Synthesis and Study of Coordination Properties of Axial Ligands Pendant to Fullerene C60, M.Sc. Thesis Sharif University of Technology ; Ghanbari, Bahram (Supervisor)
Abstract
The aim of this study at the outset is synthesis of ligands with the ability to bridge formation between two groups i.e. C60 and Cobalt Schiff base complex (CoSALEN). Hence, four Schiff base ligands with pyridine electron donor moiety in one side, and such electron donor moiety pyridine, phenol and aniline in another side were synthesized and characterized by elemental analysis, 13C¬NMR, 1HNMR and IR Spectroscopy. In next step the interaction of these Schiff base ligands with CoSALEN complex and Fullerene C60, in the mixture of two solvents, i.e. toluene/dimethylsulfoxide and benzene/methanol was explored separately by UV-Visible Spectroscopy and their kinetic studies were also undertaken...
Cataloging briefSynthesis and Study of Coordination Properties of Axial Ligands Pendant to Fullerene C60, M.Sc. Thesis Sharif University of Technology ; Ghanbari, Bahram (Supervisor)
Abstract
The aim of this study at the outset is synthesis of ligands with the ability to bridge formation between two groups i.e. C60 and Cobalt Schiff base complex (CoSALEN). Hence, four Schiff base ligands with pyridine electron donor moiety in one side, and such electron donor moiety pyridine, phenol and aniline in another side were synthesized and characterized by elemental analysis, 13C¬NMR, 1HNMR and IR Spectroscopy. In next step the interaction of these Schiff base ligands with CoSALEN complex and Fullerene C60, in the mixture of two solvents, i.e. toluene/dimethylsulfoxide and benzene/methanol was explored separately by UV-Visible Spectroscopy and their kinetic studies were also undertaken...
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