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carbon-nanotubes
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Carbon-based nanocomposites: Distinguishing between deep-bed filtration and external filter cake by coupling core-scale mud-flow tests with computed tomography imaging
, Article Journal of Natural Gas Science and Engineering ; Volume 105 , 2022 ; 18755100 (ISSN) ; Fouji, M ; Ghorbani Heidarabad, R ; Aghaei, H ; Hajiabadi, S. H ; Bedrikovetsky, P ; Mahani, H ; Sharif University of Technology
Elsevier B.V
2022
Abstract
Although Multi-Walled Carbon NanoTubes (MWCNTs) are found to influence the rheological behavior of drilling fluids, there are yet some controversies regarding their performance towards reducing formation damage induced by the invasion of water-based drilling fluids (WBFs). To address this important question, we synthesized novel nanocomposite materials via modifying the MWCNT via varying the proportion of carboxylated MWCNTs to PolyVinyl Alcohol (PVA). These nanocomposites were then used to make nano-based drilling-fluids (NDFs). The performance of the NDFs was evaluated by a set of rheological behavior tests, filtration experiments, and core-scale mud flow tests. To distinguish between the...
Synergistic effects of MWCNTs and high-pressure torsion-induced grain refinement on microhardness, tribological properties, and corrosion behavior of Cu and Cu/MWCNT nanocomposites
, Article Metals and Materials International ; Volume 28, Issue 9 , 2022 , Pages 2197-2215 ; 15989623 (ISSN) ; Mirabad, H. M ; Golenji, R. B ; Kakaei, K ; Kim, H. S ; Sharif University of Technology
Korean Institute of Metals and Materials
2022
Abstract
In this study, ultra-fine grained Cu and Cu + carbon nanotube (CNT) nanocomposites were prepared through a processes combining flake powder metallurgy, hot pressing, and high-pressure torsion (HPT). The effects of grain refinement and CNT reinforcement on the microstructure, hardness, wear resistance, and corrosion behavior of the newly developed nanocomposites were investigated. The results indicated that the HPT process decreased the grain size of Cu and Cu + CNT by 67.7% and 68.1%, respectively, and increased their microhardness by 151% and 132%. The addition of CNTs substantially improved the tribological behavior of Cu by generating a mechanically mixed carbon- and oxide-rich layer....
Vibration analysis of size dependent micro FML cylindrical shell reinforced by CNTs based on modified couple stress theory
, Article Arabian Journal of Chemistry ; Volume 15, Issue 10 , 2022 ; 18785352 (ISSN) ; Hooman, M ; Yarigarravesh, M ; Algarni, M ; Jade Catalan Opulencia, M ; Alsaikhan, F ; Turki Jalil, A ; Mohamed, A ; M.AboRas, K ; Lutfor Rahman, M ; Sani Sarjadi, M ; Sharif University of Technology
Elsevier B.V
2022
Abstract
In this manuscript, the sequel of agglomeration on the vibration of fiber metal laminated (FML) cylindrical shell in the micro phase using developed couple stress theory (MCST). Hamilton's principle has been carried out for deriving the non-classical equations of motion of size-dependent thin micro cylindrical shell on the basis of Love's first approximation theory. Mori-Tanaka and extended rule of mixture are utilized to estimate the mechanical attributes of carbon nanotubes (CNTs) and equivalent fiber, respectively. These four phases CNTs/fiber/polymer/metal laminated (CNTFPML) micro cylindrical shell is analyzed applying beam modal function model for several boundary limitations. Then, an...
The impact of employing carbon nanotube and Fe3O4 nanoparticles along with intermediate boiling fluid to improve the discharge rate of phase change material
, Article Applied Thermal Engineering ; Volume 215 , 2022 ; 13594311 (ISSN) ; Rahgozar Abadi, I ; Mohammadi, O ; Khademi, A ; Behshad Shafii, M ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
Despite the fact that solid–liquid phase change materials (PCMs) have various applications in thermal energy storage systems, the low solidification rate of PCMs, which is due to the low thermal conductivity has limited the range of applications of PCMs. One of the methods of increasing the solidification rate of PCMs is using a boiling fluid as an intermediary between the solid–liquid PCM and the condenser to prevent the direct contact between the phase change material and the condenser tubes, this method is also known as the intermediate boiling fluid (IBF) method. The IBF method has been shown to significantly increase the solidification rate (2 orders of magnitude). In this study, the...
