Sharif Digital Repository

The transformation of gibbsite to α-alumina occurs in the range 1100 to 1300°C. The higher the calcination temperature, the larger the crystallites and this leads to abnormal grain growth. The main goal of this research was to reduce the transformation temperature of gibbsite to α-alumina by reducing the gibbsite particles size. The sodium content of the gibbsite used in the study was reduced to less than 0.1% by washing it in HCl solution. It was then ground in a fast mill at ambient conditions for different times then calcined at different temperatures. The microstructure, particles size and thermal behaviour of the samples were examined with SEM, XRD, XRF, PSA and STA, respectively. In a... 

The transformation of gibbsite to α-alumina occurs in the range 1100 to 1300°C. The higher the calcination temperature, the larger the crystallites and this leads to abnormal grain growth. The main goal of this research was to reduce the transformation temperature of gibbsite to α-alumina by reducing the gibbsite particles size. The sodium content of the gibbsite used in the study was reduced to less than 0.1% by washing it in HCl solution. It was then ground in a fast mill at ambient conditions for different times then calcined at different temperatures. The microstructure, particles size and thermal behaviour of the samples were examined with SEM, XRD, XRF, PSA and STA, respectively. In a... 

In the present paper, the fabrication and characterisation of typical high temperature Ni(Ti+ Hf) alloyed thin films produced by simultaneous sputter deposition from separate elemental Ni, Ti and Hf targets are presented. Film composition, determined by energy dispersive X-ray spectroscopy, was controlled by adjusting the ratio of powers applied to each target. Films deposited at room temperature had an amorphous structure and subsequent annealing at 550°C was carried out in a high vacuum environment, based on crystallisation temperature evaluation by differential scanning calorimetry (DSC). High temperature martensitic transformation, confirmed by DSC and variable temperature X-ray... 

In the present research work the binary NiTi alloys with various compositions in the range of 50.3-51 at.% Ni were used. Samples have been annealed at 850 °C for 15 min and then quenched in water. In order to characterize transformation temperatures and enthalpy changes of the forward and the reverse martensitic transformation, Differential Scanning Calorimetric (DSC) experiments were performed. The enthalpy and entropy changes as a function of Ni atomic content have been thermodynamically investigated. Results show that enthalpy and entropy changes of martensitic transformation decrease when Ni atomic content increases. The variation of enthalpy and entropy of martensitic transformation... 

Nickel titanium shape memory alloys (NiTi-SMAs) were successfully produced from elemental Ni/Ti powders by powder metallurgical method and then subjected to age treatment. Microstructure was examined by SEM and XRD and phase transformation temperatures were measured by dilatometric method. The phase transformation temperatures increased with both duration and temperature of the age treatment. The porous product exhibited desirable shape memory effect. © 2009 Elsevier B.V. All rights reserved  

NiTiHf thin films with varying hafnium contents up to 28.7at% were fabricated using simultaneous sputter deposition from separate Ni, Ti, and Hf targets onto unheated substrates. The required film composition was achieved by adjusting the power ratio to the targets. The as-deposited films were amorphous; and post deposition annealing was performed at 550°C, slightly above their crystallization temperatures. The crystallization temperature of the films varied as a function of Hf concentration, and was as high as 520°C at a Hf content of 28.7at%. 2μm thick crystallized films with I0at% or greater Hf were martensitic at room temperature. DSC analysis demonstrated that above 10at%Hf additions... 

The strain-induced martensitic transformation greatly affects the plastic behavior of the metastable austenitic stainless steels. The martensitic transformation continuously changes the initially homogeneous material into a strongly heterogeneous bi-phase one. In addition to the hardening behavior, this phenomenon would influence the damage growth and load-carrying capacity of the material during the plastic deformation. In this study, plastic behavior of the material AISI 304 including the hardening and damage growth, has been examined at low temperature; where a high rate of martensitic transformation affects the microstructure strongly. Experimental analysis and microscopic observations... 

The present paper deals with different effects of homogenization time and cooling environment on Ni-42.5wt%Ti-7.5wt%Cu alloy. The alloy was prepared by vacuum arc melting. Afterwards, three homogenization times (half, one and two hour) and three cooling environments (water, air and furnace) at 1373 K were selected. Optical and Scanning Electron Microscopic methods, EDX, DSC and hardness tests have been used to evaluate the microstructure, transformation temperatures and hardness. Results indicate that specimens that were cooled in air are super-saturated. Also, the microstructure from furnace cooling has many disparities with the other cooling environments' microstructure and two types of... 

