Sharif Digital Repository

Variable-temperature 1H and 13C NMR spectroscopy are used to investigate barrier of C-N rotation in series of amides, such as N-benzoyl pyrrolidine, N-(4-chlorobenzoyl) pyrrolidine, N-(4-methoxybenzoyl) pyrrolidine, N-(4-chlorobenzoyl) piperidine, and N-(4-methoxybenzoyl) piperidine. Δ G298≠ of 65.2, 60.6, 58.8, 60.1, and 57.1 kJ mol-1are found for the above compounds, respectively. Theoretical studies were done for these compounds and the results showed good agreement with the experimental results. Theoretical and experimental results showed that substituted methoxy group on the para position of benzene ring decreases the rotational barrier. Increasing steric effect and therefore... 

During the year, due to weather conditions, the temperature fluctuations at surface level cause problems in underground pipes as a result of freezing water. One of the best prevention strategies is the use of polyurethane floor insulation for keeping the temperature of clay above zero degrees Celsius. In this study to calculate the minimum thickness of polyurethane insulation layer, the differential equation of energy is solved based on principle of separation of variables using imaginary eigenvalues for consistency with the temperature distribution in multi-layer consist of asphalt, gravel and polyurethane with finite thickness and clay as a semiinfinite medium with periodic thermal... 

Background: The cooling system is one of the important parts of new devices such as smartphones, servers, and other electrical devices. By employing the almost all heat transfer methods such as conduction, evaporation and condensation, heat pipes are the best choice to increase the heat transfer. The thermal conductivity of heat pipe is much higher than fins because they benefit from condensation and evaporation simultaneously. Methods: This study tries to present relative thermal conductivity base on temperature and length of a heat pipe in optimized geometry. To achieve this aim, unsteady, multiphase fluid was considered inside the heat pipe. Evaporation, condensation, and conduction were... 

In the classical parametrization of the single-diode model of photovoltaic (PV) cells and modules based on the datasheet values, first, the values of the five unknown parameters of the PV model are extracted via the values of the open-circuit voltage Voc, the short-circuit current Isc, and the voltage and current at the maximum power point Vm, Im at standard test conditions (STC). Next, using some translational formulas, the STC values of the unknown parameters are projected to the new climatic conditions other than STC. A major problem of this approach is to determine the translational formulas of the five unknown parameters of the single-diode model as a function of both temperature and... 

Globally, the impacts of climate change can vary across different regions. This study uses a probability framework to evaluate recent historical (1976–2016) and near-future projected (until 2049) climate change across Europe using Climate Research Unit and ensemble climate model datasets (under RCPs 2.6 and 8.5). A historical assessment shows that although the east and west of the domain experienced the largest and smallest increase in temperature, changes in precipitation are not as smooth as temperature. Results indicate that the maximum changes between distributions of the variables (temperature and precipitation) mainly occur at extreme percentiles (e.g., 10% and 90%). A group analysis... 

The synthesis of nano-sized CeO 2 powder was investigated via mechanochemical reactions between hydrate cerium chloride and sodium hydroxide as the starting materials. The process was followed by a subsequent calcination procedure. Characterization of as-synthesized powder was performed using X-ray diffraction, FTIR spectroscopy, Brunner-Emmett-Teller (BET) nitrogen gas absorption, scanning electron microscopy (SEM) and particle size analyzer (PSA). The precursors were milled for different milling times and then were subjected to different heat treatment procedure at variable temperatures from 100 to 700 °C. According to the results, milling time and calcination temperatures induce...