Carbon-based nanocomposite decorated with bioactive glass and CoNi2S4 nanoparticles with potential for bone tissue engineering
, Article OpenNano ; Volume 8 , 2022 ; 23529520 (ISSN) ; Aldhaher, A ; Ahmadi, S ; Baheiraei, N ; Rabiee, N ; Sharif University of Technology
Elsevier Inc
2022
Abstract
In this work, for the first time, different forms of nanocomposites based on rGO and MWCNT were prepared in conjoining with the bioactive glass (BioGlass). In the carbonic layers, a highly toxic nanoparticle, CoNi2S4, was intercalated, and the role of this nanoparticle in the alkaline phosphatase activity, relative cell viability on different cell lines, and also the effect on the cell walls and cell morphologies were investigated. From another perspective, the ability of the chemotherapy drug loading to the prepared nanocomposites was investigated, and the use of leaf extracts was thought of as a green method to lower the cytotoxicity and regulate the genotoxicity of the generated...
A study on the cementitious mortars containing multi-walled carbon nanotubes and nanographene
, Article Journal of Testing and Evaluation ; Volume 51, Issue 2 , 2022 ; 00903973 (ISSN) ; Toufigh, V ; Sharif University of Technology
ASTM International
2022
Abstract
In this paper, the effects of the multi-walled carbon nanotubes (MWCNTs) and nanographene (GP) on the mechanical performance of the cementitious mortars were investigated in different environments. Six mix designs were fabricated by considering the previous studies and exposed to potable water, acidic, and alkaline environments. The GP and MWCNTs partially replaced the cement with 0.25 %, 0.5 %, and 1 % of its weight. The standard mechanical tests, X-ray diffraction (XRD), and scanning electron microscope (SEM) analysis were performed on the specimens. The results indicated that including the MWCNTs and GP increases the compressive strength by 10 % and 20 % and similarly improves the tensile...
Unified modeling and experimental realization of electrical and thermal percolation in polymer composites
, Article Applied Physics Reviews ; Volume 9, Issue 4 , 2022 ; 19319401 (ISSN) ; Arabshahi, Z. S ; Saberi, A. A ; Moshfegh, A. Z ; Sharif University of Technology
American Institute of Physics Inc
2022
Abstract
Correlations between electrical and thermal conduction in polymer composites are blurred due to the complex contribution of charge and heat carriers at the nanoscale junctions of filler particles. Conflicting reports on the lack or existence of thermal percolation in polymer composites have made it the subject of great controversy for decades. Here, we develop a generalized percolation framework that describes both electrical and thermal conductivity within a remarkably wide range of filler-to-matrix conductivity ratios (Y f / Y m), covering 20 orders of magnitude. Our unified theory provides a genuine classification of electrical conductivity with typical Y f / Y m ≥ 10 10 as...
Controlled optical near-field growth of individual free-standing well-oriented carbon nanotubes, application for scattering SNOM/AFM probes
, Article Nanophotonics ; Volume 11, Issue 21 , 2022 , Pages 4671-4686 ; 21928614 (ISSN) ; Heydarian, H ; Rashidian, B ; Sharif University of Technology
De Gruyter Open Ltd
2022
Abstract
Exploiting localized heat-generation density and the resulting enhanced temperature-rise for controlled growth of carbon nanotubes (CNTs) is reported, and its potentials for batch-production of high-quality CNT probes are demonstrated. Optical near field chemical vapor deposition (ONF-CVD) benchtop fabrication schemes are developed for the localized integration of individual well-aligned carbon nanotubes without bending/buckling exactly at desired nanoscale sites. It is demonstrated that generating self-aligned catalyst nanoparticles superimposed on top of silicon nanotips, along with near-field induced absorption confinement, provide the ability to localize the generated heat at the...