We produced bifurcated bone-like shape memory implant (BL-SMI) with desirable tooth-root fixation capability by compact-sintering of TiH2–Ni-urea mixture. The primary constituents of the porous product were Ni and Ti. We could adjust the pores' shape, size, and interconnectivity for favorite bone ingrowth by using urea as a space holder. Without urea, we obtained an average porosity of 0.30, and a mean void size of 100 μm. With 70 vol % urea, we got 62% interconnected pores of 400 μm average size. Aging allowed us to tune the austenite-martensite transformation temperatures towards the needed body tissue arouse. Differential scanning calorimetry measured the transformation temperatures.... 

Low carbon steel sheets are subjected to severe plastic deformation (SPD) via constrained groove pressing (CGP) up to five passes. As a result of this process, strain magnitude up to 5?8 is imposed to the sheets, which leads to grain size of 225 nm. These nanostructured steel sheets, due to their high dislocation density and ultrafine microstructure, are very sensitive to heating. In the present study, recovery, recrystallisation and ferrite to austenite phase transformation phenomena for the SPD steel are investigated using differential scanning calorimetry method. The results show that with increasing the strain in steel sheets, the deformed stored energy (released through recovery and... 

Magnesium nanopowder (MgNP) of 17 nm average size was produced by planetary ball milling of Mg (φ=229 μm) with 10 wt% NaCl (φ=406 μm) for 50 h. NaCl was omissible by dissolution in saturated KOH. Partial oxidation of MgNP occurred, however, in presence of KOH. MgNP-NaCl mixture was, therefore, used for transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), differential scanning calorimetry (DSC) and Sieverts equilibrium investigation. DSC analysis of ammonium perchlorate showed one endothermic and three exothermic reactions. MgNP did not noticeably affect on the initial endothermic reaction. But it decreased transformation temperatures of the... 

Porous NiTi shape memory alloy (SMA) was fabricated by sintering of compressed constituent elements pre-mixed with NaCl or urea spacer holders. Effect of spacer to metal volume-ratio (r S) on shape, size, distribution and openness of the voids was probed by optical metallography, X-ray diffraction (XRD) and scanning electron microscopy (SEM). Differential scanning calorimetry (DSC) was used to determine the SMA transformation temperatures. Controllable void geometry helping osteoblast proliferation and bone cell growth was gained by addition of the spacers. At r S = 0.7, percentage of the open pores reached 52% while at r S = 1.43, interconnected pores with 200 to 500 μm diameter were... 

The present paper reports the effects of Nd:YAG laser welding on the microstructure, phase transformation, cyclic deformation behavior, and corrosion resistance of Ti-55 wt.% Ni wire. The results showed that the laser welding altered the microstructure of the weld metal which mainly composed of columnar dendrites grown epitaxially from the fusion line. DSC results indicated that the onset of the transformation temperatures of the weld metal differed from that of the base metal. Cyclic stress-strain behavior of laser-welded NiTi wire was comparable to the as-received material; while a little reduction in the pseudo-elastic property was noted. The weld metal exhibited higher corrosion... 

Recent uses of intelligent composites in biomedical appliances aggrandize the necessity of bonding-strength improvement in NiTi/silicone matrix interface. SEM micrographs and pull-out tests are employed to determine the strength of the NiTi/silicone bonds in a flexible composite piece. Greater adhesion strengths are obtained due to the presence of thin oxide layer, surface roughness and frictional forces between the embedded-wires and the contacting phase. Effect of curing treatment on phase transformation temperatures of the wires is determined by electrical resistivity (ER) measurements. Results show that the curing treatment shifts the transition points of the wires towards higher... 

The aim of this study was to investigate the thermal behavior of Mg-doped calcium phosphate compounds. Nanocrystalline HA and β-TCP mixtures containing different magnesium contents were synthesized via an alkoxide sol gel method. The ratio of (Ca+Mg)P was kept constant at 1.67, and the Mg content ranged between 0 and 3 mol%. The influence of magnesium on the phase composition, chemical structure, thermal behavior and morphological characteristics of nanopowders was analyzed using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Simultaneous Thermogravimetry and Differential Thermal Analysis (STA/DTA), Scanning Electron Microscopy (SEM) and Transmission Electron...