Electrocatalytic oxidation of L-ascorbic acid (L-AA) on silver electrode in alkaline solutions was studied employing cyclic voltammetry, chronoamperometry and impedance spectroscopy techniques. In comparison to Pt, the onset potential for L-AA electro-oxidation process on Ag, in a solution containg 0.02 M L-AA and 0.5 M NaOH, was 0.1 V more negative. Also, L-AA oxidation current increased more than 900% at -0.26 V/SCE. According to voltammety and impedance spectropy findings, although hydroxide anion presence was vital for L-AA oxidation to occur, at potentials more positive than -0.2 V/SCE, hydroxide ion tends to inhibit the oxidation process. Studies on the L-AA oxidation process on Ag in...