Plasmon-induced near-infrared fluorescence enhancement of single-walled carbon nanotubes
, Article Carbon ; Volume 194 , 2022 , Pages 162-175 ; 00086223 (ISSN) ; Tsoulos, T. V ; Sajjadi, S. H ; Antonucci, A ; Wu, S. J ; Tagliabue, G ; Fatmehsari Haghshenas, D ; Boghossian, A. A ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
Single-walled carbon nanotubes (SWCNTs) emit near-infrared (NIR) fluorescence that is ideal for optical sensing. However, the low quantum yields diminish the sensor's signal-to-noise ratio and limits the penetration depths for in vivo measurements. In this study, we perform a systematic investigation of the plasmonic effects of Ag and Au nanoparticles of various geometries to tune and even enhance the fluorescence intensity of single-stranded DNA-wrapped SWCNTs (ssDNA-SWCNTs). We observe a chirality-dependent NIR fluorescence enhancement that varies with both nanoparticle shape and material, with Au nanorods increasing (7, 5) and (7, 6) chirality emissions by 80% and 60% and Ag nanotriangles...
Experimental investigation and finite element modelling of PMMA/carbon nanotube nanobiocomposites for bone cement applications
, Article Soft Matter ; Volume 18, Issue 36 , 2022 , Pages 6800-6811 ; 1744683X (ISSN) ; Khakbiz, M ; Chagami, M ; Bagheri, R ; Chashmi, F. S ; Akbari, B ; Shakibania, S ; Lee, K. B ; Sharif University of Technology
Royal Society of Chemistry
2022
Abstract
Multi-walled carbon nanotubes (MWCNTs) are one of the preferred candidates for reinforcing polymeric nanobiocomposites, such as acrylic bone type of cement. In this study, at first, bulk samples of the reinforced polymethylmethacrylate (PMMA) matrix were prepared with 0.1, 0.25, and 0.5 wt per wt% of MWCNTs by the casting method. Tensile and three-point bending tests were performed to determine the essential mechanical properties of bone cement, such as tensile and bending strengths. The tensile fracture surfaces were investigated by scanning electron microscopy (SEM). The commercial software (Abaqus) was used to conduct finite element analysis (FEA) by constructing a representative volume...
PO43--Loaded zif-8-type metal-organic framework-decorated multiwalled carbon nanotube synthesis and application in silane coatings for achieving a smart corrosion protection performance
, Article Industrial and Engineering Chemistry Research ; Volume 61, Issue 32 , 2022 , Pages 11747-11765 ; 08885885 (ISSN) ; Ramezanzadeh, M ; Fedel, M ; Ramezanzadeh, B ; Mahdavian, M ; Sharif University of Technology
American Chemical Society
2022
Abstract
In this research study, interfacial assembled nanoporous zeolitic imidazolate framework (ZIF-8) multiwalled oxidized carbon nanotubes (MW-OCNTs) were developed and introduced into a silane coating. To analyze the destructive behavior of the nanoparticles exposed to salty solutions with three distinctive pHs of 2, 7.5, and 12, various types of tests such as X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and inductively coupled plasma (ICP) were accomplished. The XRD test revealed that the main characteristic peaks of ZIF-8 were eliminated and/or their intensity decreased. In accordance with the obtained data from the XRD test, nanoparticles at pH = 2 had been...
MgO-incorporated carbon nanotubes-reinforced Mg-based composites to improve mechanical, corrosion, and biological properties targeting biomedical applications
, Article Journal of Materials Research and Technology ; Volume 20 , 2022 , Pages 976-990 ; 22387854 (ISSN) ; Shamsipur, A ; Bakhsheshi-Rad, H. R ; Keshavarz, M ; Kehtari, M ; Ramakrishna, S ; Berto, F ; Sharif University of Technology
Elsevier Editora Ltda
2022
Abstract
In this study, magnesium oxide (MgO) nanoparticles are incorporated on carbon nanotubes (CNTs) to reinforce Mg-3Zn-1Mn alloy (ZM31 alloy) by semi-powder metallurgy, followed by hot extrusion, with the purpose of improving the mechanical and biological properties of Mg-based alloy. The microstructural analysis of the nanocomposites indicated a reduction in grain size of Mg alloy with the incorporation of CNTs with a maximum reduction of 61% (ZM31/CNTs), with further reduction in grain size (68%) detected when MgO integrated CNTs composites (ZM31/MgO-CNTs). The compression characteristics of the composites indicate an increase in ultimate compressive strength of 36% and 44%, respectively, with...
