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    Preparation and characterisation of diopside-based glass-ceramic foams

    , Article Ceramics International ; Volume 38, Issue 3 , 2012 , Pages 2005-2010 ; 02728842 (ISSN) Hasheminia, S ; Nemati, A ; Eftekhari Yekta, B ; Alizadeh, P ; Sharif University of Technology
    2012
    Abstract
    Foaming and crystallisation behaviours of compacted glass powders based on a diopside glass-ceramic composition were investigated using the sintering route. The foaming agent was 2 wt.% SiC particles. The effect of PbO on the foaming ability of glasses was investigated. The results showed that the addition of PbO not only improved the foaming ability, by improving the wettability of the glass-SiC particles but also increased the crystallisation temperature and widened the temperature interval between the dilatometric softening point and the onset of crystallisation. The glass-SiC wetting angle was decreased from 85°for the lead-free glass, to 55°for the glass that contains 15 wt.% PbO  

    Extended gibbs free energy and laplace pressure of ordered hexagonal close-packed spherical particles: A wettability study

    , Article Langmuir ; Volume 37, Issue 28 , 2021 , Pages 8382-8392 ; 07437463 (ISSN) Bayat, A ; Ebrahimi, M ; Rahemi Ardekani, S ; Saievar Iranizad, E ; Zaker Moshfegh, A ; Sharif University of Technology
    American Chemical Society  2021
    Abstract
    The wetting property of spherical particles in a hexagonal close-packed (HCP) ordering from extended Gibbs free energy (GFE) and Laplace pressure view points is studied. A formalism is proposed to predict the contact angle (θ) of a droplet on the HCP films and penetration angle (α) of the liquid on the spherical particles. Then, the extended Laplace pressure for the layered HCP ordering is calculated and a correlation between the wetting angle, sign of pressure, and pressure gradient is achieved. Our results show that the sign and the slope of pressure are important criteria for determining the wettability state and it is found that the contact angle is independent of the particle radius, as...