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    Electrodeposited multi-walled carbon nanotubes on Ag-loaded TiO2 nanotubes/Ti plates as a new photocatalyst for dye degradation

    , Article RSC Advances ; Volume 5, Issue 56 , 2015 , Pages 44840-44846 ; 20462069 (ISSN) Mohaghegh, N ; Faraji, M ; Gobal, F ; Gholami, M. R ; Sharif University of Technology
    Royal Society of Chemistry  2015
    Abstract
    MWCNTs/Ag/TiO2NTs plates were synthesized via electrochemical reduction of functionalized multiwalled carbon nanotubes (MWCNTs) on Ag/TiO2NTs. The loading of silver nanoparticles was carried out by electroless reduction of Ag1+ onto TiO2 nanotubes previously formed by anodizing titanium. The SEM analysis revealed that MWCNTs were loaded significantly on the as-prepared Ag/TiO2NTs, where nanoparticles of Ag had grown on the walls of TiO2NTs. The photocatalytic activity of the synthesized plates was evaluated by the photodegradation of Methyl Orange (MO) dye under UV light irradiation. The results indicated that the MWCNTs/Ag/TiO2NTs demonstrated improved efficiency for MO photodegradation in... 

    Comparative studies on Ag3PO4/BiPO4-metal-organic framework-graphene-based nanocomposites for photocatalysis application

    , Article Applied Surface Science ; Volume 351 , October , 2015 , Pages 216-224 ; 01694332 (ISSN) Mohaghegh, N ; Tasviri, M ; Rahimi, E ; Gholami, M. R ; Sharif University of Technology
    Elsevier  2015
    Abstract
    For the first time, we report novel Ag3PO4/BiPO4 (AB)-graphene-based photocatalysts. The fabricated nanocomposites were characterized by various techniques. The photocatalytic properties of the prepared catalysts were evaluated by the photodegradation of Atrazine herbicide under both visible and UV light irradiation. Atrazine concentration was determined using the spectrophotometric method according to the Konig's reaction by monitoring the absorbance at 470 nm wavelength during the photodegradation process. Both degradation rate and efficiency using graphene (GR)-based nanocomposites are found to be much better than using pure AB. Atrazine photodegradation displayed that the AB supporting... 

    Ag3PO4/BiPO4 p-n heterojunction nanocomposite prepared in room-temperature ionic liquid medium with improved photocatalytic activity

    , Article Materials Science in Semiconductor Processing ; Volume 39 , 2015 , Pages 506-514 ; 13698001 (ISSN) Mohaghegh, N ; Rahimi, E ; Gholami, M. R ; Sharif University of Technology
    Elsevier Ltd  2015
    Abstract
    Abstract A visible-light-active Ag3PO4/BiPO4 nanocomposite with a p-n heterojunction structure was fabricated via a co-precipitation hydrothermal process using 2-hydroxylethylammonium formate (RTIL) as a room-temperature ionic liquid. The resulting catalysts were characterized by various techniques. The photocatalytic activity of the photocatalysts was evaluated by the photodegradation of phthalocyanine Reactive Blue 21 (RB21) under both visible and UV light irradiations. The results reveal that the heterojunction composite prepared in RTIL noticeably exhibited an improvement in both efficiency and rate of RB21 photodegradation in comparison with pure Ag3PO4 and BiPO4. The enhanced...