Gold nanorods for drug and gene delivery: An overview of recent advancements
, Article Pharmaceutics ; Volume 14, Issue 3 , 2022 ; 19994923 (ISSN) ; Mousazadeh, M ; Taji, S ; Bahmani, A ; Zarepour, A ; Zarrabi, A ; Sharifi, E ; Azimzadeh, M ; Sharif University of Technology
MDPI
2022
Abstract
Over the past few decades, gold nanomaterials have shown great promise in the field of nanotechnology, especially in medical and biological applications. They have become the most used nanomaterials in those fields due to their several advantageous. However, rod-shaped gold nanoparticles, or gold nanorods (GNRs), have some more unique physical, optical, and chemical properties, making them proper candidates for biomedical applications including drug/gene delivery, photothermal/photodynamic therapy, and theranostics. Most of their therapeutic applications are based on their ability for tunable heat generation upon exposure to near-infrared (NIR) radiation, which is helpful in both...
Rectilinear motion of carbon nanotube on gold surface
, Article International Journal of Mechanical Sciences ; Volume 217 , 2022 ; 00207403 (ISSN) ; Youzi, M ; Vaezi, M ; Nejat Pishkenari, H ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
For many years, it has been a significant concern for nanoscience researchers to synthesize nanomachines with steerable motion. Despite the notable number of studies on the motion of nanocars on a surface, the motion characteristics of carbon nanotubes received less attention. Remarkable features such as symmetry, strength, and stiffness made carbon nanotubes (CNTs) a proper option as wheels in the nanocars. In this paper, for the first time, the motion of carbon nanotube on a gold substrate and its advantages over previous wheels such as fullerene and p-carborane are investigated. We demonstrate that contrary to the other wheels, CNT moves in a directed path, making them an ideal option as...
Investigation on dynamic stability and aeroelastic characteristics of composite curved pipes with any yawed angle
, Article Composite Structures ; Volume 284 , 2022 ; 02638223 (ISSN) ; Chen, J ; Duan, R ; Habibi, M ; Khadimallah, M. A ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
For the first time, in the current work, a dynamic stability analysis of a tilted curved pipe in a supersonic airflow under thermal loading is presented. The heat-transfer continuum problem is used for simulating the thermal environment conditions. The tilted pipe is reinforced by carbon nanotube agglomerations (CNTAs). For simulating the displacement fields of the current structure, Quasi-2D refined high order shear deformation theory is studied. The verification segment is divided into two parts. In the first and second sections, the credibility of the results of this study are confirmed by the results extracted using COMSOL multiphysics software and published articles in the literature,...
Facile electrochemical detection of morpholine in boiler water with carbon nanostructures: a comparative study of graphene and carbon nanotubes
, Article Bulletin of Materials Science ; Volume 45, Issue 2 , 2022 ; 02504707 (ISSN) ; dos Santos Castro Assis, K. L ; Paiva, V. M ; Hashempour, M ; Bestetti, M ; de Araújo, J. R ; D’Elia, E ; Sharif University of Technology
Springer
2022
Abstract
Two electrochemical sensors based on modified glassy carbon electrodes with carbon nanostructures as graphene (GCE–EG) and carbon nanotubes (GCE–CNT) were evaluated for morpholine analysis. The carbon nanostructures were obtained and characterized using X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy and cyclic voltammetry. All spectroscopic and microscopic techniques confirmed the procurement of graphene and CNT. The electrochemical studies proved the efficient behaviour of both electrodes GCE–EG and GCE–CNT in sensing and detection of morpholine via differential pulse voltammetry....
