Kinetic Study of Heterogeneous and Homogeneous Catalytic Reactions in Molecular and Ionic Solvents and Their Mixtures, Ph.D. Dissertation Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor) ; Habibi Yangjeh, Aziz (Supervisor)
Abstract
Solvatochromic parameters (ETN: normalized polarity parameter, π*: dipolarity/polarizability, β: hydrogen-bond acceptor basicity, α: hydrogen-bond donor acidity) have been determined for binary mixtures of propan-2-ol, propan-1-ol, ethanol, methanol and water with recently synthesized ionic liquid (2-hydroxyethylammonium formate) at 25 ◦C. The applicability of nearly ideal combined binary solvent/Redlich-Kister equation was proved for the correlation of various solvatochromic parameters with solvent composition. Solute-solvent and solvent-solvent interactions were applied to interpret the results. Heterogeneous catalytic hydrogenation of cyclohexene, catalyzed by Pt/Al2O3, was carried out in...
Cataloging briefKinetic Study of Heterogeneous and Homogeneous Catalytic Reactions in Molecular and Ionic Solvents and Their Mixtures, Ph.D. Dissertation Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor) ; Habibi Yangjeh, Aziz (Supervisor)
Abstract
Solvatochromic parameters (ETN: normalized polarity parameter, π*: dipolarity/polarizability, β: hydrogen-bond acceptor basicity, α: hydrogen-bond donor acidity) have been determined for binary mixtures of propan-2-ol, propan-1-ol, ethanol, methanol and water with recently synthesized ionic liquid (2-hydroxyethylammonium formate) at 25 ◦C. The applicability of nearly ideal combined binary solvent/Redlich-Kister equation was proved for the correlation of various solvatochromic parameters with solvent composition. Solute-solvent and solvent-solvent interactions were applied to interpret the results. Heterogeneous catalytic hydrogenation of cyclohexene, catalyzed by Pt/Al2O3, was carried out in...
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