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Synthesis and crystal structure of bis (tetrabutylammonium)(4,4′- azodi(phenylcyanamide)) salt • [(n-Bu)4N] 2[azodicyd2-] • H2O

Boghaei, D. M ; Sharif University of Technology | 2008

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  1. Type of Document: Article
  2. DOI: 10.1007/s10870-007-9313-7
  3. Publisher: 2008
  4. Abstract:
  5. The chemical preparation and crystal structure for a 4,4′- azodi(phenylcyanamide) salt) in the solid state are reported. This compound crystallizes in the triclinic space group P with the following unit cell parameters: a = 9.759(3) Å, b = 11.237(4) Å, c = 11.919(4) Å, α = 95.54(3)°, β = 98.50(3)°, γ = 109.39(2)°, Z = 1 and V = 1204.4(7) Å3. The 4,4′-azodi(phenylcyanamide) dianion, azodicyd2-, is approximately planar, with the cyanamide groups (-N=C=N) in an anti conformation relative to each other and the azo group (-N=N-) adopting the more thermodynamically stable trans conformation. The crystal X-ray analysis shows that there are one azo molecule cation, two tetrabutylammonium cations and one water molecule in unit cell. Intermolecular O-H•••N hydrogen bonds may be effective in the stabilization of the crystal structure of this compound and to form linear chain structure in the packing. Synthesis and crystal structure of Bis (Tetrabutylammonium)(4, 4′-Azodi(phenylcyanamide)) salt . [(n-Bu)4N]2[Azodicyd2-] • H2O[Figure not available: see fulltext.] Davar M. Boghaei 1, Fatemeh Behzadian-Asl 1 and Hamid Reza Khavasi 2 1 Department of Chemistry, Sharif University of Technology, P.O. Box 11155-9616, Tehran, Iran 2 Department of Chemistry, Shahid Beheshti University, Evin, Tehran 1983963113, Iran © 2007 Springer Science+Business Media, LLC
  6. Keywords:
  7. 4,4′-Azodi(phenylcyanamide) ; Hydrogen bond ; Cyanamide groups ; Crystal structure
  8. Source: Journal of Chemical Crystallography ; Volume 38, Issue 4 , 2008 , Pages 311-314 ; 10741542 (ISSN)
  9. URL: https://link.springer.com/article/10.1007/s10870-007-9313-7