Dynamic NMR Study of Ethyl N-(pipyridin carbotioate), M.Sc. Thesis Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
In this project rotational barrier around the C-N bond in Ethyl N-(pipyridin carbotioate) has been studied by using DNMR spectroscopy. Spectra were taken at various temperatures , and then with simulation of bandshape broadening pattern at coalescence region, the exchange rate constant of were obtained for all temperatures. For simulation of line-shpe broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from the simulation were used for calculation of thermodynamic activation parameters (...
Cataloging briefDynamic NMR Study of Ethyl N-(pipyridin carbotioate), M.Sc. Thesis Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
In this project rotational barrier around the C-N bond in Ethyl N-(pipyridin carbotioate) has been studied by using DNMR spectroscopy. Spectra were taken at various temperatures , and then with simulation of bandshape broadening pattern at coalescence region, the exchange rate constant of were obtained for all temperatures. For simulation of line-shpe broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from the simulation were used for calculation of thermodynamic activation parameters (...
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