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Selective oxidation of sulfides to sulfoxides by a molybdate-based catalyst using 30% hydrogen peroxide

Bayat, A ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1016/j.catcom.2014.03.026
  3. Abstract:
  4. An efficient method is reported for selective oxidation of various types of sulfides to sulfoxides and sulfones in good to high yields using 30% H 2O2 in the presence of catalytic amounts of molybdate-based catalyst in acetonitrile as solvent at room temperature. The catalyst can be easily recovered and reused for seven reaction cycles without considerable loss of activity
  5. Keywords:
  6. Highly reusable catalyst ; Molybdate anion ; Catalytic oxidation ; Hydrogen peroxide ; Negative ions ; Organic solvents ; Oxidation ; Peroxides ; Catalytic amounts ; Heterogeneous ; High yield ; Magnetic nano-particles ; Reaction cycles ; Reusable catalysts ; Room temperature ; Selective oxidation ; Catalysts
  7. Source: Catalysis Communications ; Vol. 52, issue , July , 2014 , pp. 16-21 ; ISSN: 15667367
  8. URL: http://www.sciencedirect.com/science/article/pii/S1566736714001204