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A simple approach to the synthesis of 3-substituted rhodanines and thiazolidine-2,4-diones

Aryanasab, F ; Sharif University of Technology | 2013

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  1. Type of Document: Article
  2. Publisher: Sharif University of Technology , 2013
  3. Abstract:
  4. A novel synthesis of 3-substituted rhodanine and thiazolidine-2,4-dione derivatives, starting from aliphatic primary amines, carbon disulfide, and methyl 2-bromoacetate, is described. The reaction proceeds successfully both in water and under solvent-free conditions, but 2-thioxothiazolidin-4-one (rhodanine) derivatives were obtained under solvent free-conditions, and thiazolidine-2,4-dions were formed when water was used as the solvent
  5. Keywords:
  6. 3-substituted rhodanines ; Solvent-free ; Thiazolidine-2,4-diones ; Carbon disulfide ; Synthesis (chemical) ; Aliphatic primary amines ; Rhodanine ; Rhodanines ; Simple approach ; Solvent free ; Solvent free conditions ; Thiazolidines ; Solvents ; Acetate ; Amino acid ; Solvent
  7. Source: Scientia Iranica ; Volume 20, Issue 6 , 2013 , Pages 1833-1838 ; 10263098 (ISSN)
  8. URL: http://www.scientiairanica.com/en/ManuscriptDetail?mid=62