Synthesis of Dithiocarbamate Derivatives and Aminolysis of Epoxides in Water and under Different Conditions, M.Sc. Thesis Sharif University of Technology ; Saeedi, Mohammad Reza (Supervisor) ; Ziyaei Halimehjani, Azim (Supervisor)
Abstract
This research project contains two parts that investigating new approaches for becoming closer to green chemistry principals is clear in it. In the first part we tried to synthesis dithiocarbamate salts using aromatic amins and than Michael addition of them to prepare bifunctional dithiocarbamats. But we found ?-thiols as final product. In the second part of this project, we investigated the regioselective epoxide ring opening with aromatic amines by using boric acid and glycerol in water as a green media. Corresponding ?-amino alcohols were obtained with excellent yields and considerable regioselectivity. High yields of the products, mild reaction conditions, using green catalyst and water...
Cataloging briefSynthesis of Dithiocarbamate Derivatives and Aminolysis of Epoxides in Water and under Different Conditions, M.Sc. Thesis Sharif University of Technology ; Saeedi, Mohammad Reza (Supervisor) ; Ziyaei Halimehjani, Azim (Supervisor)
Abstract
This research project contains two parts that investigating new approaches for becoming closer to green chemistry principals is clear in it. In the first part we tried to synthesis dithiocarbamate salts using aromatic amins and than Michael addition of them to prepare bifunctional dithiocarbamats. But we found ?-thiols as final product. In the second part of this project, we investigated the regioselective epoxide ring opening with aromatic amines by using boric acid and glycerol in water as a green media. Corresponding ?-amino alcohols were obtained with excellent yields and considerable regioselectivity. High yields of the products, mild reaction conditions, using green catalyst and water...
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