Molybdenum(VI)-oxodiperoxo complex containing an oxazine ligand: Synthesis, X-ray studies, and catalytic activity

Amini, M ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1080/00958972.2014.915525
  3. Abstract:
  4. A new mononuclear molybdenum(VI)-oxodiperoxo complex [MoO(O 2)2(phox)] with a simple bidentate ligand, 2-(2′-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (Hphox), has been synthesized and characterized by X-ray structure analysis, elemental analysis, infrared, and 1H NMR spectroscopy. A triclinic space group P-1 was determined by X-ray crystallography from single-crystal data of this complex. The resulting complex functioned as a facile sulfide oxidation catalyst with urea hydrogen peroxide as terminal oxidant at room temperature. The catalyst showed efficient reactivity in oxidation of sulfides giving high yield and selectivity
  5. Keywords:
  6. Crystal structure ; Molybdenum complex ; Oxazine ; Oxidation ; Oxodiperoxo
  7. Source: Journal of Coordination Chemistry ; Vol. 67, issue. 8 , Jul , 2014 , pp. 1429-1436 ; ISSN: 00958972
  8. URL: http://www.tandfonline.com/doi/abs/10.1080/00958972.2014.939076#.VeQr8H25JIE