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    Development of a novel graphene oxide-blended polysulfone mixed matrix membrane with improved hydrophilicity and evaluation of nitrate removal from aqueous solutions

    , Article Chemical Engineering Communications ; 2018 ; 00986445 (ISSN) Rezaee, R ; Nasseri, S ; Mahvi, A. H ; Nabizadeh, R ; Mousavi, S. A ; Maleki, A ; Alimohammadi, M ; Jafari, A ; Hemmati Borji, S ; Sharif University of Technology
    Taylor and Francis Ltd  2018
    Abstract
    In this study, four types of mixed matrix membranes were fabricated using polysulfone (as the base polymer) and different contents of graphene oxide (GO) nanosheets (as modifier) through wet phase inversion method. Based on the amounts of GO (0, 0.5, 1, and 2 wt%), the synthesized membranes named as M1, M2, M3, and M4, respectively. The membranes characteristics were evaluated using FE-SEM, FT-IR, and water contact angle measurements. In addition, the performance of the prepared membranes was investigated in terms of basic parameters: filtrate water flux, nitrate removal efficiency, and antifouling properties. Results showed significant improvements of the characteristics of modified... 

    Development of a novel graphene oxide-blended polysulfone mixed matrix membrane with improved hydrophilicity and evaluation of nitrate removal from aqueous solutions

    , Article Chemical Engineering Communications ; Volume 206, Issue 4 , 2019 , Pages 495-508 ; 00986445 (ISSN) Rezaee, R ; Nasseri, S ; Mahvi, A. H ; Nabizadeh, R ; Mousavi, S. A ; Maleki, A ; Alimohammadi, M ; Jafari, A ; Hemmati Borji, S ; Sharif University of Technology
    Taylor and Francis Ltd  2019
    Abstract
    In this study, four types of mixed matrix membranes were fabricated using polysulfone (as the base polymer) and different contents of graphene oxide (GO) nanosheets (as modifier) through wet phase inversion method. Based on the amounts of GO (0, 0.5, 1, and 2 wt%), the synthesized membranes named as M1, M2, M3, and M4, respectively. The membranes characteristics were evaluated using FE-SEM, FT-IR, and water contact angle measurements. In addition, the performance of the prepared membranes was investigated in terms of basic parameters: filtrate water flux, nitrate removal efficiency, and antifouling properties. Results showed significant improvements of the characteristics of modified... 

    Novel surface modifying macromolecules (SMMs) blended polysulfone gas separation membranes by phase inversion technique

    , Article Journal of Applied Polymer Science ; Volume 124, Issue 3 , 2012 , Pages 2287-2299 ; 00218995 (ISSN) Savoji, H ; Rana, D ; Matsuura, T ; Soltanieh, M ; Tabe, S ; Sharif University of Technology
    2012
    Abstract
    In this article an attempt was made to fabricate defect-free asymmetric polysulfone (PSf) membranes for the separation of oxygen and nitrogen. The approach is based on the enhanced delayed demixing by blending surface modifying macromolecules (SMMs) in the casting solution and by immersing the cast film in isopropanol for a certain period before it is immersed in water. Different SMMs, including hydrophobic and charged SMMs, were synthesized, characterized, and blended to the host PSf. It was found that the charged SMM could indeed contribute to the removal of defective pores from the skin layer and enhancement of oxygen/nitrogen selectivity. The experimental results were further interpreted... 

    Influence of novel surface modifying macromolecules and coagulation media on the gas permeation properties of different polymeric gas separation membranes

    , Article Journal of Applied Polymer Science ; Volume 124, Issue 3 , 2012 , Pages 2300-2310 ; 00218995 (ISSN) Savoji, H ; Rana, D ; Matsuura, T ; Soltanieh, M ; Tabe, S ; Sharif University of Technology
    2012
    Abstract
    Integrally skinned asymmetric membranes for the separation of O 2 and N 2 were fabricated by the phase inversion technique from polysulfone, polyetherimide, and polyimide. Two types of surface modifying macromolecules (SMMs) including hydrophilic SMM (LSMM) and charged SMM (cSMM) were synthesized and blended with the casting solution to modify the membrane surface. The cast film was then immersed in the first coagulant alcohol (methanol, ethanol, or isopropanol) for a predetermined period, before being immersed in the second coagulant (water). The SMMs used in these experiments were laboratory synthesized by the two-step process of polyurethane prepolymer synthesis and end capping, before...