Sharif Digital Repository

Scalable coating methods have recently emerged as practical alternative deposition techniques to the conventional spin-coating despite their lower yielding power conversion efficiencies (PCEs). The most important barrier acting against the use of scalable deposition methods to get a highly absorbing (>95%) film with controlled morphology in the high crystallinity of perovskite particles is the impossibility of antisolvent dripping during the deposition. Here, we demonstrate the positive role of both the surfactant-engineering and the vacuum-annealing (<100 Pa) process in improving the device performance to overcome this limit. A detailed optimization of the vacuum-assisted meniscus printing... 

Scale-up deposition methods in perovskite solar cell research, are mostly used under humidity environment outside the glove-box. Also, the as-printed absorbing layer before the post-annealing process is always wet. Thus, controlling the morphology and crystallization of perovskite thin-films in up-scaled deposition systems is difficult and strongly investigated by the researchers. In this work, we introduce an anti-solvent-free meniscus printing method in which, the absorbing perovskite film with optimal performance is achieved. To this end, we check the printing parameters to get to the optimized film characteristics. Also, a vacuum chamber (<100 Pa) is used for 30 s to remove the solvent... 

Vacuum deposition of transporting layers, especially the hole-transporting layer (HTL), is still a big challenge for the fabrication of large-area perovskite solar cells (PSCs). In this work, efficient and large-area PSCs are fabricated by thermal evaporation of all the layers. Poly(bis(4-phenyl)(2,4,6-trimethylphenyl)amine) (PTAA) is used as the HTL, and a compact layer of PTAA with low thickness (2–10 nm) is successfully deposited using thermal evaporation. The optical and ultraviolet photoelectron spectroscopy (UPS) measurements prove that the evaporated PTAA has a great match with the single A-cation methylammonium triiodide perovskite film in terms of quenching effect and band... 

The fabrication of efficient perovskite solar cells (PSCs) using all-vacuum processing is still challenging due to the limitations in the vacuum deposition of the hole transporting layer (HTL). Herein, inverted PSCs using copper (II) phthalocyanine (CuPC) as an ideal alternative HTL for vacuum processing are fabricated. After proper optimization, a PSC with a power conversion efficiency (PCE) of 20.3% is achieved, which is much better than the PCEs (16.8%) of devices with solution-based CuPC. As it takes a long time to dissolve CuPC in the solution-based device, the evaporation approach has better advantage in terms of fast processing. In addition, the device with the evaporated CuPC HTL...