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    Kinetics of oxygen adsorption on ZnS nanoparticles synthesized by precipitation process

    , Article Materials Science- Poland ; Volume 34, Issue 2 , 2016 , Pages 260-265 ; 20831331 (ISSN) Ahmadi, R ; Sadrnezhad, S. K ; Namivandi Zangeneh, R ; Oghabian, M. A ; Sharif University of Technology
    Walter de Gruyter GmbH 
    Abstract
    ZnS nanoparticles were synthesized through a one-step precipitation process. Effect of time and temperature on the formation reaction was investigated. The synthesized samples were characterized by X-ray diffraction (XRD), ultraviolet (UV) visible absorption and photoluminescence (PL) spectrophotometry. Based on XRD and UV-Vis data, the particles produced at 70 °C had a mean particle size of about 5 nm. Increasing time and temperature of the synthesis reaction resulted in photoluminescence intensification. PL spectroscopy helped understanding the adsorption kinetics of oxygen on ZnS nanoparticles during the precipitation synthesis process. Fabrication of ZnS structures with appropriate... 

    New blend nanocomposite membranes based on PBI/sulfonated poly(ether keto imide sulfone) and functionalized quantum dot with improved fuel cell performance at high temperatures

    , Article International Journal of Energy Research ; Volume 45, Issue 15 , August , 2021 , Pages 21274-21292 ; 0363907X (ISSN) Hooshyari, K ; Rezania, H ; Vatanpour, V ; Rastgoo Deylami, M ; Rajabi, H. R ; Sharif University of Technology
    John Wiley and Sons Ltd  2021
    Abstract
    In this work, we reported the synthesis of a sulfonated poly(ether keto imide sulfone) (SPEKIS) using a novel aromatic diol containing nitrogen heterocycles and sulfonic monomer. New nanocomposite blend membranes were prepared using obtained SPEKIS and polybenzimidazole (PBI) with the incorporation of zinc sulfide (ZnS) functionalized quantum dots (FQDs) having both -COOH and NH2 groups with a solution-casting method and were used as proton exchange membranes. The SPEKIS and ZnS FQDs were used for the first time in the preparation of new nanocomposite blend membranes based on PBI. The purpose of this study is to investigate the effect of SPEKIS and ZnS FQDs on the PBI membrane performance in...