Application of hybrid nanofluids in a novel combined photovoltaic/thermal and solar collector system
, Article Solar Energy ; Volume 239 , 2022 , Pages 102-116 ; 0038092X (ISSN) ; Salari, A ; Ma, T ; Lu, H ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
Because of the low outflow temperature of the conventional photovoltaic thermal systems and lack of electrical production of the solar thermal collectors, a novel combined system is proposed to solve the two mentioned drawbacks. This novel system is achieved by connecting a photovoltaic thermal unit to a solar thermal collector in series. To increase the overall performance of this novel combined system, different hybrid nanofluids include (1) multiwall carbon nanotube-aluminum oxide (2) multiwall carbon nanotube-silicon carbide (3) graphene-aluminum oxide, and (4) graphene-silicon carbide are compared. The investigation is performed based on the three-dimensional simulation, and the...
Enhancing Seebeck coefficient and electrical conductivity of polyaniline/carbon nanotube–coated thermoelectric fabric
, Article Journal of Industrial Textiles ; Volume 51, Issue 2_suppl , 2022 , Pages 3297S-3308S ; 15280837 (ISSN) ; Ramazani Saadatabadi, A ; Pourjahanbakhsh, M ; Siadati, M. H ; Sharif University of Technology
SAGE Publications Ltd
2022
Abstract
In this work, flexible thermoelectric fabrics, polyester/yarn fabrics coated with polyaniline/carbon nanotube (PANI/CNT) nanocomposite, were fabricated by sequential processing: (I) polyaniline/carbon nanotube nanocomposites preparation by a one-step in-situ polymerization and (II) dip coating of a mixture solution of CNT-doped PANI on a polyester/yarn fabric. Nanocomposites were synthesized with various CNT content (0.5, 2.5, 5, and 10 wt%) and characterized using different methods. The Seebeck coefficient and electrical conductivity measurements were used to determine their thermoelectric properties. The results revealed significant improvement in both electrical conductivity and the...
Green carbon-based nanocomposite biomaterials through the lens of microscopes
, Article Emergent Materials ; Volume 5, Issue 3 , 2022 , Pages 665-671 ; 25225731 (ISSN) ; Ahmadi, S ; Rabiee, M ; Bagherzadeh, M ; Vahabi, H ; Jouyandeh, M ; Saeb, M. R ; Sharif University of Technology
Springer Nature
2022
Abstract
In this work, a green synthesis method was designed and practiced to develop bioactive and biocompatible carbon-based nanocomposites biomaterials. ZnO nanoparticles were synthesized in assistance of leaf extracts and added to a composite nanostructure composed of the reduced graphene oxide (rGO) and multi-walled carbon nanotubes (MWCNT). The resulting green nanocomposite revealed ability to make π-π interactions, hydrogen bonding, and van der Waals interactions with the doxorubicin (DOX). Then, the surface morphology of the synthesized nanocomposite was investigated, and the interrelationship between the surface morphology, relative cell viability, and drug uptake and release behavior were...
Dynamics of antimicrobial peptide encapsulation in carbon nanotubes: the role of hydroxylation
, Article International Journal of Nanomedicine ; Volume 17 , 2022 , Pages 125-136 ; 11769114 (ISSN) ; Yousefi, F ; Seidi, F ; Sajadi, S. M ; Rabiee, N ; Habibzadeh, S ; Esmaeili, A ; Mashhadzadeh, A. H ; Spitas, C ; Mostafavi, E ; Saeb, M. R ; Sharif University of Technology
Dove Medical Press Ltd
2022
Abstract
Introduction: Carbon nanotubes (CNTs) have been widely employed as biomolecule carriers, but there is a need for further functionalization to broaden their therapeutic application in aqueous environments. A few reports have unraveled biomolecule–CNT interactions as a measure of response of the nanocarrier to drug-encapsulation dynamics. Methods: Herein, the dynamics of encapsulation of the antimicrobial peptide HA-FD-13 (accession code 2L24) into CNTs and hydroxylated CNTs (HCNTs) is discussed. Results: The van der Waals (vdW) interaction energy of CNT–peptide and HCNT–peptide complexes decreased, reaching −110.6 and −176.8 kcal.Mol−1, respectively, once encapsulation of the peptide inside...