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Synthesis, characterizations and catalytic studies of a new two-dimensional metal-organic framework based on Co-carboxylate secondary building units
, Article Journal of Solid State Chemistry ; Volume 223, March , 2014 , Pages 32-37 ; ISSN: 00224596 ; Ashouri, F ; Dakovic, M ; Sharif University of Technology
Abstract
A metal-organic framework [Co3(BDC)3(DMF)2(H2O)2] was synthesized and structurally characterized. X-ray single crystal analysis revealed that the framework contains a 2D polymeric chain through coordination of 1,4-benzenedicarboxylic acid linker ligand to cobalt centers. The polymer crystallize in monoclinic P21 /n space group with a=13.989(3) Å, b=9.6728(17) Å, c=16.707(3) Å, and Z=2. The polymer features a framework based on the perfect octahedral Co-O6 secondary building units. The catalytic activities of [Co3(BDC)3(DMF)2(H2O)2]n for olefins oxidation was conducted. The heterogeneous catalyst could be facilely separated from the reaction mixture, and reused three times without significant...
Synthesis, structural characterization and application of a 2D coordination polymer of Mn-terephthalate as a heterogeneous catalyst for olefin oxidation
, Article Polyhedron ; Volume 69 , 17 February , 2014 , Pages 167-173 ; ISSN: 02775387 ; Ashouri, F ; Crossed D Signakovic, M ; Sharif University of Technology
Abstract
A metal-organic coordination polymer of [Mn3(1,4- benzenedicarboxylate)3(DMF)4] ([Mn3(BDC) 3(DMF)4]n) was synthesized and characterized by IR spectra, elemental analysis (CHN), thermal gravimetric analysis (TGA) and single crystal X-ray diffraction analysis. The structure of [Mn 3(BDC)3(DMF)4]n is a 2D-periodic framework based on Mn(II)-terephthalate secondary building units (SBUs). The catalytic oxidation of various olefins was effectively carried out with [Mn 3(BDC)3(DMF)4]n. Moreover, the influence of key reaction parameters, including the solvents, reaction temperatures and nature of oxidant were studied. The optimized conditions were achieved by TBHP as the efficient oxidant in...
Synthesis, characterizations and catalytic studies of a new two-dimensional metal-organic framework based on Co-carboxylate secondary building units
, Article Journal of Solid State Chemistry ; Volume 223 , March , 2015 , Pages 32-37 ; 00224596 (ISSN) ; Ashouri, F ; Daković, M ; Sharif University of Technology
Academic Press Inc
2015
Abstract
A metal-organic framework [Co3(BDC)3(DMF)2(H2O)2] was synthesized and structurally characterized. X-ray single crystal analysis revealed that the framework contains a 2D polymeric chain through coordination of 1,4-benzenedicarboxylic acid linker ligand to cobalt centers. The polymer crystallize in monoclinic P21/n space group with a=13.989(3) Å, b=9.6728(17) Å, c=16.707(3) Å, and Z=2. The polymer features a framework based on the perfect octahedral Co-O6 secondary building units. The catalytic activities of [Co3(BDC)3(DMF)2(H2O)2]n for olefins oxidation was conducted. The heterogeneous catalyst could be facilely separated from the reaction mixture, and reused three times without significant...