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ONO pincer type binuclear Pd(II) complex: Synthesis, crystal structure and catalytic utilization of the resulting organopalladium complex in catalytic copper-free Sonogashira coupling reaction
Bagherzadeh, M ; Sharif University of Technology | 2016
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- Type of Document: Article
- DOI: 10.1016/j.ica.2016.07.032
- Publisher: Elsevier S.A , 2016
- Abstract:
- New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed excellent catalytic activity towards the copper-free Sonogashira cross coupling reaction. The main advantages over previous methodologies include low catalyst loading, less problematic reaction media (H2O–DMSO) and reusability in homogenous systems for optimal performance
- Keywords:
- Crystal structure ; Organopalladium ; Pincer complex ; Sonogashira coupling reaction
- Source: Inorganica Chimica Acta ; Volume 451 , 2016 , Pages 227-232 ; 00201693 (ISSN)
- URL: http://www.sciencedirect.com/science/article/pii/S0020169316304108