Loading...
Search for: chemical-selectivity
0.011 seconds

    Tungstate-loaded triazine-based magnetic poly(Bis-imidazolium ionic liquid): An effective bi-functional catalyst for tandem selective oxidation/Knoevenagel condensation in water

    , Article Polymer (United Kingdom) ; Volume 112 , 2017 , Pages 342-350 ; 00323861 (ISSN) Zohreh, N ; Tavakolizadeh, M ; Hosseini, S. H ; Pourjavadi, A ; Bennett, C ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    A novel bi-functional polymeric catalyst was synthesized by immobilization of tungstate anions onto the nitrogen rich poly(ionic liquid)/magnetic nanocomposite. The resulting catalyst has two types of catalytic sites: (i) immobilized WO4 anions with bis-imidazolium ionic liquid cation for selective oxidation of alcohols and (ii) basic amine groups for Knoevenagel condensation between produced aldehyde and malononitrile. Due to the polymeric nature of the catalyst, large amounts of tungstate and basic nitrogen groups were presented on the solid surface which led to a decrease in the applied catalyst mass for catalytic reaction. High catalytic activity and excellent selectivity of catalyst in... 

    Design and fabrication of sensitive carbon nanotubes/PMMA film for acetone vapour detection

    , Article International Journal of Nanomanufacturing ; Volume 5, Issue 3-4 , 2010 , Pages 268-277 ; 17469392 (ISSN) Ghasempour, R ; Iraji Zad, A ; Hormozi Nezhad, M. R ; Sharif University of Technology
    2010
    Abstract
    We present gas sensing property of carbon nanotubes (CNTs) polymethylmethacrylate (PMMA) composite as the active element for acetone vapour detection at room temperature. The polymeric films were formed by spin coating method on SiO2 substrates. Then they were activated by dropping the CNTs suspension in acetone on the PMMA films. The CNT/PMMA films were characterised by SEM, TEM and Raman spectroscopy. Variation of film's electrical resistance after exposure polar and non-polar gases is utilised as the principle of gas sensing. The experimental results showed that the samples present chemical selectivity and reversibility toward polar gases especially acetone vapour