , 2022 ; 03043894 (ISSN) Irfan, M ; Shafeeq, A ; Siddiq, U ; Bashir, F ; Ahmad, T ; Athar, M ; Butt, M.T ; Ullah, S ; Mukhtar, A ; Hussien, M ; Lam, S. S ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    The demand and importance of fairness creams as a major cosmetic have increased significantly in recent years. However, some of these cosmetics contain heavy metals, hydroquinone and microorganism that can cause various health problems. Therefore, the aim of this study is to determine and examine the concentration of metals (i.e. Cd, Pb, Cr, Ni, Zn, Hg), hydroquinone and microorganisms in nine different fairness creams produced by local and international brands. The health risk assessment of the tested substances for consumers was accessed through systemic exposure dosage (SED), margin of safety (MoS), lifetime cancer risk (LCR), hazard quotient (HQ) and hazard index (HI). The concentration... 

    An in vitro study of bare and poly(ethylene glycol)-co-fumarate-coated superparamagnetic iron oxide nanoparticles: A new toxicity identification procedure

    , Article Nanotechnology ; Volume 20, Issue 22 , 2009 ; 09574484 (ISSN) Mahmoudi, M ; Simchi, A ; Imani, M ; Milani, A. S ; Stroeve, P ; Sharif University of Technology
    2009
    Abstract
    As the use of superparamagnetic iron oxide nanoparticles (SPION) in biomedical applications increases (e.g. for targeting drug delivery and imaging), patients are likely to be exposed to products containing SPION. Despite their high biomedical importance, toxicity data for SPION are limited to date. The aim of this study is to investigate the cytotoxicity of SPION and its ability to change cell medium components. Bare and poly(ethylene glycol)-co-fumarate (PEGF)-coated SPION with narrow size distributions were synthesized. The particles were prepared by co-precipitation using ferric and ferrous salts with a molar Fe3+/Fe2+ ratio of 2. Dulbecco's modified Eagle's medium (DMEM) and primary...