Sharif Digital Repository

TiO2 has been considered the most promising photocatalyst for the degradation of pollutants in air or water; however, it shows poor absorption of visible light and requires ultraviolet (UV) light for activation. We have successfully synthesized a visible-light-active carbon and nitrogen and yttrium tridoped TiO2 catalyst. In this study, Nanocrystalline photocatalysts of TiO2 doped with yttrium, codoped with carbon and nitrogen and tridoped with carbon and nitrogen and yttrium were prepared by the sol–gel method and investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy ( DRS), Scanning electron microscopy (SEM/EDS) and... 

The purpose of this thesis is the construction of hard and tough Zirconia bodies from economical raw materials using minimum sintering time and temperature.
Stabilizers cause tetragonal particles to be remained in cubic phase. Most additives are Ca, Ce, Mg and Y ions the whole of which are rare earth elements and make solid solutions with Zirconia.
In this project different percents of CaO, MgO, CeO2, and Y2O3 were mixed with ZrO2 and they were sintered after granulation, cold pressing and Cold Isostatic Pressing. Using jar milling and fast milling, the particle size of purchased ZrO2 was reduced to 0.7 um. The whole needed additives were purchased with particle size below 300 nm.... 

Biodegradable Mg-Ag alloys are promising implants for bone tissue regeneration due to their unique ability to reduce inflammation and infection after implantation with the presence of silver. However, their biological performance, including biodegradability, needs further improvement. In this regard, the effects of adding yttrium element, solution heat treatment and coating on the microstructure, biodegradability behavior, mechanical properties and biological characteristics of a cast Mg-2Ag alloy were studied. Addition of 1 wt% of yttrium caused grain refinement in the microstructure and solid solution heat treatment led to a significant decrease in the volume fraction of secondary phases.... 

In Mg–Si alloys, both primary and eutectic Mg2Si particles normally appear with sharp edges, which can lead to weak mechanical properties as the result of stress concentration at the sharp corners of these brittle particles. On the other hand, the morphology, size and distribution of Mg2Si particles affect corrosion behavior of Mg–Si alloys. Thus, it would be of great importance to modify the morphology of these particles. In this study, microstructure modification mechanisms after 0.5 wt% Y addition and heat treatment (HT) at 420 ◦C for 24 h are comprehensively studied in hypo-eutectic Mg–1Si and hyper-eutectic Mg–2Si alloys. Microstructural observations were performed using optical and...