Crystal Engineering and Interaction Energy Calculation of Some New Rhenium(I) Tricarbonyl Complexes Bearing Bidentate NN-donor Ligand: Transmetallation of Rhenium(I) Tricarbonyl and Copper(I) Iodide, M.Sc. Thesis Sharif University of Technology ; Kia, Reza (Supervisor)
Abstract
In this research, synthesis, structural and theoretical studies of rhnium(I) tricarbonyl complexes with general formula, fac-[Re(CO)3(NN)X] in which NN´ is chelating bidentate diimine ligand and X = Cl, Br, and OCOCF3 ligands were studied. The synthesized complexes were characterized by 1H-NMR and FTIR spectroscopic methods and their solid state structures were determined by X-ray diffraction analysis. Then, the reaction of the synthesized rhenium complexes were studied by copper(I) iodide. Crystal structure determination by single-crystal X-ray diffraction allows us to fully examine the intramolecular and intermolecular interactions. We also investigated the energy of different...
Cataloging briefCrystal Engineering and Interaction Energy Calculation of Some New Rhenium(I) Tricarbonyl Complexes Bearing Bidentate NN-donor Ligand: Transmetallation of Rhenium(I) Tricarbonyl and Copper(I) Iodide, M.Sc. Thesis Sharif University of Technology ; Kia, Reza (Supervisor)
Abstract
In this research, synthesis, structural and theoretical studies of rhnium(I) tricarbonyl complexes with general formula, fac-[Re(CO)3(NN)X] in which NN´ is chelating bidentate diimine ligand and X = Cl, Br, and OCOCF3 ligands were studied. The synthesized complexes were characterized by 1H-NMR and FTIR spectroscopic methods and their solid state structures were determined by X-ray diffraction analysis. Then, the reaction of the synthesized rhenium complexes were studied by copper(I) iodide. Crystal structure determination by single-crystal X-ray diffraction allows us to fully examine the intramolecular and intermolecular interactions. We also investigated the energy of different...
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