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Synthesis of dithiocarbamates by Markovnikov addition reaction in PEG and their application in amidoalkylation of naphthols and indoles

Halimehjani, A. Z ; Sharif University of Technology | 2015

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  1. Type of Document: Article
  2. DOI: 10.5935/0103-5053.20150119
  3. Publisher: Sociedade Brasileira de Quimica , 2015
  4. Abstract:
  5. Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles
  6. Keywords:
  7. Alkyl vinyl ether ; Dithiocarbamate ; Markovnikov addition ; N-vinylpyrrolidone ; Polyethylene glycol
  8. Source: Journal of the Brazilian Chemical Society ; Volume 26, Issue 7 , 2015 , Pages 1500-1508 ; 01035053 (ISSN)
  9. URL: http://www.crossref.org/iPage?doi=10.5935%2F0103-5053.20150119