Catalytic efficacy of an oxido-peroxido tungsten(VI) complex: Synthesis, X-ray structure and oxidation of sulfides and olefins

Amini, M ; Sharif University of Technology | 2013

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  1. Type of Document: Article
  2. DOI: 10.1080/00958972.2013.794383
  3. Publisher: 2013
  4. Abstract:
  5. An oxido-peroxido tungsten(VI) complex [WO(O2)L(CH 30H)] using salicylidene benzoyl hydrazine as a tridentate ONO donor Schiff base (H2L) has been synthesized and characterized by elemental analysis, IR, 1H NMR, molar conductance data, and single-crystal X-ray analysis. The complex was used as a catalyst for epoxidation of olefins and oxidation of sulfides. The results show that epoxides and sulfoxides were produced in high yield, turnover number, and selectivity
  6. Keywords:
  7. Olefin epoxidation ; Oxido-peroxido complex ; Sulfide oxidation ; Tungsten
  8. Source: Journal of Coordination Chemistry ; Volume 66, Issue 11 , Jan , 2013 , Pages 1897-1905 ; 00958972 (ISSN)
  9. URL: http://www.tandfonline.com/doi/abs/10.1080/00958972.2013.794383