Synthesis and Application of Heterogeneous Catalysts in Oxidative C-O Coupling by Direct C-H Bond Activation of Formamides, M.Sc. Thesis Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of carbamates under optimal conditions. The robust MOF catalyst was built based on magnetic nanoparticles and HKUST-1 which further modified with thioacetamide and carbonization. The catalyst structure was confirmed by various techniques. Furthermore, the products’ yields were obtained in good to excellent for all reactions under mild conditions which result from superior activity of the synthesized heterogeneous catalyst containing Cupper. Also, the magnetic property of the MOF-based catalyst makes it easy to separate from reaction mediums and reuse in the next runs. In summary, the...
Cataloging briefSynthesis and Application of Heterogeneous Catalysts in Oxidative C-O Coupling by Direct C-H Bond Activation of Formamides, M.Sc. Thesis Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of carbamates under optimal conditions. The robust MOF catalyst was built based on magnetic nanoparticles and HKUST-1 which further modified with thioacetamide and carbonization. The catalyst structure was confirmed by various techniques. Furthermore, the products’ yields were obtained in good to excellent for all reactions under mild conditions which result from superior activity of the synthesized heterogeneous catalyst containing Cupper. Also, the magnetic property of the MOF-based catalyst makes it easy to separate from reaction mediums and reuse in the next runs. In summary, the...
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