Synthesis, X-ray studies, and catalytic activity of tridentate Schiff base dioxo-molybdenum(VI)

Amini, M ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1080/00958972.2014.939076
  3. Abstract:
  4. The reaction of a solution of MoO2(acac)2 in CH3OH and salicylidene 2-picoloyl hydrazone as a tridentate ONO donor Schiff base (ONO) afford a six-coordinated Mo(VI) complex [MoO2(ONO)(CH3OH)], with a distorted octahedral configuration. [MoO2(ONO)(CH3OH)] was isolated as an air-stable crystalline solid and fully characterized by single-crystal X-ray structure analysis. [MoO2(ONO)(CH3OH)] shows reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide as the oxidant at room temperature under air
  5. Keywords:
  6. Crystal structure ; Dioxo-Mo(VI) complex ; Schiff base ; Sulfide oxidation
  7. Source: Journal of Coordination Chemistry ; Volume 67, Issue 14 , 2014 ; ISSN: 00958972
  8. URL: http://www.tandfonline.com/doi/abs/10.1080/00958972.2014.939076#.Vd1MeLW5JIE