Sharif Digital Repository

Titanium anodes activated by noble metal oxides under the trade name of dimensionally stable anodes (DSAs) are widely used in the electrolytic industry, particularly in chlor – alkali electrolysis. Over 20 years of use, the fundamental aspects of their long – lasting performance are not fully understand and the corrosion mechanisms are still the subject of many investigations. RuO2 – TiO2 coatings on titanium substrate, due to proper electrochemical characteristics and good corrosion resistance, is most applicable as an anode in chlor – alkali systems. In the present investigation, the first layer of Pt – Ir coating is applied via electrodeposition method on the pretreated titanium substrate... 

The subject of this thesis to assessment environmental impacts of active desalination plants in Kish Island, which explains the problems derived from concentrate discharges in to the sea, sewage network, absorbing wells and ground surface.
It also studies its impacts on land and marine ecosystem and underground aquifers that are strategic resources in Kish Island. In addition, the environmental studies done in other countries, the existing regulations and by laws in the field of environmental impacts of desalination plants and concentrate discharges are re-mentioned. Concentrates contain chemicals, which are used in pre-filtration of MED and Ro systems, which are dangerous for marine... 

Polypropylene is a semi-crystalline thermoplastic used in various industries and the second most used polymer globally. Polypropylene is sensitive to degradation by o agents due to having tertiary carbon in its chain. Chlorine-based disinfectants, used to disinfect drinking water, cause the degradation of hot water pipes made of polypropylene random copolymer. The stability of polypropylene against oxidizing chemical agents depends on the type of crystalline phase and polymer morphology. This research investigated the effect of alpha, beta, and gamma crystalline phases and spherulite size on random polypropylene copolymer's chemical stability in chlorine dioxide. Three samples were prepared,... 

PE pipes and specially PE100 are commonly used for the transportation of drinking water, transferred water was mostly disinfected by disinfectants such as chlorine, chlorine dioxide and chloramine. Long-term contact with water containing disinfectants led to morphological and mechanical changes and followed by oxidative degradation and failure. Antioxidants are stabilizers which are used in PE pipes to postpone oxidation and increase the durability of these pipes. Migration of antioxidants is possible during the terms of service, in this case antioxidants can be washed by water and left the pipe. As a result, the loss of antioxidants decreases the stability of pipes and leads to oxidative... 

Today, in our beloved country of Iran and other parts of the world, reinforced concrete structures are used in large industrial projects, in some cases we see their very early failure even before the time of operation. This issue in the southern coasts of the country due to special weather conditions (humidity and high temperature) and the existence of the offensive ions such as chlorine and sulfate in seawater are more important and we always face with severe corrosion of reinforcement and reduced service life of concrete structures in these areas. Despite this, little research has been done on the reliability of concrete facilities in the vicinity of the Caspian Sea in the north of the... 

In this study, surface modification of Thin-film composite (TFC) membranes was performed in order to enhancement of its performance and chlorine resistance. TFC membranes was prepared through the interfacial polymerization between m-phenylenediamine (MPD) and trimesoyl chloride (TMC) on the polysulphone support membrane and surface modification performed through redox initiated graft polymerization of acrylic amide followed by acrylic acid. The successful surface modification of TFC membranes was evident from attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), contact angle (θ), scanning electron microscope (SEM) and atomic force microscope (AFM). Changes in... 

Reverse osmosis membrane one of the common methods used for water desalination, today membrane, thin film composite(TFC) include three layers, top the these layers named selection layer, this poly amid layer contacted with feed water, sensitivity to chlorine in polyamide layer lead to high membrane chlorine sensitive. Difference methods used for enhance the chlorine resistance in polyamide membrane that categorized in three general categories, covering and protection of sensitive areas method has best results in comparison to other methods. In this research protection method choose and used, material that used, sanitized by result from surface analysis of commercial membrane manufactured in... 

The release of toxic materials causes tragic accidents every year. There are various techniques in order to mitigate the release effect of these materials such as Application of air jets, steam curtains and water curtains. In this study first, previous works are reviewed in order to select the best technique for the mitigation of heavy toxic gas release. Then CFD modeling is used to simulate this technique.
A field situation in which chlorine gas was released upwind of water spray was simulated using the open-source software FDS (Fire Dynamic Simulator), a CFD model. Only mechanical effects of water sprays are considered; hence the effect of absorbtion is neglected. Finally tha... 

Chlorine is used in large quantities, in urban and industrial installations. Since chlorine is a toxic gas, its dispersion in such environments may have unpleasant consequences. On the point of Emergency Response Planning, it is important to know how such gases disperse. In this thesis, chlorine atmospheric dispersion is studied as an example of toxic dense gas dispersion. Chlorine accidental release from one of the storage tanks of Sohanak water refinery is selected for the case study. Laleh residential town is located in west of Sohanak refinery. According to the prevailing wind direction in Tehran (which is from the west to the east), the influence of the buildings of Laleh town on gas... 

Ionization probability of Cl2 molecule is studied by irradiation of 800 nm Ti: Sapphire laser pulses at intensities of 1014 Wcm-2 to 1016 Wcm-2 with the Gaussian package. Molecular orbital symmetry and orientation of the molecule dipole moment with laser field polarization axis are very effective in ionization probability. The results show that the most ionization probability for the intensity of 1014 wcm-2 is at 900 and also 50 at intensity of 1016 wcm-2. Due to the lack of intrinsic dipole moment, variation of dipole moment with the intensity, bond length and time evolution of dipole moment are investigated. It is found that there is a linear dependance of these parameters with ionization...