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Electrochemical oxidation of catechol in the presence of 2-thiouracil: Application to electro-organic synthesis
Shahrokhian, S ; Sharif University of Technology | 2003
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- Type of Document: Article
- DOI: 10.1016/S1388-2481(03)00170-X
- Publisher: Elsevier Inc , 2003
- Abstract:
- The electrochemical oxidation of catechol in the presence of 2-thiouracil (as a nucleophile) has been studied in aqueous solutions using cyclic voltammetry and controlled-potential coulometric techniques. The results indicate that catechol participating in a 1,4 (Michael) addition reaction converts to a new thiadiazafluorenone compound. The electrochemical synthesis of this compound has been successfully performed in an undivided cell in a good yield and purity and was characterized by IR, 1H and 13C NMR, mass spectrometry and elemental analysis. © 2003 Published by Elsevier B.V
- Keywords:
- 2-Thiouracil ; Catechol ; Electro-organic synthesis ; Thiadiazafluorenone
- Source: Electrochemistry Communications ; Volume 5, Issue 8 , 2003 , Pages 706-710 ; 13882481 (ISSN)
- URL: https://www.sciencedirect.com/science/article/pii/S138824810300170X