Synthesis, Characterization and Spectroscopic Studies of Novel Mono and bi Nuclear Zinc(II), Palladium(II) and Cobalt(II) Schiff Base Complexes: Reactivity and Interaction, Ph.D. Dissertation Sharif University of Technology ; Mohammadi Boghaei, Davar (Supervisor)
Abstract
Due to study of reactivity and interaction of Schiff base complexes, as models of biological system such as vitamin B (B6 and B12) and enzyme (cytochtome c oxidase), some mono and binuclear Zn(II), Pd(II) and Co(II) Schiff base complexes were synthesized and characterized. As a model for vitamin B6, tridentate Schiff base ligands derived from the condensation of water soluble aldehyde with the amino acids (glycine, L-alanine, L-valine, L-leucine and L-phenylalanine) in the presence of Zn (OAc)2.2H2O give rise to the formation of five new water soluble Zn(II) complexes. The IR spectra of these complexes show that, there are prominent stretching vibration of the azomethine band (HC=N) at...
Cataloging briefSynthesis, Characterization and Spectroscopic Studies of Novel Mono and bi Nuclear Zinc(II), Palladium(II) and Cobalt(II) Schiff Base Complexes: Reactivity and Interaction, Ph.D. Dissertation Sharif University of Technology ; Mohammadi Boghaei, Davar (Supervisor)
Abstract
Due to study of reactivity and interaction of Schiff base complexes, as models of biological system such as vitamin B (B6 and B12) and enzyme (cytochtome c oxidase), some mono and binuclear Zn(II), Pd(II) and Co(II) Schiff base complexes were synthesized and characterized. As a model for vitamin B6, tridentate Schiff base ligands derived from the condensation of water soluble aldehyde with the amino acids (glycine, L-alanine, L-valine, L-leucine and L-phenylalanine) in the presence of Zn (OAc)2.2H2O give rise to the formation of five new water soluble Zn(II) complexes. The IR spectra of these complexes show that, there are prominent stretching vibration of the azomethine band (HC=N) at...
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